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Predict the product(s) and write a balanced equation for each of the following redox reactions: (a) \(\mathrm{Mg}(s)+\mathrm{HCl}(a q) \longrightarrow\) (b) \(\mathrm{LiCl}(l) \stackrel{\text { electricity }}{\longrightarrow}\) (c) \(\operatorname{SnCl}_{2}(a q)+\operatorname{Co}(s) \longrightarrow\)

Short Answer

Expert verified
Reaction (a): \(\mathrm{Mg}(s) + 2\mathrm{HCl}(aq) \longrightarrow \mathrm{MgCl}_2(aq) + \mathrm{H}_2(g)\)\ Reaction (b): \(2\mathrm{LiCl}(l) \longrightarrow 2\mathrm{Li}(l) + \mathrm{Cl}_2(g)\)\ Reaction (c): \(\mathrm{SnCl}_2(aq) + \mathrm{Co}(s) \longrightarrow \mathrm{Sn}(s) + \mathrm{CoCl}_2(aq)\)

Step by step solution

01

Determine the products for reaction (a)

Identify the type of reaction. Here, Mg (solid) reacts with HCl (aqueous) in a single replacement reaction, where Mg displaces H in HCl. The products will be MgClâ‚‚ (aq) and Hâ‚‚ (g).
02

Balance equation for reaction (a)

Write the unbalanced equation: \ \(\mathrm{Mg}(s) + \mathrm{HCl}(aq) \longrightarrow \mathrm{MgCl}_2(aq) + \mathrm{H}_2(g)\) \ To balance, adjust coefficients: \ \(\mathrm{Mg}(s) + 2\mathrm{HCl}(aq) \longrightarrow \mathrm{MgCl}_2(aq) + \mathrm{H}_2(g)\)
03

Determine the products for reaction (b)

Identify the type of reaction, which is an electrolysis reaction. LiCl (l) decomposes into its elements: Li (liquid) and Clâ‚‚ (gas).
04

Balance equation for reaction (b)

Write the unbalanced equation: \ \(\mathrm{LiCl}(l) \longrightarrow \mathrm{Li}(l) + \mathrm{Cl}_2(g)\)\ To balance, maintain 1:1 mole ratio and note that two moles of LiCl will decompose to one mole of Clâ‚‚: \ \(2\mathrm{LiCl}(l) \longrightarrow 2\mathrm{Li}(l) + \mathrm{Cl}_2(g)\)
05

Determine the products for reaction (c)

Identify the type of reaction, which is a single replacement reaction where Co replaces Sn in SnClâ‚‚. The products are Sn (solid) and CoClâ‚‚ (aqueous).
06

Balance equation for reaction (c)

Write the unbalanced equation: \ \(\mathrm{SnCl}_2(aq) + \mathrm{Co}(s) \longrightarrow \mathrm{Sn}(s) + \mathrm{CoCl}_2(aq)\) \ This equation is already balanced: \ \(\mathrm{SnCl}_2(aq) + \mathrm{Co}(s) \longrightarrow \mathrm{Sn}(s) + \mathrm{CoCl}_2(aq)\)

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

chemical equations
Chemical equations are symbolic representations of chemical reactions. They show the reactants (starting materials) and the products (substances formed) in the reaction. For example, in the reaction between magnesium (Mg) and hydrochloric acid (HCl):\[ \mathrm{Mg}(s) + \mathrm{HCl}(aq) \longrightarrow \mathrm{MgCl}_2(aq) + \mathrm{H}_2(g) \]The reactants are on the left side, and the products are on the right side. Plus signs separate different reactants or products, while the arrow indicates the direction of the reaction.
To understand chemical equations, you need to be familiar with:
  • State symbols: (s) for solid, (l) for liquid, (g) for gas, and (aq) for aqueous solution.
  • Balancing equations to ensure the same number of each type of atom appears on both sides of the equation.
  • Coefficients to indicate the number of molecules or moles of each substance.
single replacement reactions
Single replacement reactions, also known as single displacement reactions, occur when one element replaces another in a compound. An example is when magnesium (Mg) reacts with hydrochloric acid (HCl):\[ \mathrm{Mg}(s) + 2\mathrm{HCl}(aq) \longrightarrow \mathrm{MgCl}_2(aq) + \mathrm{H}_2(g) \]Here, magnesium displaces hydrogen from HCl to form magnesium chloride (MgClâ‚‚) and hydrogen gas (Hâ‚‚). Elements in single replacement reactions often follow an activity series, a list of elements ordered by their reactivity. The more reactive element can replace a less reactive element in a compound. This understanding helps predict the outcome of such reactions.
This type of reaction is significant in various applications, including metal extraction and corrosion processes.
electrolysis reactions
Electrolysis reactions use electrical energy to drive a non-spontaneous chemical reaction. An example is the decomposition of molten lithium chloride (LiCl):\[ 2\mathrm{LiCl}(l) \stackrel{\text{electricity}}{\longrightarrow} 2\mathrm{Li}(l) + \mathrm{Cl}_2(g) \]In this reaction, electrical energy causes LiCl to decompose into liquid lithium and chlorine gas. Electrolysis involves:
  • An electrolyte, which conducts electricity when molten or dissolved in water.
  • Electrodes, where oxidation and reduction occur. The anode (positive) attracts anions, while the cathode (negative) attracts cations.
  • Battery or power source, which provides the energy required for the reaction.
Electrolysis is used in various industrial processes, such as metal plating, extraction of metals, and production of chlorine and hydrogen gases.
reaction balancing
Balancing chemical equations ensures the law of conservation of mass is satisfied, meaning the same number of each type of atom appears on both sides of the equation. Here are the strategies to balance equations:
  • Identify the most complex molecule in the reaction and start balancing it first.
  • Balance elements that appear only once on each side of the equation next.
  • Save hydrogen and oxygen atoms for last, as they often appear in multiple compounds.
  • Use coefficients to multiply the number of atoms as needed, but never change subscripts within a compound.
For example, in the reaction between tin (II) chloride (SnClâ‚‚) and cobalt (Co):\[\operatorname{SnCl}_{2}(a q)+\operatorname{Co}(s) \longrightarrow \operatorname{Sn}(s) + \operatorname{CoCl}_2(aq) \]This equation is already balanced, as each element has the same number of atoms on both sides. Mastering reaction balancing is crucial for accurately representing chemical processes.

