Chapter 10: Problem 35
The Goodyear blimps, which frequently fly over sporting events, hold approximately \(175,000 \mathrm{ft}^{3}\) of helium. If the gas is at \(23^{\circ} \mathrm{C}\) and \(1.0 \mathrm{~atm}\), what mass of helium is in a blimp?
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Chapter 10: Problem 35
The Goodyear blimps, which frequently fly over sporting events, hold approximately \(175,000 \mathrm{ft}^{3}\) of helium. If the gas is at \(23^{\circ} \mathrm{C}\) and \(1.0 \mathrm{~atm}\), what mass of helium is in a blimp?
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Which of the following statements best explains why nitrogen gas at STP is less dense than Xe gas at STP? (a) Because Xe is a noble gas, there is less tendency for the Xe atoms to repel one another, so they pack more densely in the gaseous state. (b) Xe atoms have a higher mass than \(\mathrm{N}_{2}\) molecules. Because both gases at STP have the same number of molecules per unit volume, the Xe gas must be denser. (c) The Xe atoms are larger than \(\mathrm{N}_{2}\) molecules and thus take up a larger fraction of the space occupied by the gas. (d) Because the Xe atoms are much more massive than the \(\mathrm{N}_{2}\) molecules, they move more slowly and thus exert less upward force on the gas container and make the gas appear denser.
Consider a mixture of two gases, \(A\) and \(B\), confined in a closed vessel. A quantity of a third gas, \(C\), is added to the same vessel at the same temperature. How does the addition of gas \(C\) affect the following: (a) the partial pressure of gas A, (b) the total pressure in the vessel, (c) the mole fraction of gas B?
The metabolic oxidation of glucose, \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\), in our bodies produces \(\mathrm{CO}_{2}\), which is expelled from our lungs as a gas: $$ \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(a q)+6 \mathrm{O}_{2}(g) \longrightarrow 6 \mathrm{CO}_{2}(g)+6 \mathrm{H}_{2} \mathrm{O}(l) $$ (a) Calculate the volume of dry \(\mathrm{CO}_{2}\) produced at body temperature \(\left(37^{\circ} \mathrm{C}\right)\) and \(0.970 \mathrm{~atm}\) when \(24.5 \mathrm{~g}\) of glucose is consumed in this reaction. (b) Calculate the volume of oxygen you would need, at \(1.00\) atm and \(298 \mathrm{~K}\), to completely oxidize \(50.0 \mathrm{~g}\) of glucose.
Ammonia and hydrogen chloride react to form solid ammonium chloride: $$ \mathrm{NH}_{3}(g)+\mathrm{HCl}(g) \longrightarrow \mathrm{NH}_{4} \mathrm{Cl}(s) $$ Two \(2.00\) - \(\mathrm{L}\) flasks at \(25^{\circ} \mathrm{C}\) are connected by a valve, as shown in the drawing on the next page. One flask contains \(5.00 \mathrm{~g}\) of \(\mathrm{NH}_{3}(g)\), and the other contains \(5.00 \mathrm{~g}\) of \(\mathrm{HCl}(g)\). When the valve is opened, the gases react until one is completely consumed. (a) Which gas will remain in the system after the reaction is complete? (b) What will be the final pressure of the system after the reaction is complete? (Neglect the volume of the ammonium chloride formed.) (c) What mass of ammo-
(a) A liquid and a gas are moved to larger containers. How does their behavior differ once they are in the larger containers? Explain the difference in molecular terms. (b) Although liquid water and carbon tetrachloride, \(\mathrm{CCl}_{4}(l)\), do not mix, their vapors form a homogeneous mixture. Explain. (c) Gas densities are generally reported in grams per liter, whereas liquid densities are reported in grams per milliliter. Explain the molecular basis for this difference.
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