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If 38.55 mL of \(\mathrm{HCl}\) is required to titrate \(2.150 \mathrm{g}\) of \(\mathrm{Na}_{2} \mathrm{CO}_{3}\) according to the following equation, what is the molarity of the HCl solution? $$\mathrm{Na}_{2} \mathrm{CO}_{3}(\mathrm{aq})+2 \mathrm{HCl}(\mathrm{aq}) \longrightarrow 2 \mathrm{NaCl}(\mathrm{aq})+\mathrm{CO}_{2}(\mathrm{g})+\mathrm{H}_{2} \mathrm{O}(\ell)$$

Short Answer

Expert verified
The molarity of the HCl solution is approximately 1.053 M.

Step by step solution

01

Write the Balanced Equation

The reaction between sodium carbonate \( \mathrm{Na}_2 \mathrm{CO}_3 \) and hydrochloric acid \( \mathrm{HCl} \) is given as: \[ \mathrm{Na}_2 \mathrm{CO}_3(\mathrm{aq}) + 2 \mathrm{HCl}(\mathrm{aq}) \rightarrow 2 \mathrm{NaCl}(\mathrm{aq}) + \mathrm{CO}_2(\mathrm{g}) + \mathrm{H}_2 \mathrm{O}(\ell) \] This shows that one mole of sodium carbonate reacts with two moles of hydrochloric acid.
02

Calculate Moles of Na2CO3

First, find the molar mass of \( \mathrm{Na}_2 \mathrm{CO}_3 \). The molar mass is calculated as follows: \[ \text{Molar mass of } \mathrm{Na}_2 \mathrm{CO}_3 = 2(22.99) + 12.01 + 3(16.00) = 105.99 \text{ g/mol} \]Next, calculate the moles of \( \mathrm{Na}_2 \mathrm{CO}_3 \): \[ \text{Moles of } \mathrm{Na}_2 \mathrm{CO}_3 = \frac{2.150 \text{ g}}{105.99 \text{ g/mol}} \approx 0.0203 \text{ mol} \]
03

Determine Moles of HCl Needed

According to the balanced equation, 2 moles of \( \mathrm{HCl} \) are needed for every mole of \( \mathrm{Na}_2 \mathrm{CO}_3 \). Thus, the moles of \( \mathrm{HCl} \) required are: \[ \text{Moles of } \mathrm{HCl} = 2 \times 0.0203 \text{ mol} = 0.0406 \text{ mol} \]
04

Calculate Molarity of HCl

Molarity is defined as moles of solute per liter of solution. Convert the volume of \( \mathrm{HCl} \) solution from mL to L: \[ 38.55 \text{ mL} = 0.03855 \text{ L} \]Use the moles of \( \mathrm{HCl} \) and the volume in liters to find the molarity: \[ \text{Molarity of } \mathrm{HCl} = \frac{0.0406 \text{ mol}}{0.03855 \text{ L}} \approx 1.053 \text{ M} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molarity calculation
Molarity is a way to express the concentration of a solution. It represents the number of moles of solute present in one liter (L) of solution. The formula for molarity (M) is: \(M = \frac{\text{moles of solute}}{\text{volume of solution in liters}}\).

In our exercise, we want to find the molarity of the \(\mathrm{HCl}\) solution used in a titration. First, we determine the number of moles of \(\mathrm{HCl}\) from the balanced chemical reaction. We then calculate the molarity by dividing the moles of \(\mathrm{HCl}\) by the volume of the solution in liters. This method is essential for understanding the concentration of reactants in chemical reactions and is widely used in laboratory settings.

Remember to always convert the volume from milliliters (mL) to liters (L) before using it in the molarity formula to ensure accuracy.
Balanced chemical equation
A balanced chemical equation is critical in describing a chemical reaction. It ensures that there are equal numbers of each type of atom on both sides of the equation by obeying the Law of Conservation of Mass.

