Chapter 8: Problem 73
How many elements in the periodic table are represented by a Lewis symbol with a single dot? Are all these elements in the same group? Explain.
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Chapter 8: Problem 73
How many elements in the periodic table are represented by a Lewis symbol with a single dot? Are all these elements in the same group? Explain.
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Consider the nitryl cation, \(\mathrm{NO}_{2}^{+}\). (a) Write one or more appropriate Lewis structures for this ion. (b) Are resonance structures needed to describe the structure? (c) With what familiar molecule is it isoelectronic?
Write Lewis structures for the following: (a) \(\mathrm{H}_{2} \mathrm{CO}\) (both \(\mathrm{H}\) atoms are bonded to \(\mathrm{C}\) ), (b) \(\mathrm{H}_{2} \mathrm{O}_{2}\), (c) \(\mathrm{C}_{2} \mathrm{~F}_{6}\) (contains a \(\mathrm{C}-\mathrm{C}\) bond \(),\) (d) \(\mathrm{AsO}_{3}{ }^{3-}\), (e) \(\mathrm{H}_{2} \mathrm{SO}_{3}(\mathrm{H}\) is bonded to \(\mathrm{O})\), (f) \(\mathrm{C}_{2} \mathrm{H}_{2}\).
Write the electron configuration for each of the following ions, and determine which ones possess noble-gas configurations: (a) \(\mathrm{Sr}^{2+}\), (b) \(\mathrm{Ti}^{2+}\), (c) \(\mathrm{Se}^{2-}\),(d) \(\mathrm{Ni}^{2+}\),(e) \(\mathrm{Br}^{-}\), (f) \(\mathrm{Mn}^{3+}\).
Arrange the bonds in each of the following sets in order of increasing polarity: (a) \(\mathrm{C}-\mathrm{F}, \mathrm{O}-\mathrm{F}, \mathrm{Be}-\mathrm{F} ;\) (b) \(\mathrm{O}-\mathrm{Cl}, \mathrm{S}-\mathrm{Br}, \mathrm{C}-\mathrm{P}\) (c) \(\mathrm{C}-\mathrm{S}, \mathrm{B}-\mathrm{F}, \mathrm{N}-\mathrm{O}\)
The reaction of indium, In, with sulfur leads to three binary compounds, which we will assume to be purely ionic. The three compounds have the following properties: $$ \begin{array}{lll} \hline \text { Compound } & \text { Mass \% In } & \text { Melting Point }\left({ }^{\circ} \mathrm{C}\right) \\ \hline \text { A } & 87.7 & 653 \\ \text { B } & 78.2 & 692 \\ \text { C } & 70.5 & 1050 \\ \hline \end{array} $$ (a) Determine the empirical formulas of compounds A, B, and C. (b) Give the oxidation state of In in each of the three compounds. (c) Write the electron configuration for the In ion in each compound. Do any of these configurations correspond to a noble-gas configuration? (d) In which compound is the ionic radius of In expected to be smallest? Explain. (e) The melting point of ionic compounds often correlates with the lattice energy. Explain the trends in the melting points of compounds A, B, and \(\mathrm{C}\) in these terms.
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