Chapter 9: Problem 70
Would Hess's law be valid if enthalpy were not a state function? Why or why not?
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Chapter 9: Problem 70
Would Hess's law be valid if enthalpy were not a state function? Why or why not?
These are the key concepts you need to understand to accurately answer the question.
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In a high-temperature gas-phase reaction, methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right)\) reacts with \(\mathrm{N}_{2}\) to produce \(\mathrm{HCN}\) and \(\mathrm{NH}_{3}\). The reaction is endothermic, requiring \(164 \mathrm{kJ}\) of thermal energy per mole of methanol under standard conditions. a. Write a balanced chemical equation for this reaction. b. Is energy a reactant or a product? c. What is the change in enthalpy under standard conditions if \(60.0 \mathrm{g}\) of \(\mathrm{CH}_{3} \mathrm{OH}(g)\) reacts with excess \(\mathrm{N}_{2}(g),\) forming \(\mathrm{HCN}(g),\) and \(\mathrm{NH}_{3}(g) ?\)
Calculate \(\Delta H_{\mathrm{rxn}}^{\circ}\) for the reaction $$2 \mathrm{Ni}(s)+\frac{1}{4} \mathrm{S}_{8}(s)+3 \mathrm{O}_{2}(g) \rightarrow 2 \mathrm{NiSO}_{3}(s) \quad \Delta H_{\mathrm{rxn}}^{\circ}=?$$ from the following data: (1) \(\mathrm{NiSO}_{3}(s) \rightarrow \mathrm{NiO}(s)+\mathrm{SO}_{2}(g) \quad \Delta H_{\mathrm{rxn}}^{\circ}=156 \mathrm{kJ}\) (2) \(\frac{1}{8} S_{8}(s)+O_{2}(g) \rightarrow \operatorname{SO}_{2}(g) \quad \quad \Delta H_{\operatorname{rxn}}^{\circ}=-297 \mathrm{kJ}\) (3) \(\mathrm{Ni}(s)+\frac{1}{2} \mathrm{O}_{2}(g) \rightarrow \mathrm{NiO}_{2}(s) \quad \Delta H_{\mathrm{rxn}}^{\circ}=-241 \mathrm{kJ}\)
Balance the following chemical equation, name the reactants and products, and calculate the enthalpy change under standard conditions. $$\mathrm{FeO}(s)+\mathrm{O}_{2}(g) \rightarrow \mathrm{Fe}_{2} \mathrm{O}_{3}(s) \quad \Delta H_{\mathrm{rxn}}^{\circ}= ?$$
Why is there a negative sign in front of the \(P \Delta V\) term in \(\Delta E=q-P \Delta V ?\)
Describe the difference between an internal energy change \((\Delta E)\) and an enthalpy change \((\Delta H)\).
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