/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 117 A mixture of \(\mathrm{KClO}_{3}... [FREE SOLUTION] | 91Ó°ÊÓ

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A mixture of \(\mathrm{KClO}_{3}\) and \(\mathrm{KCl}\) with a mass of \(0.950 \mathrm{~g}\) was heated to produce \(\mathrm{O}_{2}\). After heating, the mass of residue was 0.700 g. Assuming all the \(\mathrm{KClO}_{3}\) decomposed to \(\mathrm{KCl}\) and \(\mathrm{O}_{2}\), calculate the mass percent of \(\mathrm{KClO}_{3}\) in the original mixture.

Short Answer

Expert verified
The mass percent of \(\text{KClO}_3\) in the original mixture is 67.3%.

Step by step solution

01

Write the balanced chemical equation for the decomposition of \(\text{KClO}_3\)

The balanced equation for the decomposition reaction is: \[ \text{2KClO}_3 (s) \rightarrow 2\text{KCl} (s) + 3\text{O}_2 (g) \]
02

Calculate the mass of \(\text{O}_2\) produced

The mass of \(\text{O}_2\) produced is the difference between the initial mass of the mixture and the mass of the residue. \[\text{Mass of } \text{O}_2 = 0.950 \text{g} - 0.700 \text{g} = 0.250 \text{g}\]
03

Use the molar masses to find the moles of \(\text{O}_2\) produced

The molar mass of \(\text{O}_2\) is \(2 \times 16 = 32 \text{ g/mol}\). Therefore, the moles of \(\text{O}_2\) produced is found by \[ \text{Moles of } \text{O}_2 = \frac{0.250 \text{ g}}{32 \text{ g/mol}} = 0.00781 \text{ mol} \]
04

Use stoichiometry to find the moles of \(\text{KClO}_3\) decomposed

According to the balanced equation, \(3 \text{ moles of } \text{O}_2\) are produced from \(2 \text{ moles of } \text{KClO}_3\). Therefore, \[ \text{Moles of } \text{KClO}_3 = \frac{2}{3} \times 0.00781 = 0.00521 \text{ mol}\]
05

Calculate the mass of decomposed \(\text{KClO}_3\)

The molar mass of \(\text{KClO}_3\) is \(39.1 + 35.5 + 3 \times 16 = 122.6 \text{ g/mol}\). Using this, the mass of decomposed \(\text{KClO}_3\) is found by \[ \text{Mass of } \text{KClO}_3 = 0.00521 \text{ mol} \times 122.6 \text{ g/mol} = 0.639 \text{ g}\]
06

Calculate the mass percent of \(\text{KClO}_3\) in the original mixture

The mass percent of \(\text{KClO}_3\) in the mixture is calculated as: \[ \text{Mass percent of } \text{KClO}_3 = \frac{0.639 \text{ g}}{0.950 \text{ g}} \times 100 = 67.3 \text{%} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

stoichiometry
Understanding stoichiometry is essential for solving chemical equations and determining the relationship between reactants and products. Stoichiometry involves using the balanced chemical equation to understand the proportions of reactants and products in a chemical reaction. For example, consider the decomposition of potassium chlorate (\text{KClO}_3). The balanced equation is:
\[ 2\text{KClO}_3 (s) \rightarrow 2\text{KCl} (s) + 3\text{O}_2 (g) \]
This equation tells us that \textbf{2 moles} of \text{KClO}_3 produce \textbf{2 moles} of \text{KCl} and \textbf{3 moles} of \text{O}_2.

By using these ratios, we can calculate how much of one substance we need or will create by knowing the quantity of another. In our exercise, we use stoichiometry to find out how many moles of \text{KClO}_3 were used by relating them to the moles of \text{O}_2} produced. By understanding these mole ratios, we can deduce quantitative information about the substances involved in the chemical reaction. This is a powerful tool in chemistry for predicting outcomes and designing reactions.
molar mass
Molar mass is the mass of one mole of a substance, measured in grams per mole (\text{g/mol}). The molar mass helps us convert between the mass of a substance and the number of moles. To find the molar mass, you sum the atomic masses of all atoms in a molecule.

