Chapter 5: Problem 22
Identify the force present, and explain whether work is done when (a) a positively charged particle moves in a circle at a fixed distance from a negatively charged particle; (b) an iron nail is pulled off a magnet.
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Chapter 5: Problem 22
Identify the force present, and explain whether work is done when (a) a positively charged particle moves in a circle at a fixed distance from a negatively charged particle; (b) an iron nail is pulled off a magnet.
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Under constant-volume conditions the heat of combustion of glucose \(\left(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\right)\) is \(15.57 \mathrm{~kJ} / \mathrm{g}\). A \(2.500-\mathrm{g}\) sample of glucose is burned in a bomb calorimeter. The temperature of the calorimeter increased from \(20.55^{\circ} \mathrm{C}\) to \(23.25^{\circ} \mathrm{C}\). (a) What is the total heat capacity of the calorimeter? (b) If the size of the glucose sample had been exactly twice as large, what would the temperature change of the calorimeter have been?
The air bags that provide protection in autos in the event of an accident expand because of a rapid chemical reaction. From the viewpoint of the chemical reactants as the system, what do you expect for the signs of \(q\) and \(w\) in this process?
The complete combustion of acetic acid, \(\mathrm{CH}_{3} \mathrm{COOH}(l)\), to form \(\mathrm{H}_{2} \mathrm{O}(l)\) and \(\mathrm{CO}_{2}(g)\) at constant pressure releases \(871.7 \mathrm{~kJ}\) of heat per mole of \(\mathrm{CH}_{3} \mathrm{COOH}\). (a) Write a balanced thermochemical equation for this reaction. (b) Draw an enthalpy diagram for the reaction.
In what two ways can an object possess energy? How do these two ways differ from one another?
Calcium carbide \(\left(\mathrm{CaC}_{2}\right)\) reacts with water to form acetylene \(\left(\mathrm{C}_{2} \mathrm{H}_{2}\right)\) and \(\mathrm{Ca}(\mathrm{OH})_{2}\). From the following enthalpy of reaction data and data in Appendix \(C\), calculate \(\Delta H_{f}^{\circ}\) for \(\mathrm{CaC}_{2}(s):\) \(\mathrm{CaC}_{2}(s)+2 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Ca}(\mathrm{OH})_{2}(s)+\mathrm{C}_{2} \mathrm{H}_{2}(g)\) \(\Delta H^{\circ}=-127.2 \mathrm{~kJ}\)
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