Chapter 10: Problem 179
Write the formula for the following hydrates. a. nickel(II) chloride hexahydrate b. cobalt(II) chloride hexahydrate c. magnesium carbonate pentahydrate d. sodium sulfate decahydrate
Short Answer
Expert verified
a. NiCl鈧偮6H鈧侽
b. CoCl鈧偮6H鈧侽
c. MgCO鈧兟5H鈧侽
d. Na鈧係O鈧劼10H鈧侽
Step by step solution
01
a. nickel(II) chloride hexahydrate
First, we need to write the formula for nickel(II) chloride. Nickel has a +2 charge, which is indicated by the (II) in its name, and chloride has a -1 charge. The formula for nickel(II) chloride is NiCl鈧. Since it is a hexahydrate, there are 6 water molecules for each formula unit of the compound. To represent this, we add a dot followed by the number of water molecules and the formula for water (H鈧侽). The final formula is:
NiCl鈧偮6H鈧侽
02
b. cobalt(II) chloride hexahydrate
First, we need to write the formula for cobalt(II) chloride. Cobalt has a +2 charge, which is indicated by the (II) in its name, and chloride has a -1 charge. The formula for cobalt(II) chloride is CoCl鈧. Since it is a hexahydrate, there are 6 water molecules for each formula unit of the compound. To represent this, we add a dot followed by the number of water molecules and the formula for water (H鈧侽). The final formula is:
CoCl鈧偮6H鈧侽
03
c. magnesium carbonate pentahydrate
First, we need to write the formula for magnesium carbonate. Magnesium has a +2 charge and carbonate has a -2 charge. The formula for magnesium carbonate is MgCO鈧. Since it is a pentahydrate, there are 5 water molecules for each formula unit of the compound. To represent this, we add a dot followed by the number of water molecules and the formula for water (H鈧侽). The final formula is:
MgCO鈧兟5H鈧侽
04
d. sodium sulfate decahydrate
First, we need to write the formula for sodium sulfate. Sodium has a +1 charge and sulfate has a -2 charge. We need two sodium ions to balance the charge of one sulfate ion. The formula for sodium sulfate is Na鈧係O鈧. Since it is a decahydrate, there are 10 water molecules for each formula unit of the compound. To represent this, we add a dot followed by the number of water molecules and the formula for water (H鈧侽). The final formula is:
Na鈧係O鈧劼10H鈧侽
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chemical Nomenclature
Understanding the names of chemical compounds is essential in chemistry. Chemical nomenclature involves rules that chemists follow to name compounds systematically. It provides a way to clearly communicate what compound is being referred to, avoiding ambiguity. For hydrates, which are compounds that include water molecules physically bound to them, the naming convention indicates the number and type of ions followed by the prefix and suffix that specify the number of water molecules.
For instance, in the name nickel(II) chloride hexahydrate, 'nickel(II)' tells us the cation is nickel with a +2 charge due to the (II), 'chloride' is the anion with a -1 charge, and 'hexa' specifies that there are six water molecules attached. The correct formula, reflecting this nomenclature, is NiCl鈧偮6H鈧侽. Remember, the numeral in the cation's name (II) indicates its oxidation state, and it is vital to balance the charges for the overall neutral charge of the compound. Furthermore, the number of water molecules in the hydrate is not related to the stoichiometry of the compound's ions, but it is crucial to include it for proper naming and chemical representation.
For instance, in the name nickel(II) chloride hexahydrate, 'nickel(II)' tells us the cation is nickel with a +2 charge due to the (II), 'chloride' is the anion with a -1 charge, and 'hexa' specifies that there are six water molecules attached. The correct formula, reflecting this nomenclature, is NiCl鈧偮6H鈧侽. Remember, the numeral in the cation's name (II) indicates its oxidation state, and it is vital to balance the charges for the overall neutral charge of the compound. Furthermore, the number of water molecules in the hydrate is not related to the stoichiometry of the compound's ions, but it is crucial to include it for proper naming and chemical representation.
Ionic Compounds
Ionic compounds are made of positive and negative ions that are held together by strong electrostatic forces known as ionic bonds. In nomenclature and formula writing, the positive ion (or cation) is named first, followed by the negative ion (or anion). The charges of these ions must balance out because compounds are electrically neutral.
For example, cobalt(II) chloride hexahydrate is composed of Co虏鈦 ions and Cl鈦 ions, with the formula CoCl鈧. The subscript '2' in Cl鈧 balances the +2 charge on the cobalt ion, achieving neutrality. When a hydrate like CoCl鈧偮6H鈧侽 forms, it simply means that each formula unit of CoCl鈧 is associated with six water molecules, an essential aspect of the compound's structure which affects its physical and chemical properties. This inclusion of water molecules doesn't affect the charge balance between the cations and anions, but it's critical when considering the compound's molecular weight and during processes like heating or chemical reactions where water is released from the hydrate.
For example, cobalt(II) chloride hexahydrate is composed of Co虏鈦 ions and Cl鈦 ions, with the formula CoCl鈧. The subscript '2' in Cl鈧 balances the +2 charge on the cobalt ion, achieving neutrality. When a hydrate like CoCl鈧偮6H鈧侽 forms, it simply means that each formula unit of CoCl鈧 is associated with six water molecules, an essential aspect of the compound's structure which affects its physical and chemical properties. This inclusion of water molecules doesn't affect the charge balance between the cations and anions, but it's critical when considering the compound's molecular weight and during processes like heating or chemical reactions where water is released from the hydrate.
Stoichiometry of Hydrates
Stoichiometry is the area of chemistry that involves the quantitative relationships between reactants and products in a chemical reaction. For hydrates, stoichiometry includes the number of water molecules associated with each formula unit of the compound. These water molecules are an integral part of the hydrate's structure, but they can be removed through heating, a process known as dehydration.
For instance, magnesium carbonate pentahydrate, MgCO鈧兟5H鈧侽, has five water molecules for every one unit of MgCO鈧. When determining the molar mass of the hydrate, it is essential to include the mass of these water molecules. Additionally, when hydrates are involved in chemical reactions, their stoichiometry must be considered to predict the products accurately and calculate the yield. A common exercise in the laboratory is to heat a known mass of hydrate and measure the mass of the anhydrous (water-free) compound to determine the number of water molecules originally present. This can help students understand the concept of mole-to-mole relationships and how to apply stoichiometry to real-world situations.
For instance, magnesium carbonate pentahydrate, MgCO鈧兟5H鈧侽, has five water molecules for every one unit of MgCO鈧. When determining the molar mass of the hydrate, it is essential to include the mass of these water molecules. Additionally, when hydrates are involved in chemical reactions, their stoichiometry must be considered to predict the products accurately and calculate the yield. A common exercise in the laboratory is to heat a known mass of hydrate and measure the mass of the anhydrous (water-free) compound to determine the number of water molecules originally present. This can help students understand the concept of mole-to-mole relationships and how to apply stoichiometry to real-world situations.