Chapter 9: Problem 101
What is meant by fuel value?
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Chapter 9: Problem 101
What is meant by fuel value?
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Use a Born-Haber cycle to calculate the lattice energy of potassium chloride (KCl) from the following data: $$\begin{aligned} &\text { Ionization energy of } \mathrm{K}(g)=419 \mathrm{kJ} / \mathrm{mol}\\\ &\text { Electron affinity of } \mathrm{Cl}(g)=-349 \mathrm{kJ} / \mathrm{mol}\\\ &\text { Energy to sublime } \mathrm{K}(s)=89 \mathrm{kJ} / \mathrm{mol}\\\ &\text { Bond energy of } \mathrm{Cl}_{2}(g)=243 \mathrm{kJ} / \mathrm{mol} \end{aligned}$$ Standard heat of formation of \(\mathrm{KCl}=-436.5 \mathrm{kJ} / \mathrm{mol}\)
Breaking the small pouch of water inside a chemical cold pack containing ammonium nitrate activates the pack, which is used by sports trainers for injured athletes. What is the sign of \(\Delta H\) for the process taking place in the cold pack?
Calculate the lattice energy of sodium oxide \(\left(\mathrm{Na}_{2} \mathrm{O}\right)\) from the following data: Ionization energy of \(\mathrm{Na}(g)=495 \mathrm{kJ} / \mathrm{mol}\) Electron affinity of \(\mathrm{O}(g)\) for 2 electrons \(=603 \mathrm{kJ} / \mathrm{mol}\) Energy to sublime \(\mathrm{Na}(s)=109 \mathrm{kJ} / \mathrm{mol}\) Bond energy of \(\mathrm{O}_{2}(g)=498 \mathrm{kJ} / \mathrm{mol}\) \(\Delta H_{\mathrm{rxn}}\) for \(2 \mathrm{Na}(s)+\frac{1}{2} \mathrm{O}_{2}(g) \rightarrow \mathrm{Na}_{2} \mathrm{O}(s)=-416 \mathrm{kJ} / \mathrm{mol}\)
Use the following data to sketch a heating curve for one mole of methanol. Start the curve at \(-100^{\circ} \mathrm{C}\) and end it at \(100^{\circ} \mathrm{C}\). $$\begin{array}{ll}\hline \text { Boiling point } & 65^{\circ} \mathrm{C} \\\\\hline \text { Melting point } & -94^{\circ} \mathrm{C} \\\\\hline \text { Heat of vaporization } & 35.3 \mathrm{kJ} / \mathrm{mol} \\\\\hline \text { Heat of fusion }\left(\Delta \mathrm{H}_{\text {fus }}\right) & 3.18 \mathrm{kJ} / \mathrm{mol} \\\\\hline \text { Molar heat capacity }(\ell) & 81.1 \mathrm{J} /\left(\mathrm{mol} \cdot^{\circ} \mathrm{C}\right) \\\\\hline \text { Molar heat capacity }(g) & 43.9 \mathrm{J} /\left(\mathrm{mol} \cdot^{\circ} \mathrm{C}\right) \\\\\hline \text { Molar heat capacity }(\mathrm{s}) & 48.7 \mathrm{J} /\left(\mathrm{mol} \cdot^{\circ} \mathrm{C}\right) \\\\\hline\end{array}$$
During a strenuous workout, an athlete generates \(233 \mathrm{kJ}\) of thermal energy. What mass of water would have to evaporate from the athlete's skin to dissipate this energy?
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