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Predict which of the following compounds are ionic and which are covalent, based on the location of their constituent atoms in the periodic table:

(a) \({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{CO}}\) (b) \({\rm{MnO}}\) (c) \({\rm{NC}}{{\rm{l}}_{\rm{3}}}\) (d) \({\rm{CoB}}{{\rm{r}}_{\rm{2}}}\) (e) \({{\rm{K}}_{\rm{2}}}{\rm{S}}\) (f) \({\rm{CO}}\) (g) \({\rm{Ca}}{{\rm{F}}_{\rm{2}}}\) (h) \({\rm{HI}}\) (i) \({\rm{CaO}}\) (j) \({\rm{IBr}}\) (k) \({\rm{C}}{{\rm{O}}_{\rm{2}}}\) .

Short Answer

Expert verified

The ionic compounds are: \({\rm{MnO, CoB}}{{\rm{r}}_{\rm{2}}}{\rm{, }}{{\rm{K}}_{\rm{2}}}{\rm{S, Ca}}{{\rm{F}}_{\rm{2}}}\) and \({\rm{CaO}}\).

The covalent compounds are: \({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{CO, NC}}{{\rm{l}}_{\rm{3}}}{\rm{, CO, HI, IBr}}\) and \({\rm{C}}{{\rm{O}}_{\rm{2}}}\).

Step by step solution

01

Define Chemical Bonding 

A chemical bond is a long-term attraction between atoms, ions, or molecules that allows chemical compounds to form.

02

Predicting that the ions are ionic or covalent?

Based on the location of the elements in the periodic table: If the elements in a compound are close to one another in the periodic table, the bond is more likely to be covalent, but if the elements are far apart, the bond is more likely to be ionic.

Now, based on the above reasoning, we may conclude that:

Ionic compounds include\({\rm{MnO, CoB}}{{\rm{r}}_{\rm{2}}}{\rm{, }}{{\rm{K}}_{\rm{2}}}{\rm{S, Ca}}{{\rm{F}}_{\rm{2}}}\), and\({\rm{CaO}}\), whereas covalent compounds include\({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{CO, NC}}{{\rm{l}}_{\rm{3}}}{\rm{, CO, HI, IBr}}\), and\({\rm{C}}{{\rm{O}}_{\rm{2}}}\).

Therefore, Ionic include \({\rm{MnO, CoB}}{{\rm{r}}_{\rm{2}}}{\rm{, }}{{\rm{K}}_{\rm{2}}}{\rm{S, Ca}}{{\rm{F}}_{\rm{2}}}\), and \({\rm{CaO}}\), as well as covalent compounds are \({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{CO, NC}}{{\rm{l}}_{\rm{3}}}{\rm{, CO, HI, IBr}}\), and \({\rm{C}}{{\rm{O}}_{\rm{2}}}\).

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Most popular questions from this chapter

Which of the following compounds requires the most energy to convert one mole of the solid into separate ions?

(a) \({\rm{MgO}}\)

(b) \({\rm{SrO}}\)

(c) \({\rm{KF}}\)

(d) \({\rm{CsF}}\)

(e) \({\rm{Mg}}{{\rm{F}}_{\rm{2}}}\)

Which compound in each of the following pairs has the larger lattice energy? Note: \({\rm{M}}{{\rm{g}}^{{\rm{2 + }}}}\) and \({\rm{L}}{{\rm{i}}^{\rm{ + }}}\) have similar radii; \({{\rm{O}}^{{\rm{2 - }}}}\) and \({{\rm{F}}^{\rm{ - }}}\) have similar radii. Explain your choices.

(a) \({\rm{MgO}}\) or \({\rm{MgSe}}\)

(b) \({\rm{LiF}}\) or \({\rm{MgO}}\)

(c) \({\rm{L}}{{\rm{i}}_{\rm{2}}}{\rm{O}}\) or \({\rm{LiCl}}\)

(d) \({\rm{L}}{{\rm{i}}_{\rm{2}}}{\rm{Se}}\) or \({\rm{MgO}}\)

Explain the difference between electron-pair geometry and molecular structure.

Question: Using the standard enthalpy of formation data in Appendix G, determine which bond is stronger: the \({\rm{S - F}}\) bond in \({\rm{S}}{{\rm{F}}_{\rm{4}}}{\rm{(g)}}\) or in \({\rm{S}}{{\rm{F}}_{\rm{6}}}{\rm{(g)}}\)?

Question: Using the bond energies in Table \({\rm{7}}{\rm{.2}}\), determine the approximate enthalpy change for each of the following reactions:

(a) \({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{(g) + 3}}{{\rm{F}}_{\rm{2}}}{\rm{(g)}} \to {\rm{2Cl}}{{\rm{F}}_{\rm{3}}}{\rm{(g)}}\)

(b) \({{\rm{H}}_{\rm{2}}}{\rm{C = C}}{{\rm{H}}_{\rm{2}}}{\rm{(g) + }}{{\rm{H}}_{\rm{2}}}{\rm{(g)}} \to {{\rm{H}}_{\rm{3}}}{\rm{CC}}{{\rm{H}}_{\rm{3}}}{\rm{(g)}}\)

(c) \({\rm{2}}{{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{6}}}{\rm{(g) + 7}}{{\rm{O}}_{\rm{2}}}{\rm{(g)}} \to {\rm{4C}}{{\rm{O}}_{\rm{2}}}{\rm{(g) + 6}}{{\rm{H}}_{\rm{2}}}{\rm{O(g)}}\)

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