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A gas mixture containing 85.0 mole \(\% \mathrm{N}_{2}\) and the balance \(n\) -hexane flows through a pipe at a rate of \(100.0 \mathrm{m}^{3} / \mathrm{h} .\) The pressure is 2.00 atm absolute and the temperature is \(100^{\circ} \mathrm{C}\). (a) What is the molar flow rate of the gas in \(\mathrm{kmol} / \mathrm{h}\) ? (b) Is the gas saturated? If not, to what temperature ( \(^{C} C\) ) would it have to be cooled at constant pressure in order to begin condensing hexane? (c) To what temperature ( \(C\) ) would the gas have to be cooled at constant pressure in order to condense \(80 \%\) of the hexane?

Short Answer

Expert verified
(a) The molar flow rate is approximately 6.56 kmol/h. (b) No, the gas is not saturated. The hexane would start to condense at about 50°C. (c) The gas would have to be cooled to approximately the bubble point temperature to condense 80% of the hexane.

Step by step solution

01

Calculate the molar flow rate

The molar flow rate is calculated using the ideal gas law: \(PV = nRT\). Rearranging for molar flow rate gives \(n = PV/RT\). Given P=2 atm, V=100 m3/h, T=100°C =373 K, and R=0.0821 atm.m3/mol.K, the molar flow rate becomes \(n = (2*100)/(0.0821*373)\) kmol/h.
02

Check for saturation and find the condensation point

The pressure at which a component in a mixture starts to condense is called its dew point. For hexane, the vapor pressure at 100 °C is 2 atm. Since the total pressure of the mixture is also 2 atm, there is no component which is saturated. Hence, hexane cannot start to condense at the given temperature. To find out at what temperature it would start to condense, we need to find the temperature at which the vapor pressure of hexane equals the partial pressure of hexane in the mixture. The composition of hexane is 15% (100%-85%), therefore the partial pressure of hexane = 0.15 * 2 atm = 0.3 atm. From hexane vapor pressure data, the dew point temperature corresponding to this pressure can be found as below or approximately equals 50 °C.
03

Find the condensation temperature for 80% hexane

To condense 80% of hexane, the temperature has to be decreased further. This temperature, known as bubble point, is found from the vapor pressure data of hexane corresponding to the pressure at which 80% of hexane would be in the liquid phase. This is determined by the fraction of hexane in liquid phase to total hexane = 0.8 = n liquid hexane / (n liquid hexane + n vapor hexane). Here, n liquid hexane is the moles of hexane in liquid phase and n vapor hexane is the moles of hexane in vapor phase.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Law
The ideal gas law is a fundamental equation in the study of gas behavior, and it's given by the formula: \( PV = nRT \). Here, \( P \) represents pressure, \( V \) is volume, \( n \) is the number of moles, \( R \) is the universal gas constant, and \( T \) is the temperature in Kelvin. In practical terms, this law allows us to calculate the amount of gas present (as moles) if we know the pressure, volume, and temperature conditions. In the given example, we use this equation to calculate the molar flow rate of a gas mixture flowing through a pipe.

When dealing with molar flow rate, we're interested in how many moles of gas pass through a certain point per hour in our case. It's crucial because it dictates how much substance is available for a chemical reaction or a physical process like condensation, which is exactly why it's a key figure in the provided exercise.
Saturation Point
The saturation point in a gas phase occurs when the gas contains the maximum amount of a vapor that it can hold at a particular temperature and pressure. Beyond this point, any additional vapor will start to condense into liquid. It's the edge of condensation, and for a mixture, it varies for each component of the mixture. The saturation point is an essential concept when distinguishing between a saturated and unsaturated gas.

The exercise asks to determine if the gas is saturated with hexane. Understanding the saturation point is key to answering whether the gas is at a state where hexane can begin to condense, which provides insight into the behavior of the gas under various conditions, such as temperature changes at a constant pressure.
Dew Point
The dew point is a specific type of saturation point—it is the temperature at which a gas becomes fully saturated with a vapor and condensation begins. At the dew point, the vapor's partial pressure equals its vapor pressure, leading to condensation. In the exercise, we check whether hexane starts condensing at the given temperature of 100°C and a pressure of 2 atm by comparing it with vapor pressure data of hexane.

Understanding the dew point is critical for many industrial processes, to prevent unwanted condensation in gas lines, for instance. Determining the dew point gives us a threshold temperature to ensure the gas remains in the vapor phase. This exercise requires such understanding to establish at what temperature condensation would start under a constant pressure.
Bubble Point
Opposite to the dew point, the bubble point is the temperature at which the first bubbles of vapor form when a liquid mixture is heated. For a solution with multiple components, the bubble point corresponds to the temperature where the solution becomes saturated enough for the least volatile component to vaporize. In the exercise scenario, we are asked to calculate the temperature at which 80% of hexane would have condensed out of the mixture, essentially looking for the bubble point of the hexane in the nitrogen-hexane mix.

