Chapter 5: Problem 21
Identify the force present, and explain whether work is being performed in the following cases: (a) You lift a pencil off the top of a desk. (b) A spring is compressed to half its normal length.
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Chapter 5: Problem 21
Identify the force present, and explain whether work is being performed in the following cases: (a) You lift a pencil off the top of a desk. (b) A spring is compressed to half its normal length.
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(a) When a 0.235-g sample of benzoic acid is combusted in a bomb calorimeter, the temperature rises \(1.642^{\circ} \mathrm{C}\). When a 0.265-g sample of caffeine, \(\mathrm{C}_{8} \mathrm{H}_{10} \mathrm{O}_{2} \mathrm{~N}_{4}\), is burned, the temperature rises \(1.525^{\circ} \mathrm{C}\). Using the value \(26.38 \mathrm{~kJ} / \mathrm{g}\) for the heat of combustion of benzoic acid, calculate the heat of combustion per mole of caffeine at constant volume. (b) Assuming that there is an uncertainty of \(0.002^{\circ} \mathrm{C}\) in each temperature reading and that the masses of samples are measured to \(0.001 \mathrm{~g}\), what is the estimated uncertainty in the value calculated for the heat of combustion per mole of caffeine?
Identify the force present, and explain whether work is done when (a) a positively charged particle moves in a circle at a fixed distance from a negatively charged particle; (b) an iron nail is pulled off a magnet.
Two solid objects, \(\mathrm{A}\) and \(\mathrm{B}\), are placed in boiling water and allowed to come to temperature there. Each is then lifted out and placed in separate beakers containing \(1000 \mathrm{~g}\) water at \(10.0{ }^{\circ} \mathrm{C}\). Object \(\mathrm{A}\) increases the water temperature by \(3.50^{\circ} \mathrm{C} ; \mathrm{B}\) increases the water temperature by \(2.60^{\circ} \mathrm{C}\). (a) Which object has the larger heat capacity? (b) What can you say about the specific heats of A and B?
Methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right)\) is used as a fuel in race cars. (a) Write a balanced equation for the combustion of liquid methanol in air. (b) Calculate the standard enthalpy change for the reaction, assuming \(\mathrm{H}_{2} \mathrm{O}(g)\) as a product. (c) Calculate the heat produced by combustion per liter of methanol. Methanol has a density of \(0.791 \mathrm{~g} / \mathrm{mL}\) (d) Calculate the mass of \(\mathrm{CO}_{2}\) produced per \(\mathrm{kJ}\) of heat emitted.
Given the data $$ \begin{aligned} \mathrm{N}_{2}(g)+\mathrm{O}_{2}(g)-\cdots+2 \mathrm{NO}(g) & \Delta H=+180.7 \mathrm{~kJ} \\ 2 \mathrm{NO}(g)+\mathrm{O}_{2}(g) \cdots-\rightarrow 2 \mathrm{NO}_{2}(g) & \Delta H=-113.1 \mathrm{~kJ} \\ 2 \mathrm{~N}_{2} \mathrm{O}(g)-\cdots 2 \mathrm{~N}_{2}(g)+\mathrm{O}_{2}(g) & \Delta H=-163.2 \mathrm{~kJ} \end{aligned} $$ use Hess's law to calculate \(\Delta H\) for the reaction $$ \mathrm{N}_{2} \mathrm{O}(g)+\mathrm{NO}_{2}(g) \stackrel{-\cdots} 3 \mathrm{NO}(g) $$
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