/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q101E Question: Under which of the fol... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

Question: Under which of the following sets of conditions does a real gas behave most like an ideal gas, and for which conditions is a real gas expected to deviate from ideal behaviour? Explain.

(a) high pressure, small volume

(b) high temperature, low pressure

(c) low temperature, high pressure

Short Answer

Expert verified

In the conditions specified in part (b), a real gas acts ideally, but in the conditions described in parts (a) and (c), it deviates from ideal behaviour (c).

Step by step solution

01

Step 1: Define Gas

One of the four fundamental states of matter, a gas is made up of particles with no definite volume or structure.

02

Explanation for the parts

(a) When the pressure is high and the volume is small, the gas molecules collide more often with each other and the container walls, increasing the pressure exerted by the gas molecules in comparison to an ideal gas. Under these conditions, a real gas is likely to vary from ideal behaviour.

(b) The gas molecules are widely apart and have a large kinetic energy at high temperature and low pressure. Collisions are less common, there is less attraction between molecules, and there is less contact between molecules. So, under these conditions, a true gas would behave perfectly.

(c) As, the gas molecules have a smaller KE than the attractive forces at low temperatures and high pressures, they are less successful in resisting these attractions after colliding with one another. As a result, under these conditions, actual gas is predicted to depart from ideal behaviour.

Therefore, In the conditions specified in (b), a real behave gas behaves perfectly, but in the situations described in (a) and (c).

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

A litre of methane gas, \({\rm{C}}{{\rm{H}}_4}\), at STP contains more atoms of hydrogen than does a litre of pure hydrogen gas, \({{\rm{H}}_2}\), at STP. Using Avogadro's law as a starting point, explain why.

The effect of chlorofluorocarbons (such as \({\rm{CC}}{{\rm{l}}_2}\;{{\rm{F}}_2}\) ) on the depletion of the ozone layer is well known. The use of substitutes, such as \({\rm{C}}{{\rm{H}}_3}{\rm{C}}{{\rm{H}}_2}\;{\rm{F}}(g)\), for the chlorofluorocarbons, has largely corrected the problem. Calculate the volume occupied by \(10.0\;{\rm{g}}\)of each of these compounds at STP:

(a) \({\rm{CC}}{{\rm{l}}_2}\;{{\rm{F}}_2}(g)\)

(b) \({\rm{C}}{{\rm{H}}_3}{\rm{C}}{{\rm{H}}_2}\;{\rm{F}}(g)\)

A sample of gas isolated from unrefined petroleum contains \({\rm{90}}{\rm{.0\% C}}{{\rm{H}}_{\rm{4}}}{\rm{, 8}}{\rm{.9\% }}{{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{6}}}{\rm{, and 1}}{\rm{.1\% }}{{\rm{C}}_{\rm{3}}}{{\rm{H}}_{\rm{8}}}\) at a total pressure of\({\rm{307}}{\rm{.2 kPa}}\). What is the partial pressure of each component of this gas? (The percentages given indicate the percent of the total pressure that is due to each component.)

For a given amount of gas showing ideal behaviour, draw labelled graphs of:

(a) The variation of\(P\)with\(V\)

(b) The variation of \(V\)with\(T\)

(c) The variation of \(P\)with\(T\)

(d) The variation of \(\frac{1}{P}\)with\(V\)

Methanol,CH3OH, is produced industrially by the following reaction:

Assuming that the gases behave as ideal gases, find the ratio of the total volume of the reactants to the final volume.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.