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Write the reaction quotient expression for the ionization of NH3 in water:

Short Answer

Expert verified

The reaction quotient expression for the ionization of NH3 in water:

\({Q_c} = \frac{{c\left( {NH_4^ + } \right) \cdot c\left( {O{H^ - }} \right)}}{{c\left( {N{H_3}} \right) \cdot 1}}\).

Step by step solution

01

The reaction regarding the ionization of NH3 in water:

The reaction of dissociation of\({\rm{N}}{{\rm{H}}_3}\)is:

\({\rm{N}}{{\rm{H}}_3}(aq) + {{\rm{H}}_2}{\rm{O}}(l) \to {\rm{NH}}_4^ + (aq) + O{{\rm{H}}^ - }(aq)\)

(Note, there needs to be double arrow, because this is a reverse reaction).

02

The reaction quotient expression for the ionization of NH3 in water:

Equation for reaction quotient is the same as for equilibrium constant, but we don't use equilibrium concentrations, but concentrations in any time before equilibrium.

\({Q_c} = \frac{{c\left( {NH_4^ + } \right) \cdot c\left( {O{H^ - }} \right)}}{{c\left( {N{H_3}} \right)}}\)

Water is not included into the equation because it is liquid and its activity is 1,

so, it would be like this:

\({Q_c} = \frac{{c\left( {NH_4^ + } \right) \cdot c\left( {O{H^ - }} \right)}}{{c\left( {N{H_3}} \right) \cdot 1}}\).

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Most popular questions from this chapter

The following reaction has \({K_P} = 4.50 \times {10^{ - 5}}\) at \(720\;{\rm{K}}\).

\({{\rm{N}}_2}(g) + 3{{\rm{H}}_2}(g) \rightleftharpoons 2{\rm{N}}{{\rm{H}}_3}(g)\)

If a reaction vessel is filled with each gas to the partial pressures listed, in which direction will it shift to reach equilibrium?

\(P\left( {{\rm{N}}{{\rm{H}}_3}} \right) = 93\;{\rm{atm}},\;P\left( {\;{{\rm{N}}_2}} \right) = 48\;{\rm{atm}},\;{\rm{and}}\;P\left( {{{\rm{H}}_2}} \right) = 52\)

Pure iron metal can be produced by the reduction of iron(III) oxide with hydrogen gas.

(a) Write the expression for the equilibrium constant \(\left( {{K_c}} \right.)\)for the reversible reaction

\(F{e_2}{O_3}(s) + 3{H_2}(g) \rightleftharpoons 2Fe(s) + 3{H_2}O(g)\) \(\Delta H = 98.7kJ\)

(b) What will happen to the concentration of each reactant and product at equilibrium if more \(Fe\)is added?

(c) What will happen to the concentration of each reactant and product at equilibrium if \({H_2}O\) is removed?

(d) What will happen to the concentration of each reactant and product at equilibrium if \({H_2}\) is added?

(e) What will happen to the concentration of each reactant and product at equilibrium if the pressure on the system is increased by reducing the volume of the reaction vessel?

(f) What will happen to the concentration of each reactant and product at equilibrium if the temperature of the system is increased?

What are all concentrations after a mixture that contains \(\left[ {{{\bf{H}}_{\bf{2}}}{\bf{O}}} \right] = {\bf{1}}.{\bf{00Mand}}\left[ {{\bf{C}}{{\bf{l}}_{\bf{2}}}{\bf{O}}} \right] = {\bf{1}}.{\bf{00M}}\) comes to equilibrium at \({\bf{25}}^\circ {\bf{C}}\)?

\({{\mathbf{H}}_{\mathbf{2}}}{\mathbf{O}}(g) + {\mathbf{C}}{{\mathbf{l}}_{\mathbf{2}}}{\mathbf{O}}(g) \rightleftharpoons {\mathbf{2HOCl}}(g);\;{\mathbf{Kc}} = {\mathbf{0}}.{\mathbf{0900}}\)

A student solved the following problem and found the equilibrium concentrations to be \(\left[ {S{O_2}} \right] = 0.590M\), \(\left[ {{O_2}} \right] = 0.0450M\), and \(\left[ {S{O_3}} \right] = 0.260M\). How could this student check the work without reworking the problem? The problem was: For the following reaction at \(60{0^0}C\):

\(2S{O_2}(g) + {O_2}(g) \rightleftharpoons 2S{O_3}(g)\)

\({K_c} = 4.32\)

What are the equilibrium concentrations of all species in a mixture that was prepared with \(\left[ {S{O_3}} \right] = 0.500M\), \(\left[ {S{O_2}} \right] = 0M\)and \(\left[ {{O_2}} \right] = 0.350M\)?

What property of a reaction can we use to predict the effect of a change in temperature on the value of an equilibrium constant?

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