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The empirical formula is given by the simplest number ratio of the number of different atoms present in the compound.

The molecular formula gives the actual number of different atoms present in the same molecule.

The whole number multiple given as the ratio of molar mass to the empirical formula mass of each element deduces the molecular formula.

The whole number multiple is given as,

$\mathrm{whole}-\mathrm{number}\text{ }\mathrm{multiple}=\text{ }\frac{\mathrm{molar}\text{ }\mathrm{mass}(\mathrm{g}/\mathrm{mol})}{\mathrm{empirical}\text{ }\mathrm{formula}\text{ }\mathrm{mass}(\mathrm{g}/\mathrm{mol})}$

The mass fraction of the Cl atom is:

$\mathbf{\text{Cl=0.791}}$

The mass fraction of the Si atom is calculated as:

$\mathbf{\text{Si=1-0.791=0.209}}$

Then, the ratio of the number of moles of Si and Cl atoms is:

$\begin{array}{l}\mathrm{n}\left(\mathrm{Cl}\right):\mathrm{n}\left(\mathrm{Si}\right)=\frac{\frac{0.791}{35.45}}{\frac{0.209}{28.09}}\\ \mathrm{n}\left(\mathrm{Cl}\right):\mathrm{n}\left(\mathrm{Si}\right)=0.022:0.007\\ \mathrm{n}\left(\mathrm{Cl}\right):\mathrm{n}\left(\mathrm{Si}\right)=3:1\end{array}$

Thus, the empirical formula is${\mathbf{SiCl}}_{\mathbf{3}}$

The empirical formula is${\mathbf{SiCl}}_{\mathbf{3}}$

The empirical formula mass is calculated as:

$\begin{array}{c}{\mathrm{M}}_{\mathrm{w}}\text{ }\mathrm{of}\text{ }\mathrm{empirical}\text{ }\mathrm{formula}={\mathrm{M}}_{\mathrm{w}}\text{ }\mathrm{of}\text{ }\mathrm{Si}+3×\left({\mathrm{M}}_{\mathrm{w}}\text{ }\mathrm{of}\text{ }\mathrm{Cl}\right)\\ =28.09\text{ }\mathrm{g}/\mathrm{mol}+3×\left(35.45\text{ }\mathrm{g}/\mathrm{mol}\right)\\ =135.44\text{ }\mathrm{g}/\mathrm{mol}\end{array}$

The molecular formula mass = 269 g/mol

The whole-number ratio is:

$\mathrm{whole}-\mathrm{number}\text{ }\mathrm{multiple}=\text{ }\frac{269(\mathrm{g}/\mathrm{mol})}{134.44(\mathrm{g}/\mathrm{mol})}≈2$

Multiplying subscripts of ${\mathbf{SiCl}}_{\mathbf{3}}$by 2, the molecular formula is given by

$\mathbf{=}\mathbf{\text{ }}{\mathbf{Si}}_{\mathbf{(}\mathbf{1}\mathbf{×}\mathbf{2}\mathbf{)}}\mathbf{×}{\mathbf{Cl}}_{\mathbf{(}\mathbf{3}\mathbf{×}\mathbf{2}\mathbf{)}}$

Thus, the molecular formula is${\mathbf{Si}}_{\mathbf{2}}{\mathbf{Cl}}_{\mathbf{6}}$