Chapter 19: Q.18E (page 1093)
Describe the electrolytic process for refining copper.
Short Answer
We use electrolysis to get pure form of copper.
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Chapter 19: Q.18E (page 1093)
Describe the electrolytic process for refining copper.
We use electrolysis to get pure form of copper.
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Sketch the structures of the following complexes. Indicate any cis, trans, and optical isomers.
\(\begin{aligned}{}(a)\left( {Pt{{\left( {{H_2}O} \right)}_2}B{r_2}} \right)\\(b)\left( {Pt\left( {N{H_3}} \right)(py)(Cl)(Br)} \right)\\(c)\left( {Zn{{\left( {N{H_3}} \right)}_3}Cl} \right)\\(d){\left( {Pt{{\left( {N{H_3}} \right)}_3}Cl} \right)^ + }\\(e)\left( {Ni{{\left( {{H_2}O} \right)}_4}C{l_2}} \right)\\(f){\left( {Co{{\left( {{C_2}{O_4}} \right)}_2}C{l_2}} \right)^{3 - }}\end{aligned}\)
Draw diagrams for any cis, trans, and optical isomers that could exist for the following (en is ethylenediamine):
\(\begin{aligned}{}(a){\left( {Co{{(en)}_2}\left( {N{O_2}} \right)Cl} \right)^ + }\\(b){\left( {Co{{(en)}_2}C{l_2}} \right)^ + }\\(c)\left( {Pt{{\left( {N{H_3}} \right)}_2}C{l_4}} \right)\\(d){\left( {Cr{{(en)}_3}} \right)^{3 + }}\\(e)\left( {Pt{{\left( {N{H_3}} \right)}_2}C{l_2}} \right)\end{aligned}\)
A 2.5624-g sample of a pure solid alkali metal chloride is dissolved in water and treated with excess silver nitrate. The resulting precipitate, filtered and dried, weighs 3.03707 g. What was the percent by mass of chloride ion in the original compound? What is the identity of the salt?
The solid anhydrous solid \(CoC{l_2}\)is blue in color. Because it readily absorbs water from the air, it is used as a humidity indicator to monitor if equipment (such as a cell phone) has been exposed to excessive levels of moisture. Predict what product is formed by this reaction, and how many unpaired electrons this complex will have.
Would you expect the complex \(\left( {Co{{(en)}_3}} \right)C{l_3}\) to have any unpaired electrons? Any isomers?
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