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Which atoms can bond to sulfur so as to produce a positive partial charge on the sulfur atom?

Short Answer

Expert verified

The atoms than can bond to sulfur to produce a positive partial charge on the sulfur atom are: \({\rm{N,O,F}}\) and \({\rm{Cl}}\).

Step by step solution

01

Define Chemical Bonding

A chemical bond is a long-term attraction between atoms, ions, or molecules that allows chemical compounds to form.

02

Explanation

A neighboring atom must have a greater electronegativity than sulphur in order to produce a positive charge on Sulfur.

A few things to keep in mind:

(1) As you travel from left to right in the periodic table, the size of the atom shrinks because proton addition has a greater effect than electron addition. Because of the strong force of the nucleus, it will be able to receive electrons more easily as its size decreases.

According to the foregoing argument, electronegativity rises as one moves from left to right in the periodic table.

(2) As you proceed from the top to the bottom of a group, the size of the group grows due to the addition of fresh energy shells. Because the force of attraction of the nucleus is no longer able to attract additional electrons as the size of the nucleus rises, electronegativity will drop as the group size decreases.

So, according to the previous argument, only four elements are more electronegative than sulphur:\({\rm{N,O,F}}\), and\({\rm{Cl}}\).

Therefore, the elements are: \({\rm{N,O,F}}\) and \({\rm{Cl}}\) .

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Most popular questions from this chapter

For which of the following substances is the least energy required to convert one mole of the solid into separate ions?

(a) \({\rm{MgO}}\)

(b) \({\rm{SrO}}\)

(c) \({\rm{KF}}\)

(d) \({\rm{CsF}}\)

(e) \({\rm{Mg}}{{\rm{F}}_{\rm{2}}}\)

Use the simulation (http://openstaxcollege.org/l/16MolecPolarity) to perform the following exercises for a two-atom molecule: (a) Adjust the electronegativity value so the bond dipole is pointing toward B. Then determine what the electronegativity values must be to switch the dipole so that it points toward A. (b) With a partial positive charge on A, turn on the electric field and describe what happens. (c) With a small partial negative charge on A, turn on the electric field and describe what happens. (d) Reset all, and then with a large partial negative charge on A, turn on the electric field and describe what happens.

What information can you use to predict whether a bond between two atoms is covalent or ionic?

Describe the molecular structure around the indicated atom or atoms:

  1. The sulfur atom in sulfuric acid, H2SO4 [ (HO)2 SO2]

  2. The chlorine atom in chloric acid, HClO3 [HOClO2]

  3. The oxygen atom in Hydrogen peroxide, HOOH

  4. The nitrogen atom in nitric acid, HNO3 [HONO2]

  5. The oxygen atom in OH group in nitric acid, HNO3 [HONO2]

  6. The central oxygen atom in the ozone molecule, O3

  7. Each of the carbon atoms in the propyne, CH3 CCH

  8. The carbon atom in Freon, CCl2 F2

  9. each of the carbon atoms in allene H2CCCH2

Calculate the formal charge of chlorine in the molecules \({\rm{C}}{{\rm{l}}_{\rm{2}}}\), \({\rm{BeC}}{{\rm{l}}_{\rm{2}}}\), and \({\rm{Cl}}{{\rm{F}}_{\rm{5}}}\).

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