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When each of the following pairs of aqueous solutions is mixed, does a precipitation reaction occur? If so, write balanced molecular, total ionic, and net ionic equations:

(a) Sodium nitrate + copper(II) sulfate

(b) Ammonium bromide + silver nitrate

Short Answer

Expert verified

(a) Precipitation reaction does not occur.

(b) A precipitation reaction occurs.

Step by step solution

01

Write the equation of sodium nitrate and copper(II) sulfate

For each pair of solutions, we note the ions present in the reactants, and write the cation-anion combinations if any of them are insoluble or soluble. For the molecular equation, we predict the products

(a)2NaNO3(aq)+CuSO4(aq)Na2SO4(aq)+Cu(NO3)2(aq)

Since these compounds are soluble in aqueous solvent hence this reaction does not give a precipitate.

All ammonium, sodium, and most perchlorate compounds are soluble, and all bromides, nitrates are soluble except those of Ag+, Pb2+, Cu+, and Hg22+

Therefore, the compounds remain dissociated in the solution as solvated ions.

02

Write the equation of ammonium bromide and silver nitrate

For each pair of solutions, we note the ions present in the reactants and write the cation-anion combinations if any of them are insoluble or soluble. For the molecular equation, we predict the products:

The balanced molecular reaction is:

(b)NH4Br(aq)+AgNO3(aq)NH4NO3(aq)+AgBr(s)

The total ionic equation is:

NH4+(aq)+Br-(aq)+Ag+(aq)+NO3-(aq)NH4+(aq)+NO3-(aq)+AgBr(s)

The net ionic equation is:

Ag+(aq)+Br-(aq)AgBr(s)

Since, silver bromide is insoluble in aqueous solution, precipitate is formed.

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