Chapter 7: Q101E (page 405)
The molecule XF3 has a dipole moment. Is X boron or phosphorus?
Short Answer
The molecular structure of \({\rm{P}}{{\rm{F}}_{\rm{3}}}\)is not symmetrical and hence dipole does not cancels out.
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Chapter 7: Q101E (page 405)
The molecule XF3 has a dipole moment. Is X boron or phosphorus?
The molecular structure of \({\rm{P}}{{\rm{F}}_{\rm{3}}}\)is not symmetrical and hence dipole does not cancels out.
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What feature of a Lewis structure can be used to tell if a molecule’s (or ion’s) electron-pair geometry and molecular structure will be identical?
Question: Using the bond energies in Table \({\rm{7}}{\rm{.2}}\), determine the approximate enthalpy change for each of the following reactions:
(a) \({{\rm{H}}_{\rm{2}}}{\rm{(g) + B}}{{\rm{r}}_{\rm{2}}}{\rm{(g)}} \to {\rm{2HBr(g)}}\)
(b) \({\rm{C}}{{\rm{H}}_{\rm{4}}}{\rm{(g) + }}{{\rm{I}}_{\rm{2}}}{\rm{(g)}} \to {\rm{C}}{{\rm{H}}_{\rm{3}}}{\rm{I(g) + HI(g)}}\)
(c) \({{\rm{C}}_{\rm{2}}}{{\rm{H}}_4}{\rm{(g) + 3}}{{\rm{O}}_{\rm{2}}}{\rm{(g)}} \to {\rm{2C}}{{\rm{O}}_{\rm{2}}}{\rm{(g) + 2}}{{\rm{H}}_{\rm{2}}}{\rm{O(g)}}\)

Which of the following molecules have dipole moments?
From the labels of several commercial products, prepare a list of six ionic compounds in the products. For each compound, write the formula. (You may need to look up some formulas in a suitable reference.)
Predict which of the following compounds are ionic and which are covalent, based on the location of their constituent atoms in the periodic table:
(a) \({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{CO}}\) (b) \({\rm{MnO}}\) (c) \({\rm{NC}}{{\rm{l}}_{\rm{3}}}\) (d) \({\rm{CoB}}{{\rm{r}}_{\rm{2}}}\) (e) \({{\rm{K}}_{\rm{2}}}{\rm{S}}\) (f) \({\rm{CO}}\) (g) \({\rm{Ca}}{{\rm{F}}_{\rm{2}}}\) (h) \({\rm{HI}}\) (i) \({\rm{CaO}}\) (j) \({\rm{IBr}}\) (k) \({\rm{C}}{{\rm{O}}_{\rm{2}}}\) .
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