Chapter 8: Problem 30
Which of these elements is unlikely to form covalent bonds: \(\mathrm{S}, \mathrm{H}, \mathrm{K}, \mathrm{Ar}, \mathrm{Si}\) ? Explain your choices.
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Chapter 8: Problem 30
Which of these elements is unlikely to form covalent bonds: \(\mathrm{S}, \mathrm{H}, \mathrm{K}, \mathrm{Ar}, \mathrm{Si}\) ? Explain your choices.
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Calculate the formal charge on the indicated atom in each of the following molecules or ions: (a) the central oxygen atom in \(\mathrm{O}_{3}\), (b) phosphorus in \(\mathrm{PF}_{6}^{-}\), (c) nitrogen in \(\mathrm{NO}_{2}\), (d) iodine in \(\mathrm{ICl}_{3}\), (e) chlorine in \(\mathrm{HClO}_{4}\) (hydrogen is bonded to \(\mathrm{O}\) ).
(a) Write the electron configuration for the element titanium, Ti. How many valence electrons does this atom possess? (b) Hafnium, Hf, is also found in group \(4 \mathrm{~B}\). Write the electron configuration for Hf. (c) Both \(\mathrm{Ti}\) and Hf behave as though they possess the same number of valence electrons. Which of the subshells in the electron configuration of Hf behave as valence orbitals? Which behave as core orbitals?
Based on data in Table \(8.2\), estimate (within \(30 \mathrm{~kJ} / \mathrm{mol}\) ) the lattice energy for (a) LiBr, (b) \(\mathrm{CsBr}\), (c) \(\mathrm{CaCl}_{2}\).
(a) Based on the lattice cncrgics of \(\mathrm{MgCl}_{2}\) and \(\mathrm{SrCl}_{2}\) given in Table 8.2, what is the range of values that you would expect for the lattice energy of \(\mathrm{CaCl}_{2}\) ? (b) Using data from Appendix C, Figure 7.12, and Figure \(7.14\) and the value of the second ionization energy for \(\mathrm{Ca}\), \(1145 \mathrm{~kJ} / \mathrm{mol}\), calculate the lattice energy of \(\mathrm{CaCl}_{2}\).
Write the electron configuration for phosphorus. Identify the valence electrons in this configuration and the nonvalence electrons. From the standpoint of chemical reactivity, what is the important difference between them?
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