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A cylinder of \({{\bf{O}}_2}\)(g) used in breathing by emphysema patients has a volume of \({\bf{3}}.{\bf{00}}\)L at a pressure of 10.0 atm. If the temperature of the cylinder is \({\bf{28}}.{\bf{0}}{\rm{ }}^\circ {\bf{C}}\), what mass of oxygen is in the cylinder?

Short Answer

Expert verified

Mass \(\left( m \right) = 38.8\) grams of oxygen is in the cylinder

Step by step solution

01

Definition volume

A substance's volume is the amount of space it occupies.

02

Define density

Let us solve the given problem.

We have,

\(PV = nRT\)

where,

\(P = \)pressure of the gas.

\(V = \)volume of the gas.

\(n = \)number of moles of the gas.

\(T = \)temperature of the gas.

\(R = \)Ideal gas constant

\( = 0.08206L{\rm{ atm mo}}{{\rm{l}}^{ - 1}}{K^{ - 1}}\)

If, amount of the gas \((n)\)is in moles, temperature \((T)\) is in Kelvin \((K)\), pressure \((P)\)is in atm.

\(\begin{aligned}{}\frac{P}{{RT}}& = \frac{n}{V}\\\frac{{P \cdot (\mu )}}{{RT}} &= \frac{{n \cdot (\mu )}}{V}\\\frac{{P \cdot (\mu )}}{{RT}} &= \frac{m}{V}\\\frac{{P \cdot (\mu )}}{{RT}} &= \rho {\rm{ }}\\{\rm{Density }}(\rho ) &= \frac{{P \cdot (\mu )}}{{RT}}\end{aligned}\)

where \(\mu = \)molar mass.

03

Convert he temperature

Consider the given information.

Volume \((V) = 3L\).

Pressure \((P) = 10{\rm{kPa}}\).

Temperature \((T) = {28^\circ }C\).

Molar mass \((\mu )\)of \({{\bf{O}}_2}\)

Atomic weight of Carbon \((O) = 16\) grams.

So, molecular weight of \({{\rm{O}}_2} = (2) \cdot (16)\) grams.

\( = 32\)grams.

Molar mass of \({{\rm{O}}_2} = 32\frac{{{\rm{ gram }}}}{{{\rm{mol}}}}\).

Converting the temperature in degree Celsius to kelvins.

We have, \({0^\circ } = (0) + 273.15K\)

So,

\(\begin{aligned}{}{28^\circ }C = (28) + 273.15K\\ = 301.15K\end{aligned}\)

04

Calculate the mass

First find the density.

\(\begin{aligned}{}{\mathop{\rm Density}\nolimits} (\rho ) &= \frac{{P \cdot (\mu )}}{{RT}}\\ &= \frac{{(10) \cdot (32)}}{{(0.08206) \cdot (301.15)}}\\ &= \frac{{320}}{{24.712}}\\ &= 12.94\frac{{{\mathop{\rm gram}\nolimits} }}{L}\end{aligned}\)

We know that,

\(\begin{aligned}{}\rho = \frac{m}{V}\;\\{\rm{m}} = \rho \cdot V\end{aligned}\)

Where,

\(\begin{aligned}{}\rho &= {\rm{ density }}\\m &= {\rm{ mass }}\\V &= {\rm{ Volume }}\\{\mathop{\rm mass}\nolimits} (m) &= \rho \cdot V\\ &= (12.94) \cdot (3)\\ &= 38.8{\rm{ grams}}\end{aligned}\)

Therefore, mass \(\left( m \right) = 38.8\)grams.

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Most popular questions from this chapter

While resting, the average\({\rm{70 - kg}}\)human male consumes \(14\;{\rm{L}}\) of pure \({{\rm{O}}_2}\) per hour at \({25^\circ }{\rm{C}}\)and \({\rm{100 kPa}}\). How many moles of \({{\rm{O}}_2}\)are consumed by a \({\rm{70\;kg}}\)man while resting for \({\rm{1}}{\rm{.0\;h}}\)?

The chlorofluorocarbon CCl2F2 can be recycled into a different compound by reaction with hydrogen to produce CH2F2(g), a compound useful in chemical manufacturing: CCl2F2 (g) + 4H2 (驳)鉄禖贬2F2 (g) + 2HCl(g)

(a) Outline the steps necessary to answer the following question: What volume of hydrogen at 225 atm and 35.5 掳C would be required to react with 1 ton (1.000 脳 103 kg) of CCl2F2?

(b) Answer the question

Question: Describe what happens to the average kinetic energy of ideal gas molecules when the conditions are changed as follows:

(a) The pressure of the gas is increased by reducing the volume at constant temperature.

(b) The pressure of the gas is increased by increasing the temperature at constant volume.

(c) The average velocity of the molecules is increased by a factor of \({\rm{2}}\).

Ethanol, C2H5OH,is produced industrially from ethylene, C2H4, by the following sequence of reactions:

\begin{aligned}{\rm{3}}{{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{4}}}{\rm{+2}}{{\rm{H}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\to{{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{5}}}{\rm{HS}}{{\rm{O}}_{\rm{4}}}{\rm{+(}}{{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{5}}}{{\rm{)}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\\{{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{5}}}{\rm{HS}}{{\rm{O}}_{\rm{4}}}{\rm{ +(}}{{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{5}}}{{\rm{)}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}{\rm{+3}}{{\rm{H}}_{\rm{2}}}{\rm{O}}\to{\rm{3}}{{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{5}}}{\rm{OH + 2}}{{\rm{H}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}} \end{aligned}

What volume of ethylene at STP is required to produce 1000 metric tons (1000kg) of ethanol if the overall yield of ethanol is 90.1%?

One way to state Boyle鈥檚 law is 鈥淎ll other things being equal, the pressure of a gas is inversely proportional to its volume.鈥 (a) What is the meaning of the term 鈥渋nversely proportional?鈥 (b) What are the 鈥渙ther things鈥 that must be equal?

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