Understanding the bubble point is crucial for tasks such as distillation or separation processes, where control over the phase of substances is necessary. It informs the specific conditions required to initiate the phase transition from liquid to vapor, providing a precise control over the substance's state.
Vapor Pressure
Vapor pressure is the pressure exerted by a vapor in equilibrium with its liquid or solid form at a particular temperature. It's an indication of a liquid's evaporation rate and depends on the substance's temperature. Vapor pressure is used to find the dew point and bubble point by establishing when a component of a mixture will transition between its liquid and vapor phases.

In the exercise, the vapor pressure of hexane is critical to determining the dew and bubble points. By comparing the vapor pressure of hexane at various temperatures with the partial pressure of hexane in the gas mixture, we can ascertain the temperature at which hexane begins to condense, as well as the temperature needed to condense a specified quantity of hexane, when the mix is at a constant pressure.

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Most popular questions from this chapter

Air containing 20.0 mole \(\%\) water vapor at an initial pressure of 1 atm absolute is cooled in a 1 -liter sealed vessel from \(200^{\circ} \mathrm{C}\) to \(15^{\circ} \mathrm{C}\).(a) What is the pressure in the vessel at the end of the process? (Hint: The partial pressure of air in the system can be determined from the expression \(p_{\text {air }}=n_{\text {air }} R T / V\) and \(P=p_{\text {air }}+p_{\mathrm{H}_{1}, \mathrm{O}} .\) You may neglect the volume of the liquid water condensed, but you must show that condensation occurs.) (b) What is the mole fraction of water in the gas phase at the end of the process?(c) How much water (grams) condenses?

The vapor pressure of an organic solvent is \(50 \mathrm{mm}\) Hg at \(25^{\circ} \mathrm{C}\) and \(200 \mathrm{mm} \mathrm{Hg}\) at \(45^{\circ} \mathrm{C}\). The solvent is the only species in a closed flask at \(35^{\circ} \mathrm{C}\) and is present in both liquid and vapor states. The volume of gas above the liquid is \(150 \mathrm{mL}\). (a) Estimate the amount of the solvent \((\mathrm{mol})\)contained in the gas phase. (b) What assumptions did you make? How would your answer change if the species dimerized (one molecule results from two molecules of the species combining)?

Ethyl alcohol has a vapor pressure of \(20.0 \mathrm{mm} \mathrm{Hg}\) at \(8.0^{\circ} \mathrm{C}\) and a normal boiling point of \(78.4^{\circ} \mathrm{C}\). Estimate the vapor pressure at \(45^{\circ} \mathrm{C}\) using \((\mathrm{a})\) the Antoine equation; (b) the Clausius-Clapeyron equation and the two given data points; and (c) linear interpolation between the two given points. Taking the first estimate to be correct, calculate the percentage error associated with the second and third estimates.

A fuel gas containing methane and ethane is burned with air in a furnace, producing a stack gas at \(300^{\circ} \mathrm{C}\) and \(105 \mathrm{kPa}\) (absolute). You analyze the stack gas and find that it contains no unburned hydrocarbons, oxygen, or carbon monoxide. You also determine the dew-point temperature.(a) Estimate the range of possible dew-point temperatures by determining the dew points when the feed is either pure methane or pure ethane. (b) Estimate the fraction of the feed that is methane if the measured dew- point temperature is \(59.5^{\circ} \mathrm{C}\). (c) What range of measured dew point temperatures would lead to calculated methane mole fractions within 5\% of the value determined in Part (b)?

An adult inhales approximately 12 times per minute, taking in about 500 mL of air with each inhalation. Oxygen and carbon dioxide are exchanged in the lungs, but there is essentially no exchange of nitrogen. The exhaled air has a mole fraction of nitrogen of 0.75 and is saturated with water vapor at body temperature, \(37^{\circ} \mathrm{C}\). If ambient conditions are \(25^{\circ} \mathrm{C}, 1\) atm, and \(50 \%\) relative humidity, what volume of liquid water (mL) would have to be consumed over a two-hour period to replace the water loss from breathing? How much would have to be consumed if the person is on an airplane where the temperature, pressure, and relative humidity are respectively \(25^{\circ} \mathrm{C}, 1 \mathrm{atm},\) and \(10 \% ?\)

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