Chapter 8: Problem 30
Which of these elements is unlikely to form covalent bonds: \(\mathrm{S}, \mathrm{H}, \mathrm{K}, \mathrm{Ar}, \mathrm{Si}\) ? Explain your choices.
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Chapter 8: Problem 30
Which of these elements is unlikely to form covalent bonds: \(\mathrm{S}, \mathrm{H}, \mathrm{K}, \mathrm{Ar}, \mathrm{Si}\) ? Explain your choices.
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A common form of elemental phosphorus is the tetrahedral \(\mathrm{P}_{4}\) molecule, where all four phosphorus atoms are equivalent: At room temperature phosphorus is a solid. (a) Do you think there are any unshared pairs of electrons in the \(\mathrm{P}_{4}\) molecule? (b) How many \(\mathrm{P}-\mathrm{P}\) bonds are there in the molecule? (c) Can you draw a Lewis structure for a linear \(\mathrm{P}_{4}\) molecule that satisfies the octet rule? (d) Using formal charges, what can you say about the stability of the linear molecule vs. that of the tetrahedral molecule?
How many elements in the periodic table are represented by a Lewis symbol with a single dot? Are all these elements in the same group? Explain.
Using Lewis symbols, diagram the reaction between magnesium and oxygen atoms to give the ionic substance \(\mathrm{MgO}\).
The dipole moment and bond distance measured for the highly reactive gas phase OH molecule are \(1.78 \mathrm{D}\) and \(0.98 \AA\), respectively. (a) Given these values calculate the effective charges on the \(\mathrm{H}\) and \(\mathrm{O}\) atoms of the OH molecule in units of the electronic charges \(e\). (b) Is this bond more or less polar than the \(\mathrm{H}-\mathrm{Cl}\) bond in an \(\mathrm{HCl}\) molecule? (c) Is that what you would have expected based on electronegativities?
(a) Determine the formal charge on the chlorine atom in the hypochlorite ion, \(\mathrm{ClO}^{-}\), and the perchlorate ion, \(\mathrm{ClO}_{4}^{-}\), using resonance structures where the \(\mathrm{Cl}\) atom has an octet. (b) What are the oxidation numbers of chlorine in \(\mathrm{ClO}^{-}\) and in \(\mathrm{ClO}_{4}^{-} ?(\mathrm{c})\) Is it uncommon for the formal charge and the oxidation state to be different? Explain. (d) Perchlorate is a much stronger oxidizing agent than hypochlorite. Would you expect there to be any relationship between the oxidizing power of the oxyanion and either the oxidation state or the formal charge of chlorine?
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