In this exercise, we examined the reaction between sodium carbonate (\text{Na}_2\text{CO}_3) and hydrochloric acid (\text{HCl}). The balanced equation is: \[\text{Na}_2\text{CO}_3(\text{aq}) + 2 \text{HCl}(\text{aq}) \rightarrow 2 \text{NaCl}(\text{aq}) + \text{CO}_2(\text{g}) + \text{H}_2\text{O}(\ell)\] This equation tells us:
  • 1 mole of \(\text{Na}_2\text{CO}_3\) reacts with 2 moles of \(\text{HCl}\).
  • The products formed are 2 moles of \(\text{NaCl}\), 1 mole of \(\text{CO}_2\), and 1 mole of \(\text{H}_2\text{O}\).
Understanding balanced equations is fundamental for predicting the amounts of reactants needed and products formed.
Stoichiometry
Stoichiometry involves calculating the relationships between reactants and products in a chemical reaction.
To solve stoichiometry problems, you must first have a balanced equation. The equation provides the ratio of moles of reactants and products. Using these ratios, you can determine the amount of a reactant required or a product expected.

In the given titration problem, stoichiometry helps us calculate how many moles of \(\mathrm{HCl}\) were needed to completely react with a known amount of \(\mathrm{Na}_2 \mathrm{CO}_3\). With \(1\) mole of \(\mathrm{Na}_2 \mathrm{CO}_3\) requiring \(2\) moles of \(\mathrm{HCl}\), we used this ratio to find the moles of \(\mathrm{HCl}\) needed to react with \(0.0203\) moles of \(\mathrm{Na}_2 \mathrm{CO}_3\).

Mastering stoichiometry is crucial because it allows chemists to make precise calculations in lab work.
Acid-base reaction
An acid-base reaction is a chemical reaction that involves the transfer of a proton (\(\text{H}^+\)). Acids donate protons while bases accept them. This type of reaction fundamentally changes the materials involved, creating different compounds called products.

In the titration problem, the reaction between \(\text{HCl}\) (an acid) and \(\text{Na}_2\text{CO}_3\) (a base) falls into this category. When they react, \(\text{HCl}\) donates protons to \(\text{Na}_2\text{CO}_3\), resulting in the formation of water (\(\text{H}_2\text{O}\)) and carbon dioxide (\(\text{CO}_2\)). These are typical products of an acid-base reaction.

Understanding acid-base reactions is essential for predicting outcomes in various chemical processes and is widely used in industrial applications and laboratory experiments alike.

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Most popular questions from this chapter

A An unknown solid acid is either citric acid or tartaric acid. To determine which acid you have, you titrate a sample of the solid with NaOH. The appropriate reactions are as follows: Citric acid: \(\mathrm{H}_{3} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{O}_{7}(\mathrm{aq})+3 \mathrm{NaOH}(\mathrm{aq}) \longrightarrow\) $$ 3 \mathrm{H}_{2} \mathrm{O}(\ell)+\mathrm{Na}_{3} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{O}_{7}(\mathrm{aq}) $$ Tartaric acid: \(\mathrm{H}_{2} \mathrm{C}_{4} \mathrm{H}_{4} \mathrm{O}_{6}(\mathrm{aq})+2 \mathrm{NaOH}(\mathrm{aq}) \longrightarrow\) $$2 \mathrm{H}_{2} \mathrm{O}(\ell)+\mathrm{Na}_{2} \mathrm{C}_{4} \mathrm{H}_{4} \mathrm{O}_{6}(\mathrm{aq})$$ A \(0.956-\mathrm{g}\) sample requires \(29.1 \mathrm{mL}\) of \(0.513 \mathrm{M} \mathrm{NaOH}\) for titration to the equivalence point. What is the unknown acid?

