/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q22.12P Describe three pathways for the ... [FREE SOLUTION] | 91影视

91影视

Describe three pathways for the utilization of atmospheric nitrogen. Is human activity a significant factor? Explain.

Short Answer

Expert verified

Atmospheric fixation, industrial fixation, and biological fixation are the three methods for removing nitrogen from the atmosphere.

Water contamination is caused by human activities, such as the overuse of fertilisers and automobiles.

Step by step solution

01

Atmosphere

The gases that surround a star or planetary body are held in place by gravity and are referred to as the atmosphere. If gravity is high and the temperature of the atmosphere is low, a body is more likely to keep an atmosphere over time.

02

Explanation

Atmospheric fixation, industrial fixation, and biological fixation are the three methods for utilising atmospheric nitrogen. The following paragraphs detail each procedure.

Human activity is a significant contributor to the overall quantity of fixed nitrogen in the atmosphere. Artificially manufactured nitrogen-based fertiliser (ammonia, urea, ammonium salts) is taken up by plants and enters the biosphere.

The considerable rise in vehicle traffic also contributes to total nitrogen fixed, as high engine running temperatures resemble lightning, causingNOto develop from the air taken in to burn the hydrocarbon fuel. Overuse of fertilisers and cars are major sources of water contamination. Nitrate from fertiliser and vehicle operation leaches into natural waters, causing eutrophication鈥攖he depletion of oxygen and the death of aquatic animal life鈥攁s a result of excessive algal and plant growth and degradation.

03

Explanation of pathways

a. Atmospheric fixation entails high-temperature endothermic processes including the conversion of N2and O2to NOwhich is then oxidised exothermically by ozone to generate NO2.NO2interacts with a hydroxyl radical to generate HNO3during the day.

N2(g)+O2(g)2NO(g)NO(g)+O3(g)NO2(g)+O2(g)NO2(g)+HO(g)HNO3(g)

The acid is then carried down by rain and enters both the sea and the land as NO3-, which plants can use.

b. Industrial fixing usually entails the Haber process, which produces ammonia. A metal catalyst converts gaseous nitrogen and hydrogen to ammonia under high pressure and temperature.

N2(g)+3H2(g)2NH3(g)

While some of the NH3is transformed to HNO3the majority of the ammonia is used as a fertiliser, either directly or as urea and ammonium salts (sulphate, phosphate, nitrate).

c. The most prevalent method of fixing atmospheric N2is biological fixation. It's found in blue-green algae and nitrogen-fixing bacteria found on leguminous plant roots. A sequence of enzymes in root bacteria repair N2by converting it to NH3and NH4+. Other soil bacteria have enzymes that catalyse the multistep oxidation of NH4+to NO2-, finally NO3-which plants then decrease to generate their protein. Animals consume plant proteins in order to produce their own proteins and excrete nitrogenous waste such as urea.

Therefore, human activities are significant factor for water pollution. And the three pathways for nitrogen fixation are atmospheric fixation, industrial fixation and biological fixation.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Like heavy water (D2O), so-called 鈥渟emi-heavy water鈥 (HDO) undergoes H/D exchange. The scenes below depict an initial mixture of HDO and H2reaching equilibrium.


a) Write the balanced equation for the reaction. (b) Is the value of K greater or less than? (c) If each molecule depicted represents0.10M, calculate K.

The use of silica to form slag in the production of phosphorus from phosphate rock was introduced by Robert Boyle more than years ago. When fluorapatite [Ca5(PO4)3F]is used in phosphorus production, most of the fluorine atoms appear in the slag, but some end up in toxic and corrosive SiF4(g).

(a) If by mass of the fluorine in 100.kgof Ca5(PO4)3Fforms SiF4, what volume of this gas is collected at 1.00atmand the industrial furnace temperature of 1450C?

(b) In some facilities, the SiF4 is used to produce sodium hexafluoro silicate (Na2SiF6)which is sold for water fluoridation:

2SiF4(g)+Na2CO3(s)+H2O(l)Na2SiF6(aq)+SiO2(s)+CO2(g)+2HF(aq)

How many cubic meters of drinking water can be fluoridated to a level of 1.0ppm

of F-

using the

SiF4

produced in part (a)?

Question: Chemosynthetic bacteria reduce CO2by 鈥渟plitting鈥H2S(g)instead of the H2O(g)used by photosynthetic organisms. Compare the free energy change for splitting H2Swith that for splittingH2O . Is there an advantage to using H2Sinstead ofH2O?

Nitric oxide occurs in the tropospheric nitrogen cycle, but it destroys ozone in the stratosphere.

(a) Write equations for its reaction with ozone and for the reverse reaction.

(b) Given thaGt the forward and reverse steps are first order in each component, write general rate laws for them.

(c) Calculate for this reaction at280 K , the average temperature in the stratosphere. (Assume that the Hand Svalues in Appendix B do not change with temperature.)

(d) What ratio of rate constants is consistent withK at this temperature

Question: Silver has a face-cantered cubic structure with a unit cell edge length of 408.6pm. Sterling silver is a substitutional alloy that contains 7.5%copper atoms. Assuming the unit cell remains the same, find the density of silver and of sterling silver.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.