Chapter 9: Problem 69
How is Hess's law consistent with the law of conservation of energy?
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Chapter 9: Problem 69
How is Hess's law consistent with the law of conservation of energy?
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Oxygen and ozone are both forms of elemental oxygen. Are the standard heats of formation of oxygen and ozone the same? Why or why not?
Use a Born-Haber cycle to calculate the lattice energy of potassium chloride (KCl) from the following data: $$\begin{aligned} &\text { Ionization energy of } \mathrm{K}(g)=419 \mathrm{kJ} / \mathrm{mol}\\\ &\text { Electron affinity of } \mathrm{Cl}(g)=-349 \mathrm{kJ} / \mathrm{mol}\\\ &\text { Energy to sublime } \mathrm{K}(s)=89 \mathrm{kJ} / \mathrm{mol}\\\ &\text { Bond energy of } \mathrm{Cl}_{2}(g)=243 \mathrm{kJ} / \mathrm{mol} \end{aligned}$$ Standard heat of formation of \(\mathrm{KCl}=-436.5 \mathrm{kJ} / \mathrm{mol}\)
Explain the difference between potential energy and kinetic energy in molecules.
Would Hess's law be valid if enthalpy were not a state function? Why or why not?
In a simple "kitchen chemistry" experiment, some vinegar is poured into an empty soda bottle. A deflated balloon containing baking soda is stretched over the mouth of the bottle. Holding up the balloon and shaking it allows the baking soda to fall into the vinegar, which starts the following reaction and inflates the balloon: $$\begin{aligned} \mathrm{NaHCO}_{3}(a q)+\mathrm{CH}_{3} \mathrm{COOH}(a q) \rightarrow & \\ & \mathrm{CH}_{3} \mathrm{COONa}(a q)+\mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(\ell) \end{aligned}$$ If the contents of the bottle are the system, is work being done on the surroundings or on the system?
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