91Ó°ÊÓ

Thermodynamics is the study of the connections between heat, work, temperature, and energy. Thermodynamic principles specify how energy develops within a system and whether it is capable of having a positive impact on its surroundings.

Hydrogen and Iodine combine to generateHI. Write the reaction equation for the creation ofmole ofHIand balance it.

$\frac{1}{2}{\mathrm{H}}_2\left(\mathrm{g}\right)+\frac{1}{2}{\mathrm{I}}_2\left(\mathrm{s}\right)→\mathrm{HI}\left(\mathrm{g}\right)$

After that, make a list of each compound ${\mathrm{Δ³\S }}^{\mathrm{o}}$ values:

$\begin{array}{c}\mathrm{S}°\left({\mathrm{H}}_2\left(\mathrm{g}\right)\right)=130.6\mathrm{J}/\mathrm{mol}\mathrm{K}\\ \mathrm{S}°\left({\mathrm{I}}_2\left(\mathrm{g}\right)\right)=260.58\mathrm{J}/\mathrm{mol}\mathrm{K}\\ \mathrm{S}°\left(\mathrm{HI}\left(\mathrm{g}\right)\right)=206.33\mathrm{J}/\mathrm{mol}\mathrm{K}\end{array}$

Solve for the ${\mathrm{Δ³\S }}^{\mathrm{o}}$now as:

role="math" localid="1663361502945" $\begin{array}{c}\mathrm{Δ³\S }°=∑{\mathrm{n}}_{\mathrm{p}}\mathrm{S}°\left(\mathrm{product}\right)-∑{\mathrm{n}}_{\mathrm{r}}\mathrm{S}°\left(\mathrm{reactant}\right)...........................\left(1\right)\\ =\left[\mathrm{nS}°\left(\mathrm{HI}\left(\mathrm{s}\right)\right)\right]-\left[\mathrm{nS}°({\mathrm{H}}_2\left(\mathrm{s}\right))+\mathrm{nS}°\left({\mathrm{I}}_2\left(\mathrm{g}\right)\right)\right].............................\left(2\right)\\ =\left(\left[1\right(206.33\left)\right]-\left[\frac{1}{2}(130.6)+\frac{1}{2}(116.14)\right]\right)\mathrm{J}/\mathrm{K}...................\left(3\right)\\ \mathrm{Δ³\S }°=82.63\mathrm{J}/\mathrm{K}....................................................................\left(4\right)\end{array}$

Therefore, the value is: $\mathrm{Δ³\S }°=82.63\mathrm{J}/\mathrm{K}$.