Chapter 18: Problem 69
Identify the conjugate acid-base pairs in the reaction of \(\mathrm{H}_{3} \mathrm{PO}_{4}\) with water.
Short Answer
Expert verified
In the reaction of H鈧働O鈧 with water (H鈧働O鈧 (aq) + H鈧侽 (l) 鈬 H鈧侾O鈧勨伝 (aq) + H鈧僌鈦 (aq)), the conjugate acid-base pairs are:
1. H鈧働O鈧 (acid) and H鈧侾O鈧勨伝 (conjugate base)
2. H鈧侽 (base) and H鈧僌鈦 (conjugate acid)
Step by step solution
01
Write the chemical reaction involving H鈧働O鈧 and water
First, let's write out the equation for the reaction of H鈧働O鈧 with water, considering that H鈧働O鈧 behaves as an acid:
H鈧働O鈧 (aq) + H鈧侽 (l) 鈬 H鈧侾O鈧勨伝 (aq) + H鈧僌鈦 (aq)
In this reaction, H鈧働O鈧 donates a proton to H鈧侽, forming H鈧侾O鈧勨伝 and H鈧僌鈦.
02
Identify the acid and base
In the reaction, the species that donates a proton (loses an H鈦 ion) is H鈧働O鈧, so it is the acid. The species that accepts the proton (gains an H鈦 ion) is H鈧侽, and it is the base.
03
Identify the conjugate acid and conjugate base
When H鈧働O鈧 loses a proton, it forms H鈧侾O鈧勨伝, which is the conjugate base. When H鈧侽 gains a proton, it forms H鈧僌鈦, which is the conjugate acid.
04
Identify the conjugate acid-base pairs
Now that we've identified the acid, base, conjugate acid, and conjugate base, we can identify the conjugate acid-base pairs in the reaction. The conjugate acid-base pair consists of the species that differ by one proton.
The conjugate acid-base pairs in the reaction are:
1. H鈧働O鈧 (acid) and H鈧侾O鈧勨伝 (conjugate base)
2. H鈧侽 (base) and H鈧僌鈦 (conjugate acid)
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chemical Reactions
In a chemical reaction, substances known as reactants undergo a process to create new substances called products. During this process, bonds between atoms in the reactants are broken and new bonds are formed to yield the products. This is represented by a chemical equation. Understanding chemical reactions is crucial because they describe the transformation of matter.
For instance, the reaction of \(\mathrm{H}_{3}\mathrm{PO}_{4}\) with water involves a combination of molecules that results in the formation of new products: \(\mathrm{H}_{2}\mathrm{PO}_{4}^{-}\) and \(\mathrm{H}_{3}\mathrm{O}^{+}\). This particular chemical reaction is reversible, meaning it can proceed in both forward and reverse directions, indicated by a double arrow (\(\rightleftharpoons\)) in the equation.
Understanding chemical reactions is the first step in exploring specific types of reactions, such as acid-base reactions.
For instance, the reaction of \(\mathrm{H}_{3}\mathrm{PO}_{4}\) with water involves a combination of molecules that results in the formation of new products: \(\mathrm{H}_{2}\mathrm{PO}_{4}^{-}\) and \(\mathrm{H}_{3}\mathrm{O}^{+}\). This particular chemical reaction is reversible, meaning it can proceed in both forward and reverse directions, indicated by a double arrow (\(\rightleftharpoons\)) in the equation.
Understanding chemical reactions is the first step in exploring specific types of reactions, such as acid-base reactions.
Acid-Base Reaction
Acid-base reactions are a specific type of chemical reaction. They occur when an acid donates a proton (H鈦 ion) to a base. This proton transfer results in the formation of a conjugate acid and a conjugate base.
In the case of the reaction between \(\mathrm{H}_{3}\mathrm{PO}_{4}\) and water, \(\mathrm{H}_{3}\mathrm{PO}_{4}\) acts as the acid because it donates a proton. Water (\(\mathrm{H}_{2}\mathrm{O}\)) acts as the base because it accepts the proton.
It's a neat dance of acidity and basicity, where one molecule donates a proton and another accepts it, illustrating the nature of acidity and basicity in a simple yet profound way.