For example, let's calculate the molar mass of potassium chlorate (\text{KClO}_3):
\[ \text{Molar mass of KClO}_3 = (39.1 \text{ for K}) + (35.5 \text{ for Cl}) + (3 \times 16 \text{ for 3 O atoms}) = 122.6 \text{ g/mol} \]
In our exercise, we calculated the molar mass of \text{O}_2 and \text{KClO}_3 to convert between grams and moles. The molar mass of \text{O}_2 is: \[ \text{Molar mass of O}_2 = 2 \times 16 = 32 \text{ g/mol} \]
Using these molar masses, we can solve the exercise by converting the grams of \text{O}_2 produced to moles, and then using the stoichiometric ratios to find out how many moles of \text{KClO}_3 were decomposed. Finally, we convert the moles of \text{KClO}_3 back to grams using its molar mass.
mass percent composition
Mass percent composition is a way of expressing the concentration of a component in a mixture. It measures how much of the total mass is made up by a specific component. It is calculated by dividing the mass of the component by the total mass of the mixture and then multiplying by 100 to get a percentage.

In our exercise, we found the mass percent of potassium chlorate (\text{KClO}_3) in the original mixture by first determining the mass of decomposed \text{KClO}_3.
We found that: \[ \text{Mass of } \text{KClO}_3 = 0.639 \text{ g} \]
Given that the total mass of the mixture was 0.950 g, we calculated the mass percent using: \[ \text{Mass percent of } \text{KClO}_3 = \frac{0.639 \text{ g}}{0.950 \text{ g}} \times 100 = 67.3 \text{%} \]
This means that 67.3% of the original mixture was \text{KClO}_3. The mass percent composition helps us understand the proportion of each substance in mixtures, which is crucial for many chemical applications including reactions and formulations.

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Most popular questions from this chapter

The amount of ascorbic acid (vitamin \(\left.\mathrm{C}, \mathrm{C}_{6} \mathrm{H}_{8} \mathrm{O}_{6}\right)\) in tablets is determined by reaction with bromine and then titration of the hydrobromic acid with standard base: $$ \begin{array}{l} \mathrm{C}_{6} \mathrm{H}_{8} \mathrm{O}_{6}(a q)+\mathrm{Br}_{2}(a q) \longrightarrow \mathrm{C}_{6} \mathrm{H}_{6} \mathrm{O}_{6}(a q)+2 \mathrm{HBr}(a q) \\ \mathrm{HBr}(a q)+\mathrm{NaOH}(a q) \longrightarrow \mathrm{NaBr}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \end{array} $$ A certain tablet is advertised as containing \(500 \mathrm{mg}\) of vitamin \(\mathrm{C}\). One tablet was dissolved in water and reacted with \(\mathrm{Br}_{2}\). The solution was then titrated with \(43.20 \mathrm{~mL}\) of \(0.1350 \mathrm{M} \mathrm{NaOH}\). Did the tablet contain the advertised quantity of vitamin C?

A student forgets to weigh a mixture of sodium bromide dihydrate and magnesium bromide hexahydrate. Upon strong heating, the sample loses \(252.1 \mathrm{mg}\) of water. The mixture of anhydrous salts reacts with excess AgNO \(_{3}\) solution to form \(6.00 \times 10^{-3} \mathrm{~mol}\) of solid AgBr. Find the mass \(\%\) of each compound in the original mixture.

Predict the product(s) and write a balanced equation for each of the following redox reactions: (a) \(\mathrm{Mg}(s)+\mathrm{HCl}(a q) \longrightarrow\) (b) \(\mathrm{LiCl}(l) \stackrel{\text { electricity }}{\longrightarrow}\) (c) \(\operatorname{SnCl}_{2}(a q)+\operatorname{Co}(s) \longrightarrow\)

Is each of the following very soluble in water? Explain. (a) Benzene, \(\mathrm{C}_{6} \mathrm{H}_{6}\) (b) Sodium hydroxide (c) Ethanol, \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\) (d) Potassium acetate 4.15 Is cach of the following very soluble in water? Explain. (a) Lithium nitrate (b) Gilycine, \(\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{COOH}\) (c) Pentane (d) Ethylene glycol, \(\mathrm{HOCH}_{2} \mathrm{CH}_{2} \mathrm{OH}\)

How many moles of \(\mathrm{H}^{+}\) ions are present in each of the following aqueous solutions? (a) \(1.4 \mathrm{~mL}\) of \(0.75 \mathrm{M}\) hydrobromic acid (b) \(2.47 \mathrm{~mL}\) of \(1.98 \mathrm{M}\) hydriodic acid (c) \(395 \mathrm{~mL}\) of \(0.270 \mathrm{M}\) nitric acid

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