Chapter 8: Problem 13
Using Lewis symbols, diagram the reaction between magnesium and oxygen atoms to give the ionic substance \(\mathrm{MgO}\).
/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none}
Learning Materials
Features
Discover
Chapter 8: Problem 13
Using Lewis symbols, diagram the reaction between magnesium and oxygen atoms to give the ionic substance \(\mathrm{MgO}\).
All the tools & learning materials you need for study success - in one app.
Get started for free
Using bond enthalpies (Table 8.4), estimate \(\Delta H\) for each of the following reactions: (a) \(2 \mathrm{CH}_{4}(\mathrm{~g})+\mathrm{O}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{CH}_{3} \mathrm{OH}(g)\) (b) \(\mathrm{H}_{2}(g)+\mathrm{Br}_{2}(g) \longrightarrow 2 \mathrm{HBr}(g)\) (c) \(2 \mathrm{H}_{2} \mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(g)+\mathrm{O}_{2}(g)\)
(a) Write a Lewis structure for the phosphorus trifluoride molecule, \(\mathrm{PF}_{3}\). Is the octet rule satisfied for all the atoms in your structure? (b) Determine the oxidation numbers of the \(\mathrm{P}\) and \(\mathrm{F}\) atoms. (c) Determine the formal charges of the \(\mathrm{P}\) and \(\mathrm{F}\) atoms. (d) Is the oxidation number for the \(\mathrm{P}\) atom the same as its formal charge? Explain why or why not.
(a) Using average bond enthalpies, predict which of the following reactions will be most exothermic: (i) \(\mathrm{C}(\mathrm{g})+2 \mathrm{~F}_{2}(\mathrm{~g}) \longrightarrow \mathrm{CF}_{4}(\mathrm{~g})\) (ii) \(\mathrm{CO}(\mathrm{g})+3 \mathrm{~F}_{2} \longrightarrow \mathrm{CF}_{4}(g)+\mathrm{OF}_{2}(g)\) (iii) \(\mathrm{CO}_{2}(g)+4 \mathrm{~F}_{2} \longrightarrow \mathrm{CF}_{4}(g)+2 \mathrm{OF}_{2}(g)\) (b) Explain the trend, if any, that exists between reaction exothermicity and the extent to which the carbon atom is bonded to oxygen.
(a) Use bond enthalpies to estimatethe enthalpy change for the reaction of hydrogen with ethene: $$\mathrm{H}_{2}(\mathrm{~g})+\mathrm{C}_{2} \mathrm{H}_{4}(g) \longrightarrow \mathrm{C}_{2} \mathrm{H}_{6}(g)$$ (b) Calculate the standard enthalpy change for this reaction, using heats of formation. Why does this value differ from that calculated in (a)?
For the following collection of nonmetallic elements, \(\mathrm{O}\), \(\mathrm{P}, \mathrm{Te}, \mathrm{I}, \mathrm{B},(\mathrm{a})\) which two would form the most polar single bond? (b) Which two would form the longest single bond? (c) Which two would be likely to form a compound of formula \(\mathrm{XY}_{2}\) ? (d) Which combinations of elements would likely yield a compound of empirical formula \(\mathrm{X}_{2} \mathrm{Y}_{3} ?\) In each case explain your answer.
What do you think about this solution?
We value your feedback to improve our textbook solutions.