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Complete the changes in concentrations (or pressure, if requested) for each of the following reactions.

Short Answer

Expert verified

a)

2SO3(g) (g)⇌ 2HO2(g)+ O2(g)

Change in concentration

\[ - 2x\]

\[ + 2x\]

\[ + x\]

Change in concentration

\[ - 0.125 \cdot 2 = - 0.250M\]

\[ + 0.125 \cdot 2 = + 0.250M\]

\[ + 0.125{\rm{M}}\]

b)

4NH3(g) + 3O2(g)⇌ 2N2O (g) 6H2 O(g)

Change in concentration

\[ + 4x\]

\[ + 3x\]

\[ - 2x\]

$ + 6x$

Change in concentration

\[\frac{{0.24M}}{3} \cdot 4 = + 0.32M\]

\[ + 0.24{\rm{M}}\]

\[ - \frac{{0.24M}}{3} \cdot 2 = - 0.16M\]

\[ - \frac{{0.24M}}{3} \cdot 6 = - 0.48M\]

c)

2CH4 (g)⇌ C2H2 (g) 3H2(g)

Change in concentration

\[ - 2x\]

\[ + x\]

\[ + 3x\]

Change in concentration

\[ - 25 \cdot 2 = - 50{\rm{\;torr\;}}\]

\[25{\rm{\;torr\;}}\]

\[ + 25{\rm{\;torr\;}} \cdot 3 = + 75{\rm{\;torr\;}}\]

d)

CH4 (g) + H2O(g)⇌ CO(g)

Change in concentration

\[ + x\]

\[ + x\]

\[ - x\]

$ - 3x$

Change in concentration

\[ + 5atm\]

\[5{\rm{atm}}\]

\[ - 5atm\]

\[ - 5{\rm{atm}} \cdot 3 = - 15{\rm{atm}}\]

e)

NH4°ä±ô(²õ)⇌N±á3(g) + HCl (g)

Change in concentration

\[ + x\]

\[ + x\]

Change in concentration

\[1.03 \cdot {10^{ - 4}}{\rm{M}}\]

\[ + 1.03 \cdot {10^{ - 4}}{\rm{M}}\]

f)

Ni (s) + 4CO (g)⇌Ni(CO)4 (g)

Change in concentration

\[ + 4x\]

\[ - x\]

Change in concentration

\[0.40atm\]

\[ - \frac{{0.40{\rm{atm}}}}{4} = - 0.10{\rm{atm}}\]

Step by step solution

01

Definition of change in concentration

The rate of a chemical reaction is defined as the rate of change in concentration of a reactant or product divided by its coefficient from the balanced equation.

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Most popular questions from this chapter

Question:Calculate the value of the equilibrium constant \({K_P}\) for the reaction \(2NO(g) + C{l_2}(g) \rightleftharpoons 2NOCl(g)\) from these equilibrium pressures: NO, \(0.050atm;C{l_2},0.30atm;NOCl,1.2atm\)

Question: Antimony pentachloride decomposes according to this equation:

An equilibrium mixture in a 5.00-L flask at 4480C contains 3.85 g of \({\rm{SbC}}{{\rm{l}}_5}\),9.14 g of \({\rm{SbC}}{{\rm{l}}_3}\)and 2.84 g of \({\rm{C}}{{\rm{l}}_2}\).How many grams of each will be found if the mixture is transferred into a 2.00-L flask at the same temperature?

Calculate the pressures of all species at equilibrium in a mixture of NOCl, NO, and Cl2produced when a sample of NOCl with a pressure of 10.0 atm comes to equilibrium according to this reaction:

\(2NOCl(g) \rightleftharpoons 2NO(g) + C{l_2}(g)\quad {K_P} = 4.0 \times 1{0^{ - 4}}\)

A sample of ammonium chloride was heated in a closed container. NH4 Cl (s)⇌ NH3 (g) + HCl(g)at equilibrium, the pressure of NH3 (g)was found to be 1.75 atm. What is the value of the equilibrium constant, Kp, for the decomposition at this temperature?

A student solved the following problem and found \(\left[ {{N_2}{O_4}} \right] = 0.16M\)at equilibrium. How could this student recognize that the answer was wrong without reworking the problem? The problem was: What is the equilibrium concentration of \(\left[ {{N_2}{O_4}} \right]\) in a mixture formed from a sample of \(N{O_2}\) with a concentration of \(0.10M\)?

\(2N{O_2}(g) \rightleftharpoons {N_2}{O_4}(g)\)

\({K_c} = 160\)

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