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A \(5.00-\mathrm{wt} \%\) aqueous sulfuric acid solution \((\rho=1.03 \mathrm{g} / \mathrm{ml})\) flows through a \(45-\mathrm{m}\) long pipe with a\(6.0 \mathrm{cm}\) diameter at a rate of \(82 \mathrm{L} / \mathrm{min}\). (a) What is the molarity of sulfuric acid in the solution? (b) How long (in seconds) would it take to fill a 55-gallon drum, and how much sulfuric acid (Ibm) would the drum contain? (You should arrive at your answers with two dimensional equations.) (c) The mean velocity of a fluid in a pipe equals the volumetric flow rate divided by the cross-sectional area normal to the direction of flow. Use this information to estimate how long (in seconds) it takes the solution to flow from the pipe inlet to the outlet.

Short Answer

Expert verified
The molarity of sulfuric acid in the solution is 0.525 M. It would take approximately 152.4 seconds to fill a 55-gallon drum and the drum would contain 10.72 kg of sulfuric acid. Finally, it would take approximately 888 seconds for the solution to flow through the 45-m long pipe.

Step by step solution

01

Determine Molarity

Firstly, convert the mass percentage of sulfuric acid to mass. The mass of sulfuric acid is \(0.05 \times mass \ of \ solution\). Given that the density \(\rho\) of the solution is 1.03 g/ml, the mass of the solution = Volume \(\times \rho = 1000 \ ml \times 1.03 \ g/ml = 1030 \ g\). Hence, mass of sulfuric acid = \(0.05 \times 1030 = 51.5 \ g\). Convert this mass to moles using the molar mass of sulfuric acid (98.08 g/mol), yielding \(mol = \frac{51.5 \ g}{98.08 \ g/mol} = 0.525 \ moles\). The molarity of sulfuric acid in the solution can then be found by dividing the moles of sulfuric acid by the volume of the solution in liters. Therefore, the molarity of H2SO4 = \(\frac{0.525 \ moles}{1 \ L} = 0.525 \ M\)
02

Calculate Time to Fill the Drum and Amount of Sulfuric Acid

To calculate the time it would take to fill the drum, convert the flow rate from L/min to gallons per min. The flow rate conversion can be done by using the relation \(1 \ gallon = 3.78541 \ liters\). Hence, flow rate = \(\frac{82 \ liters/min}{3.78541} = 21.67 \ gallons/min\). Time to fill a 55-gallon drum = \(\frac{55 \ gallons}{21.67 \ gallons/min} = 2.54 \ min \approx 152.4 \ seconds\). To calculate how much sulfuric acid the drum would contain, use the fact that the drum is 55 gallons, which equates to \(55 \times 3.78541 = 208.2 \ liters\). We already calculated the mass of sulfuric acid per liter in Step 1, so the mass of sulfuric in the drum will be \(208.2 \ L \times 51.5 \ g/L = 10722.3 \ g\) or 10.72 kg.
03

Calculate Flow Time through the Pipe

First, calculate the cross-sectional area of the pipe. The given diameter must be converted to m: \(d = 0.06 \ m\). So, the cross-sectional area \(A = \pi*(d/2)^2 = 0.00283 \ m^2\). Then, calculate the volumetric flow rate in \(\m^3/s\). Convert 82L/min to \(\m^3/s: 82 \ L/min = 0.00137 \ m^3/s\). Finally, using the formula for mean velocity \(v = Flow \ rate/Area\), the time taken for the solution to flow through the pipe can be calculated as \(time = length/v = 45m / 0.00137 \ m^3/s ÷ 0.00283 \ m^2 = 887.7 \ seconds\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molarity Calculation
Understanding molarity is a cornerstone in the study of chemistry, especially when dealing with solutions and their concentrations. Molarity, often represented by the symbol 'M', is a measure of the concentration of a solute in a solution. It is defined as the number of moles of solute dissolved in one liter of solution. To calculate molarity, you divide the number of moles of the solute by the volume of the solution in liters. The process involves several conversion steps, starting with the weight percentage given as follows:

First, convert the weight percentage to mass, taking into account not only the percentage but also the density of the solution. This is crucial because the density provides a direct link between the volume of the liquid and its mass - a key step that should not be overlooked. After the mass of the solute is determined, it's converted into moles by using the molar mass of the solute, which is specific to each chemical compound. In our case, the conversion of grams of sulfuric acid to moles is done via its molar mass. Finally, as seen in the solution provided, the calculated moles are divided by the volume of the solution to obtain the molarity. Remember, the accuracy of these steps, particularly the correct usage of density and molar mass, is paramount to ending up with the correct molarity.
Volumetric Flow Rate
When dealing with the dynamics of fluids in motion, the volumetric flow rate becomes an essential parameter. It quantifies the volume of fluid passing through a given section of a pipe or channel per unit time. Essentially, it's a measure of how 'fast' the fluid is moving in terms of volume over time. In our exercise, the volumetric flow rate is provided in liters per minute, which we must work with in terms of more standard units like cubic meters per second when dealing with equations that utilize SI units.

The conversion from the given unit to the standard unit involves dividing by 1000 (since there are 1000 liters in a cubic meter) and then by 60 (since there are 60 seconds in a minute). Understanding and performing such unit conversions are critical as they ensure compatibility when applying formulas within fluid mechanics, such as calculating the mean velocity of a fluid in a pipe or the Bernoulli equation, for instance. In practice, the volumetric flow rate is a pivotal factor when calculating the time needed for filling a tank or for fluids to traverse particular distances, as it directly impacts the time-based outcomes of such operations.
Fluid Mechanics in Pipes
When one dives into fluid mechanics, the behavior of fluids in pipes presents a variety of interesting phenomena addressed through various principles and equations. In a pipe system, the mean velocity is the average speed at which a fluid is moving along the pipe. As elucidated in the exercise's given information, the mean velocity can be found by dividing the volumetric flow rate by the cross-sectional area of the pipe. This calculation is foundational in understanding how long it takes for a fluid to travel from one point to another within the pipe system.

To begin, calculate the cross-sectional area with the pipe's internal diameter; remember that it's the radius squared, not the diameter, that's used in the area calculation of a circle. Once the cross-sectional area is determined, it's a relatively straightforward process to derive the mean velocity by using the volumetric flow rate — now converted into appropriate units — and apply this information to find out how long it takes for the entire volume of fluid to flow through the length of the pipe. This aspect of fluid mechanics is especially important in fields ranging from engineering to environmental science, where the timing and distribution of fluid flow can have significant implications.

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Most popular questions from this chapter

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