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What is the difference betweenΔ³Ò° andΔ³Ò ? Under what circumstances does Δ³Ò=Δ³Ò°?

Short Answer

Expert verified

Δ³Òo=Δ³Òwhen all concentrations equal 1M and all partial pressures equal 1 atm.

This is due to the fact that the values of Q=1 and lnQ=0 in the following equation,

Δ³Ò=Δ³Òo+RTln(Q)

Where,

R is gas constant

T is the temperature

Δ³Ò is the free energy

Step by step solution

01

Definition of Concept

Solubility: The maximum amount of solute that can be dissolved in the solvent at equilibrium is defined as solubility.

Constant of soluble product: For equilibrium between solids and their respective ions in a solution, the solubility product constant is defined. In general, the term "solubility product" refers to water-equilibrium insoluble or slightly soluble ionic substances.

02

Find the difference between   ΔG°and ΔG

Considering the given information:

When all of the system's components are in their standard states, the standard free energy change Δ³Òooccurs.

The standard state is defined as 1atm for gases, 1M for solutes, and 1M for pure solids and liquids. The term "standard state" does not specify a temperature because it can occur at any temperature.

Δ³Òo=Δ³Òwhen all concentrations equal 1M and all partial pressures equal 1 atm.

This is due to the fact that the values of Q=1 and lnQ=0in the following equation,

Δ³Ò=Δ³Òo+RTln(Q)

Where,

R is gas constant

T is the temperature

Δ³Òis the free energy

Δ³Òois standard free energy.

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