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Citric acid (right) is concentrated in citrus fruits and plays a central metabolic role in nearly every animal and plant cell. (a) What are the molar mass and formula of citric acid? (b) How many moles of citric acid are in 1.50 qt of lemon juice (d = 1.09 g/mL) that is 6.82% citric acid by mass?

Short Answer

Expert verified
  1. The formula of citric acid is C6H8O7and the molar mass is192.124 g/mol.
  2. The moles of citric acid is1.75 mol.

Step by step solution

01

Determine the formula of citric acid

The pink dots in the given figure represents theOatom. So, the number ofOatoms in citric acid is 7.

The black dot represents the Catom, thus the number of Catoms in citric acid is 6. And the blue dots represent the Hatom, so the number of Hatoms in citric acid is 8.

Therefore, the formula of citric acid isC6H8O7.

02

Calculate the molar mass of the citric acid

The molar mass of = 12.01 g/mol

The molar mass of = 1.008 g/mol

The molar mass of = 16 g/mol

The molar mass of citric acid is calculated as:

molar mass of C6H8O7=6×molar mass of C+8×molar mass of H+7×molar mass of O6×12.01 g/mol+8×1.008 g/mol+7×16 g/mol192.124 g/mol

03

Calculate the mass of the citric acid 

Since 1 qt is nearly equal to 946.35 mL.

The mass fraction of citric acid(W) = 6.82 %

The density of citric acid (d) = 1.09 g/mL

The volume of citric acid(V) = 1.50 qt

Thus, the mass of citric acid(m) is calculated as:

m=w d V=0.0682×1.09 g/mL×4.79×946.35 mL=336.98 g

04

Calculate the mass of the citric acid

The molar mass of citric acid = 192.124 g/mol

The mass of citric acid = 336.98 g

The number of moles of citric acid is calculated as:

moles of citric acid=mass of citric acidMolar mass of citric acid=336.98 g192.124 g/mol=1.75 mol

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