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Chapter 7: Chemical Bonding and Molecular Geometry

Q24 E

Page 393

Many monatomic ions are found in seawater, including the ions formed from the following list of elements. Write the Lewis symbols for the monatomic ions formed from the following elements: (a)\({\rm{CI}}\)(b)\({\rm{Na}}\)(c)\({\rm{Mg}}\)(d)\({\rm{Ca}}\)(e)\({\rm{K}}\)(f)\({\rm{Br}}\)(g)\({\rm{Sr}}\)(h)\({\rm{F}}\).

Q25 E

Page 393

Write the Lewis symbols of the ions in each of the following ionic compounds and the Lewis symbols of the atom from which they are formed: (a) \({\rm{MgS}}\) (b) \({\rm{A}}{{\rm{l}}_{\rm{2}}}{{\rm{O}}_{\rm{3}}}\) (c) \({\rm{GaC}}{{\rm{l}}_{\rm{3}}}\) (d) \({{\rm{K}}_{\rm{2}}}{\rm{O}}\) (e) \({\rm{L}}{{\rm{i}}_{\rm{3}}}{\rm{N}}\) (f) \({\rm{KF}}\) .

Q26 E

Page 394

In the Lewis structures listed here, M and X represent various elements in the third period of the periodic table. Write the formula of each compound using the chemical symbols of each element:

Q27 E

Page 394

Write the Lewis structure for the diatomic molecule \({{\rm{P}}_{\rm{2}}}\), an unstable form of phosphorus found in high temperature phosphorus vapor.

Q29 E

Page 405

Write Lewis structures for the following: (a)\({{\rm{O}}_{\rm{2}}}\)(b)\({{\rm{H}}_{\rm{2}}}{\rm{CO}}\)(c)\({\rm{As}}{{\rm{F}}_{\rm{3}}}\)(d)\({\rm{ClNO}}\)(e)\({\rm{SiC}}{{\rm{l}}_{\rm{4}}}\)(f)\({{\rm{H}}_{\rm{3}}}{{\rm{O}}^{\rm{ + }}}\)(g)\({\rm{N}}{{\rm{H}}_{\rm{4}}}^{\rm{ + }}\)(h)\({\rm{B}}{{\rm{F}}_{\rm{4}}}^{\rm{ - }}\)(i)\({\rm{HCCH}}\)(j)\({\rm{CICN}}\)(k)\({{\rm{C}}_{\rm{2}}}^{{\rm{2 + }}}\).

Q2E

Page 389

Iron(\({\rm{III}}\)) sulfate (\({\rm{F}}{{\rm{e}}_{\rm{2}}}{{\rm{(S}}{{\rm{O}}_{\rm{4}}}{\rm{)}}_{\rm{3}}}\)) is composed of \({\rm{F}}{{\rm{e}}^{{\rm{3 + }}}}\) and \({\rm{S}}{{\rm{O}}_{\rm{4}}}^{{\rm{2 - }}}\) ions. Explain why a sample of iron(\({\rm{III}}\)) sulfate is uncharged.

Q30 E

Page 405

Write Lewis structures for the following: (a) \({\rm{CI}}{{\rm{F}}_{\rm{3}}}\) (b) \({\rm{PC}}{{\rm{I}}_{\rm{5}}}\) (c) \({\rm{B}}{{\rm{F}}_{\rm{3}}}\) (d) \({\rm{P}}{{\rm{F}}_{\rm{6}}}^{\rm{ - }}\) .

Q31 E

Page 395

Write Lewis structures for the following: (a)\({\rm{Se}}{{\rm{F}}_{\rm{6}}}\)(b)\({\rm{Xe}}{{\rm{F}}_{\rm{4}}}\)(c)\({\rm{SeC}}{{\rm{l}}_{\rm{3}}}^{\rm{ + }}\)(d)\({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{BBC}}{{\rm{l}}_{\rm{2}}}\)(contains a\({\rm{B - B}}\)bond).

Q32 E

Page 395

Write Lewis structures for: (a) \({\rm{P}}{{\rm{O}}_{\rm{4}}}^{{\rm{3 - }}}\) (b) \({\rm{IC}}{{\rm{I}}_{\rm{4}}}^{\rm{ - }}\) (c) \({\rm{S}}{{\rm{O}}_{\rm{3}}}^{{\rm{2 - }}}\) (d) \({\rm{HONO}}\) .

Q33 E

Page 395

Correct the following statement: 鈥淭he bonds in solid\({\text{PbC}}{{\text{I}}_{\text{2}}}\)are ionic; the bond in a\({\text{HCl}}\)molecule is covalent. Thus, all of the valence electrons in\({\text{PbC}}{{\text{I}}_{\text{2}}}\)are located on the\({\text{C}}{{\text{I}}^{\text{ - }}}\)ions, and all of the valence electrons in a\({\text{HCl}}\)molecule are shared between the\({\text{H}}\)and\({\text{CI}}\)atoms.鈥

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