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Complete the changes in concentrations (or pressure, if requested) for each of the following reactions.


Short Answer

Expert verified

a)

2H2(g) + O2 (g) ⇌ 2H2O (g)

Change in concentration

-2X

-X

+2X

Change in concentration

-1.50M

1.50M/2 =0.75M

1.50M

b)

CS2 (g) +4H2(g)⇌ CH4 (g) 2H2S(g)

Change in concentration

\[{\rm{+x}}\]

\[+4{\rm{x}}\]

\[-{\rm{x}}\]

\[-2{\rm{x}}\]

Change in concentration

\[0.020{\rm{M}}\]

\[0.020M\cdot4=0.080{\rm{M}}\]

\[-0.020{\rm{M}}\]

\[-0.020M \cdot 2=-0.040{\rm{M}}\]

c)

H2 (g) + cl2 (g)⇌ 2HCl (g)

Change in concentration

+x

+x

-2x

Change in concentration

1.50M

1.50M

-1.50M.2=-3.00M

d)

2NH3(g) + 2O2(g)⇌ N2O (g) 3H2 O(g)

Change in concentration

\[-\frac{{2x}}{3}\]

\[-\frac{{2x}}{3}\]

\[+\frac{x}{3}\]

\[+x\]

Change in concentration

\[-\frac{{60.6{\rm{\;torr\;}}2}}{3}=-40.4{\rm{\;torr\;}}\]

\[-\frac{{60.6{\rm{\;torr\;}}\cdot 2}}{3}=-40.4{\rm{\;torr\;}}\]

\[+\frac{{60.6{\rm{\;torr\;}}}}{3}=+20.2{\rm{\;torr\;}}\]

\[60.6{\rm{\;torr\;}}\]

e)

NH4HS(s)⇌ NH3 (g) + H2S (g)

Change in concentration

\[+{\rm{x}}\]

\[+x\]

Change in concentration

\[9.8\cdot{10^{-6}}{\rm{M}}\]

\[9.8\cdot{10^{-6}}{\rm{M}}\]

f)

Fe(S) + 5CO(g)⇌ Fe(CO)4(g)

Change in concentration

\[{\rm{ - 5x}}\]

\[ + x\]

Change in concentration

\[ - 0.012{\rm{atm}} \cdot 5 = - 0.06{\rm{atm}}\]

\[0.012{\rm{atm}}\]

Step by step solution

01

Definition of change in concentration

The rate of a chemical reaction is defined as the rate of change in concentration of a reactant or product divided by its coefficient from the balanced equation.

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Most popular questions from this chapter

Pure iron metal can be produced by the reduction of iron(III) oxide with hydrogen gas.

(a) Write the expression for the equilibrium constant \(\left( {{K_c}} \right.)\)for the reversible reaction

\(F{e_2}{O_3}(s) + 3{H_2}(g) \rightleftharpoons 2Fe(s) + 3{H_2}O(g)\) \(\Delta H = 98.7kJ\)

(b) What will happen to the concentration of each reactant and product at equilibrium if more \(Fe\)is added?

(c) What will happen to the concentration of each reactant and product at equilibrium if \({H_2}O\) is removed?

(d) What will happen to the concentration of each reactant and product at equilibrium if \({H_2}\) is added?

(e) What will happen to the concentration of each reactant and product at equilibrium if the pressure on the system is increased by reducing the volume of the reaction vessel?

(f) What will happen to the concentration of each reactant and product at equilibrium if the temperature of the system is increased?

Write the mathematical expression for the reaction quotient, \({Q_c}\), for each of the following reactions:

(a) \({N_2}(g) + 3{H_2}(g) \rightleftharpoons 2N{H_3}(g)\)

(b) \(4N{H_3}(g) + 5{O_2}(g) \rightleftharpoons 4NO(g) + 6{H_2}O(g)\)

(c) \({N_2}{O_4}(g) \rightleftharpoons 2N{O_2}(g)\)

(d) \(C{O_2}(g) + {H_2}(g) \rightleftharpoons CO(g) + {H_2}O(g)\)

(e) \(N{H_4}Cl(s) \rightleftharpoons N{H_3}(g) + HCl(g)\)

(f) \(2\;Pb{\left( {N{O_3}} \right)_2}(s) \rightleftharpoons 2PbO(s) + 4N{O_2}(g) + {O_2}(g)\)

(g) \(2{H_2}(g) + {O_2}(g) \rightleftharpoons 2{H_2}O(l)\)

(h) \({S_8}(g) \rightleftharpoons 8\;S(g)\)

Question: A reaction is represented by this equation: \({K_c} = 1 \times 1{0^3}\)

(a) Write the mathematical expression for the equilibrium constant.

Calculate the number of moles of \(HI\) that are at equilibrium with \(1.25mol\)of \({H_2}\)and \(1.25\,mol\)of \({I_2}\) in a \(5.00\,L\)flask at \(44{8^0}C\).\({H_2} + {I_2} \rightleftharpoons 2HI\)

\({K_c} = 50.2\,at\,44{8^o}C\)

What is the pressure of \(C{O_2}\)in a mixture at equilibrium that contains \(0.50atm\)\({H_2}\), \(2.0atm\)of \({H_2}O\), and \(1.0atm\)of \(CO\) at \(99{0^0}C\)?

\({H_2}(g) + C{O_2}(g) \rightleftharpoons {H_2}O(g) + CO(g)\)

\({K_P} = 1.6\,at\, 99{0^o}C\)

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