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How many cubic feet of air at a pressure of 760 torr and 0 掳C is required per ton of \(F{e_2}{O_3}\)to convert that \(F{e_2}{O_3}\)into iron in a blast furnace? For this exercise, assume air is 19% oxygen by volume.

Short Answer

Expert verified

Hence, we need \({3.53.10^{ - 5}}f{t^3}\)of air to convert \(F{e_2}{O_3}\)to iron in a blast furnance.

Step by step solution

01

solving using ideal equation:

We need an ideal gas equation:

\(p \cdot V = n \cdot R \cdot T\)


where p is pressure, V volume, n number of moles, T temperature of gas and R is a gas constant which is \(8.314\frac{J}{{Kmol}}\)

we get,

\(V = \frac{{n \cdot R \cdot T}}{p}\)

Convert pressure from torr to pascal = 101325 Pa

The reaction occurs is,

\(\begin{aligned}{}2C + {O_2} \to 2CO\\F{e_2}{O_3} + 3CO \to 2Fe + 3C{O_2}\\\frac{{n(F{e_2}{O_3})}}{{n(CO)}} &= \frac{1}{3}\\n(CO) = 3.n(F{e_2}{O_3})\end{aligned}\)

Calculating moles of \(F{e_2}{O_3}\)from a simple formula:

\(\begin{aligned}{}n(CO) &= 3.n(F{e_2}{O_3})\\n(F{e_2}{O_3}) &= \frac{{9.07 \cdot {{10}^5}}}{{159.69gmo{l^{ - 1}}}}\\n(F{e_2}{O_3}) &= 5.68 \cdot {10^3}mol\end{aligned}\)

02

Calculating the moles of oxygen:

We get,

\(\begin{aligned}{}n(CO) &= 3.n(F{e_2}{O_3})\\n(CO) &= 3 \cdot 5.68 \cdot {10^3}mol\\n(CO) &= 17.04 \cdot {10^3}mol\\\\\frac{{n({O_2})}}{{n(CO)}} &= \frac{1}{2}\\n({O_2}) &= \frac{1}{2}.n(CO)\\n({O_2}) &= \frac{1}{2}{.17.04.10^3}mol\\n({O_2}) &= {8.52.10^3}mol\end{aligned}\)

03

Calculating the volume oxygen:

Volume of oxygen:

\(\begin{aligned}{}V({O_2}) &= \frac{{n.R.T}}{p}\\V({O_2}) &= \frac{{{{8.52.10}^3}mol.8.134\frac{J}{{kmol}}.273.15K}}{{101325Pa}}\\V({O_2}) &= 190.97{m^3} &= 190970d{m^3}\end{aligned}\)

We have 19% of oxygen in the air it means we have 19\(c{m^3}\)of oxygen in 100\(c{m^3}\)of air

\(\begin{aligned}{}V(air) &= \frac{{100c{m^3}(air)}}{{19c{m^3}({O_2})}}{.1.92.10^8}c{m^3}({O_2})\\V(air) &= {1.10^9}c{m^3} &= {3.53.10^4}f{t^3}\\1c{m^3} &= {3.53.10^{ - 5}}f{t^3}\end{aligned}\)

Hence, we need \({3.53.10^{ - 5}}f{t^3}\)of air to convert \(F{e_2}{O_3}\)to iron in a blast furnance.

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Most popular questions from this chapter

Give the coordination numbers and write the formulas for each of the following, including all isomers where appropriate:

(a) tetrahydroxozincate(II) ion (tetrahedral)

(b) hexacyanopalladate(IV) ion

(c) dichloroaurate(I) ion (note that aurum is Latin for 鈥済old鈥)

(d) diamminedichloroplatinum(II)

(e) potassium diamminetetrachlorochromate(III)

(f) hexaamminecobalt(III) hexacyanochromate(III)

(g) dibromobis(ethylenediamine) cobalt(III) nitrate

Give the coordination number for each metal ion in the following compounds:

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A 2.5624-g sample of a pure solid alkali metal chloride is dissolved in water and treated with excess silver nitrate. The resulting precipitate, filtered and dried, weighs 3.03707 g. What was the percent by mass of chloride ion in the original compound? What is the identity of the salt?

Trimethylphosphine, \(P{\left( {C{H_3}} \right)_3}\) can act as a ligand by donating the lone pair of electrons on the phosphorus atom. If trimethylphosphine is added to a solution of nickel \(\left( {II} \right)\) chloride in acetone, a blue compound that has a molecular mass of approximately \(270 g\) and contains \(21.5\% Ni,26.0\% Cl,\)and \(52.5\% P{\left( {C{H_3}} \right)_3}\) can be isolated. This blue compound does not have any isomeric forms. What are the geometry and molecular formula of the blue compound?

Give the oxidation state of the metal, number of \(d\)electrons, and the number of unpaired electrons predicted for \(\left( {Co{{\left( {N{H_3}} \right)}_6}} \right)C{l_3}. \)

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