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Most popular questions from this chapter

A mixture of \(\mathrm{KClO}_{3}\) and \(\mathrm{KCl}\) with a mass of \(0.950 \mathrm{~g}\) was heated to produce \(\mathrm{O}_{2}\). After heating, the mass of residue was 0.700 g. Assuming all the \(\mathrm{KClO}_{3}\) decomposed to \(\mathrm{KCl}\) and \(\mathrm{O}_{2}\), calculate the mass percent of \(\mathrm{KClO}_{3}\) in the original mixture.

Do either of the following reactions go to completion? If \(\mathrm{so}\) what factor(s) cause(s) cach to do so? (a) \(\mathrm{MgSO}_{3}(s)+2 \mathrm{HCl}(a q) \longrightarrow \mathrm{MgCl}_{2}(a q)+\mathrm{SO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(l)\) (b) \(3 \mathrm{Ba}(\mathrm{OH})_{2}(a q)+2 \mathrm{H}_{3} \mathrm{PO}_{4}(a q) \longrightarrow \mathrm{Ba}_{3}\left(\mathrm{PO}_{4}\right)_{2}(s)+6 \mathrm{H}_{2} \mathrm{O}(I)\)

Identify the oxidizing and reducing agents in the following reactions: $$ \begin{array}{l} \text { (a) } 5 \mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(a q)+2 \mathrm{MnO}_{4}^{-}(a q)+6 \mathrm{H}^{*}(a q) \longrightarrow \\ 2 \mathrm{Mn}^{2+}(a q)+10 \mathrm{CO}_{2}(g)+8 \mathrm{H}_{2} \mathrm{O}(l) \end{array} $$ (b) \(3 \mathrm{Cu}(s)+8 \mathrm{H}^{+}(a q)+2 \mathrm{NO}_{3}^{-}(a q) \longrightarrow\) $$ 3 \mathrm{Cu}^{2+}(a q)+2 \mathrm{NO}(g)+4 \mathrm{H}_{2} \mathrm{O}(l) $$

Physicians who specialize in sports medicine routinely treat athletes and dancers. Ethyl chloride, a local anesthetic commonly used for simple injuries, is the product of the combination of ethylene with hydrogen chloride: $$ \mathrm{C}_{2} \mathrm{H}_{4}(g)+\mathrm{HCl}(g) \longrightarrow \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Cl}(g) $$ Assume that \(0.100 \mathrm{~kg}\) of \(\mathrm{C}_{2} \mathrm{H}_{4}\) and \(0.100 \mathrm{~kg}\) of \(\mathrm{HCl}\) react. (a) How many molecules of gas (reactants plus products) are present when the reaction is complete? (b) How many moles of gas are present when half the product forms?

In a titration of \(\mathrm{HNO}_{3}\), you add a few drops of phenolphthalein indicator to \(50.00 \mathrm{~mL}\) of acid in a flask. You quickly add \(20.00 \mathrm{~mL}\) of \(0.0502 \mathrm{M} \mathrm{NaOH}\) but overshoot the end point, and the solution turns deep pink. Instead of starting over, you add \(30.00 \mathrm{~mL}\) of the acid, and the solution turns colorless. Then, it takes \(3.22 \mathrm{~mL}\) of the \(\mathrm{NaOH}\) to reach the end point. (a) What is the concentration of the \(\mathrm{HNO}_{3}\) solution? (b) How many moles of \(\mathrm{NaOH}\) were in excess after the first addition?

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