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Calculate the concentration of PO43-when Ag3 PO4 starts to precipitate from a solution that is 0.0125M in Ag+.

Short Answer

Expert verified

The value of [PO43-±Õ=9.22×10-16M

Step by step solution

01

Define concentration

The concentration is the abundance of a constituent divided by the total volume of a mixture. Several types of mathematical descriptions can be distinguished: mass concentration, molar concentration, number concentration, and volume concentration.

02

Calculate the concentration

Precipitation of PO43-will begins when the ion product value is higher than solubility product constant value of Ag3 PO4

\[{K_{sp}}=1.8\times{10^{-18}}={\left[{A{g^+}}\right]^3}\left[{PO_4^{3-}}\right]=\left[{PO_4^{3-}}\right]\left({{{0.0125}^3}}\right)\]

\[\left[{PO_4^{3-}}\right]=\frac{{1.8 \times{{10}^{-18}}}}{{{{0.0125}^3}}}=9.22\times{10^{-16}}M\]

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