In the case of the reaction between \(\mathrm{H}_{3}\mathrm{PO}_{4}\) and water, \(\mathrm{H}_{3}\mathrm{PO}_{4}\) acts as the acid because it donates a proton. Water (\(\mathrm{H}_{2}\mathrm{O}\)) acts as the base because it accepts the proton.
It's a neat dance of acidity and basicity, where one molecule donates a proton and another accepts it, illustrating the nature of acidity and basicity in a simple yet profound way.
Proton Transfer
Proton transfer lies at the heart of acid-base reactions. During proton transfer, an acid gives up a proton, which is then accepted by the base. This transaction is what transforms the acid into its conjugate base and the base into its conjugate acid.
For the reaction between \(\mathrm{H}_{3}\mathrm{PO}_{4}\) and water, \(\mathrm{H}_{3}\mathrm{PO}_{4}\) donates a proton, changing into \(\mathrm{H}_{2}\mathrm{PO}_{4}^{-}\), its conjugate base. Concurrently, \(\mathrm{H}_{2}\mathrm{O}\) accepts this proton and becomes \(\mathrm{H}_{3}\mathrm{O}^{+}\), its conjugate acid.
This step is fundamental as it highlights the process of how acids and bases interact on the molecular level, showcasing the principle of proton transfer that defines acid-base chemistry.
For the reaction between \(\mathrm{H}_{3}\mathrm{PO}_{4}\) and water, \(\mathrm{H}_{3}\mathrm{PO}_{4}\) donates a proton, changing into \(\mathrm{H}_{2}\mathrm{PO}_{4}^{-}\), its conjugate base. Concurrently, \(\mathrm{H}_{2}\mathrm{O}\) accepts this proton and becomes \(\mathrm{H}_{3}\mathrm{O}^{+}\), its conjugate acid.
This step is fundamental as it highlights the process of how acids and bases interact on the molecular level, showcasing the principle of proton transfer that defines acid-base chemistry.
Conjugate Bases
A conjugate base is what remains after an acid donates a proton in a chemical reaction. It essentially forms when an acid's proton is removed.
In our reaction, \(\mathrm{H}_{3}\mathrm{PO}_{4}\) donates a proton and transforms into \(\mathrm{H}_{2}\mathrm{PO}_{4}^{-}\). Since \(\mathrm{H}_{2}\mathrm{PO}_{4}^{-}\) is the substance left after \(\mathrm{H}_{3}\mathrm{PO}_{4}\) loses a proton, it is known as the conjugate base.
Conjugate bases are important because they help re-balance a system in dynamic equilibrium, ready to regain a proton in the reverse reaction, thereby emphasizing their role in reversible reactions.
In our reaction, \(\mathrm{H}_{3}\mathrm{PO}_{4}\) donates a proton and transforms into \(\mathrm{H}_{2}\mathrm{PO}_{4}^{-}\). Since \(\mathrm{H}_{2}\mathrm{PO}_{4}^{-}\) is the substance left after \(\mathrm{H}_{3}\mathrm{PO}_{4}\) loses a proton, it is known as the conjugate base.
Conjugate bases are important because they help re-balance a system in dynamic equilibrium, ready to regain a proton in the reverse reaction, thereby emphasizing their role in reversible reactions.
Conjugate Acids
A conjugate acid is formed when a base accepts a proton. It represents the base after it has undergone protonation.
In the reaction where \(\mathrm{H}_{2}\mathrm{O}\) acts as a base, it gains a proton and transforms into \(\mathrm{H}_{3}\mathrm{O}^{+}\). Thus, \(\mathrm{H}_{3}\mathrm{O}^{+}\) is considered the conjugate acid.
Understanding conjugate acids is crucial because they demonstrate how a base transforms through proton acceptance, completing the acid-base dynamic. This comprehension is key to grasping how reversible reactions facilitate balance through proton exchanges.
In the reaction where \(\mathrm{H}_{2}\mathrm{O}\) acts as a base, it gains a proton and transforms into \(\mathrm{H}_{3}\mathrm{O}^{+}\). Thus, \(\mathrm{H}_{3}\mathrm{O}^{+}\) is considered the conjugate acid.
Understanding conjugate acids is crucial because they demonstrate how a base transforms through proton acceptance, completing the acid-base dynamic. This comprehension is key to grasping how reversible reactions facilitate balance through proton exchanges.