Chapter 5: Problem 7
Which will release more heat as it cools from \(50^{\circ} \mathrm{C}\) to \(25^{\circ} \mathrm{C}, 1 \mathrm{~kg}\) of water or \(1 \mathrm{~kg}\) of aluminum? How do you know? [Section 5.5]
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Chapter 5: Problem 7
Which will release more heat as it cools from \(50^{\circ} \mathrm{C}\) to \(25^{\circ} \mathrm{C}, 1 \mathrm{~kg}\) of water or \(1 \mathrm{~kg}\) of aluminum? How do you know? [Section 5.5]
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Consider the twodiagramsbelow. (a) Based on \((t)\), write an equation showing how \(\Delta H_{\mathrm{A}}\) is related to \(\Delta H_{\mathrm{B}}\) and \(\Delta H_{\mathrm{C}}\). How do both diagram (i) and your equation relate to the fact that enthalpy is a state function? (b) Based on (ii), write an equation relating \(\Delta H_{Z}\) to the other enthalpy changes in the diagram. (c) How do these diagrams relate to Hess's law? [Section 5.6]
Identify the force present, and explain whether work is done when (a) a positively charged particle moves in a circle at a fixed distance from a negatively charged particle; (b) an iron nail is pulled off a magnet.
Consider the following reaction: $$ 2 \mathrm{Mg}(s)+\mathrm{O}_{2}(g)-\longrightarrow 2 \mathrm{MgO}(s) \quad \Delta H=-1204 \mathrm{~kJ} $$ (a) Is this reaction exothermic or endothermic? (b) Calculate the amount of heat transferred when \(2.4 \mathrm{~g}\) of \(\mathrm{Mg}(s)\) reacts at constant pressure. (c) How many grams of \(\mathrm{MgO}\) are produced during an enthalpy change of \(-96.0 \mathrm{~kJ} ?\) (d) How many kilojoules of heat are absorbed when \(7.50 \mathrm{~g}\) of \(\mathrm{MgO}(s)\) is decomposed into \(\mathrm{Mg}(s)\) and \(\mathrm{O}_{2}(g)\) at constant pressure?
When solutions containing silver ions and chloride ions are mixed, silver chloride precipitates: $$ \mathrm{Ag}^{+}(a q)+\mathrm{Cl}^{-}(a q)-\longrightarrow \mathrm{AgCl}(s) \quad \Delta H=-65.5 \mathrm{~kJ} $$ (a) Calculate \(\Delta H\) for production of \(0.200 \mathrm{~mol}\) of \(\mathrm{AgCl}\) by this reaction. (b) Calculate \(\Delta H\) for the production of \(2.50 \mathrm{~g}\) of \(\mathrm{AgCl}\). (c) Calculate \(\Delta \mathrm{H}\) when \(0.150 \mathrm{mmol}\) of AgCl dissolves in water.
A 200-lb man decides to add to his exercise routine by walking up three flights of stairs ( \(45 \mathrm{ft}\) ) 20 times per day. He figures that the work required to increase his potential energy in this way will permit him to eat an extra order of French fries, at 245 Cal, without adding to his weight. Is he correct in this assumption?
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