A compound has been isolated that can have either of two possible formulas: (a) \(\mathrm{K}\left[\mathrm{Fe}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{2}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}\right]\) or (b) \(\mathrm{K}_{3}\left[\mathrm{Fe}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{3}\right] .\) To find which is correct, you dissolve a weighed sample of the compound in acid and then titrate the oxalate ion \(\left(\mathrm{C}_{2} \mathrm{O}_{4}^{2}\right)\) that comes from the compound with potassium permanganate, \(\mathrm{KMnO}_{4}\) (the source of the \(\mathrm{MnO}_{4}^{-}\) ion). The balanced, net ionic equation for the titration is $$\begin{array}{rl}5 \mathrm{C}_{2} \mathrm{O}_{4}^{2-}(\mathrm{aq})+2 \mathrm{MnO}_{4}^{-}(\mathrm{aq})+16 \mathrm{H}^{+}(\mathrm{aq}) & \longrightarrow \\\2 \mathrm{Mn}^{2+}(\mathrm{aq})+10 \mathrm{CO}_{2}(\mathrm{g})+8 & \mathrm{H}_{2} \mathrm{O}(\ell) \end{array}$$ Titration of \(1.356 \mathrm{g}\) of the compound requires \(34.50 \mathrm{mL}\) of \(0.108 \mathrm{M} \mathrm{KMnO}_{4} .\) Which is the correct formula of the iron-containing compound: (a) or (b)?

Write a balanced equation for the ionization of nitric acid in water.

A The cancer chemotherapy drug cisplatin, \(\operatorname{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{2}\) can be made by reacting (NH_) \(_{2} \mathrm{PtCl}_{4}\) with ammonia in aqueous solution. Besides cisplatin, the other product is \(\mathrm{NH}_{1} \mathrm{Cl}\) (a) Write a balanced equation for this reaction. (b) To obtain \(12.50 \mathrm{g}\) of cisplatin, what mass of \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{PtCl}_{4}\) is required? What volume of \(0.125 \mathrm{M}\) \(\mathrm{NH}_{3}\) is required? (c) Cisplatin can react with the organic compound pyridine, \(\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{N},\) to form a new compound. $$\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{2}(\mathrm{aq})+x \mathrm{C}_{5} \mathrm{H}_{5} \mathrm{N}(\mathrm{aq}) \longrightarrow \mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{2}\left(\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{N}\right)_{x}(\mathrm{s})$$ Suppose you treat \(0.150 \mathrm{g}\) of cisplatin with what you believe is an excess of liquid pyridine \((1.50 \mathrm{mL}\) \(d=0.979 \mathrm{g} / \mathrm{mL}) .\) When the reaction is complete, you can find out how much pyridine was not used by titrating the solution with standardized HCl. If 37.0 mL. of \(0.475 \mathrm{M} \mathrm{HCl}\) is required to titrate the excess pyridine, \(\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{N}(\mathrm{aq})+\mathrm{HCl}(\mathrm{aq}) \longrightarrow \mathrm{C}_{5} \mathrm{H}_{5} \mathrm{NH}^{+}(\mathrm{aq})+\mathrm{Cl}^{-}(\mathrm{aq})\) what is the formula of the unknown compound \(\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{2}\left(\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{N}\right)_{x} ?\)

Vitamin C is the simple compound \(\mathrm{C}_{6} \mathrm{H}_{8} \mathrm{O}_{6}\). Besides being an acid, it is a reducing agent. One method for determining the amount of vitamin C in a sample is therefore to titrate it with a solution of bromine, \(\mathbf{B r}_{2},\) an oxidizing agent. \(\mathrm{C}_{6} \mathrm{H}_{8} \mathrm{O}_{6}(\mathrm{aq})+\mathrm{Br}_{2}(\mathrm{aq}) \longrightarrow 2 \mathrm{HBr}(\mathrm{aq})+\mathrm{C}_{6} \mathrm{H}_{6} \mathrm{O}_{6}(\mathrm{aq})\) A \(1.00-\mathrm{g}\) " chewable" vitamin C tablet requires \(27.85 \mathrm{mL}\) of \(0.102 \mathrm{M} \mathrm{Br}_{2}\) for titration to the equivalence point. What is the mass of vitamin C in the tablet?

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