Chapter 8: Problem 13
Using Lewis symbols, diagram the reaction between magnesium and oxygen atoms to give the ionic substance \(\mathrm{MgO}\).
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Chapter 8: Problem 13
Using Lewis symbols, diagram the reaction between magnesium and oxygen atoms to give the ionic substance \(\mathrm{MgO}\).
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Mothballs are composed of naphthalene, \(\mathrm{C}_{10} \mathrm{H}_{8}\), a molecule of which consists of two six-membered rings of carbon fused along an edge, as shown in this incomplete Lewis structure: (a) Write two complete Lewis structures for naphthalene. (b) The observed \(\mathrm{C}-\mathrm{C}\) bond lengths in the molecule are intermediate between \(\mathrm{C}-\mathrm{C}\) single and \(\mathrm{C}=\mathrm{C}\) double bonds. Explain. (c) Represent the resonance in naphthalene in a way analogous to that used to represent it in benzene.
Draw the Lewis structures for each of the following ions or molecules. Identify those that do not obey the octet rule, and explain why they do not. (a) \(\mathrm{SO}_{3}{ }^{2-}\), (b) \(\mathrm{AlH}_{3}\), (c) \(\mathrm{N}_{3}^{-}\), (d) \(\mathrm{CH}_{2} \mathrm{Cl}_{2}\) (e) \(\mathrm{SbF}_{5}\).
For each of these Lewis symbols, indicate the group in the periodic table in which the element \(X\) belongs: (a) \(\cdot \dot{\mathrm{X}} \cdot(\mathrm{b}) \cdot \mathrm{X} \cdot(\mathrm{c}): \dot{\mathrm{X}}\)
(a) Describe the molecule chlorine dioxide, \(\mathrm{ClO}_{2}\), using three possible resonance structures. (b) Do any of these resonance structures satisfy the octet rule for every atom in the molecule? Why or why not? (c) Using formal charges, select the resonance structure(s) that is (are) most important.
Using bond enthalpies (Table 8.4), estimate \(\Delta H\) for each of the following reactions: (a) \(2 \mathrm{CH}_{4}(\mathrm{~g})+\mathrm{O}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{CH}_{3} \mathrm{OH}(g)\) (b) \(\mathrm{H}_{2}(g)+\mathrm{Br}_{2}(g) \longrightarrow 2 \mathrm{HBr}(g)\) (c) \(2 \mathrm{H}_{2} \mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(g)+\mathrm{O}_{2}(g)\)
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