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The beakers below depict the aqueous dissociations of weak acids HA (blue and green) and HB (blue and yellow); solvent molecules are omitted for clarity. If the HA solution is0.50L, and the HB solution is 0.25L, and each particle representsmol, 铿乶d the Ka of each acid. Which acid, if either, is stronger?

Short Answer

Expert verified

HB is the stronger acid.

Step by step solution

01

Find stronger acid

Solve for the concentration of each molecule in the beaker.

Green isA-, 1脳0.010mol=0.010mol

A-=molL=0.010mol0.5L=0.020M.

Green-white isHA, 5脳0.010mol=0.050mol

[HA] =molL=0.050mol0.5L=0.10M

Red-white isH3O+, 1脳0.010mol=0.010mol

H3O+=molL=1mol0.5L=0.020M.

Write the reaction expression.

HA +H2OH3O++A-

Solve forKa.

Ka=[ product ][reactant]=H3O+A-HA]=(0.020M)(0.020M)0.10M

02

Solve the equation

Yellow isB-, 1脳0.010mol=0.010mol

B-=molL=0.010mol0.25L=0.040M

Green white isHB, 4脳0.010mol=0.040mol

[HB]=molL=0.040mol0.25L=0.16M.

Red white isH3O+,1脳0.010尘辞濒=0.010尘辞濒

H3O+=molL=1mol0.25L=0.040M.

Write the reaction expression.

HB +H2OH3O++B-

Solve forKa.

Ka=[ product ][ reactant ]=H3O+B-[HB]=(0.040M)(0.040M)0.16M=1.010-2

Since theKaof HBis greater than theKaof HA, HB is the stronger acid.

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