Chapter 9: Problem 101
What is meant by fuel value?
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Chapter 9: Problem 101
What is meant by fuel value?
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Given the following thermochemical data: $$\begin{array}{ll}\frac{1}{2} \mathrm{N}_{2}(g)+\frac{1}{2} \mathrm{O}_{2}(g) \rightarrow \frac{1}{2} \mathrm{NO}(g) & \Delta H_{\mathrm{rxn}}^{\circ}=+90.3 \mathrm{kJ} \\\ \mathrm{NO}(g)+\frac{1}{2} \mathrm{Cl}_{2}(g) \rightarrow \mathrm{NOCl}(g) & \Delta H_{\mathrm{rxn}}^{\circ}=-38.6 \mathrm{kJ} \end{array}$$ what is the value of \(\Delta H_{\mathrm{rxn}}^{\circ}\) for the decomposition of NOCl? $$2 \mathrm{NOCl}(g) \rightarrow \mathrm{N}_{2}(g)+\mathrm{O}_{2}(g)+\mathrm{Cl}_{2}(g) \quad \Delta H_{\mathrm{rxn}}^{\circ}=?$$
The mineral spodumene \(\left(\operatorname{LiAlSi}_{2} \mathrm{O}_{6}\right)\) exists in two crystalline forms called \(\alpha\) and \(\beta .\) Use Hess's law and the following information to calculate \(\Delta H_{\mathrm{rxn}}^{\circ}\) for the conversion of \(\alpha\) -spodumene into \(\beta\) -spodumene: $$\begin{array}{r}\mathrm{Li}_{2} \mathrm{O}(s)+2 \mathrm{Al}(s)+4 \mathrm{SiO}_{2}(s)+\frac{3}{2} \mathrm{O}_{2}(g) \rightarrow 2 \alpha-\mathrm{LiAlSi}_{2} \mathrm{O}_{6}(s) \\ \Delta H_{\mathrm{rxn}}^{\circ}=-1870.6 \mathrm{kJ} \end{array}$$ $$\begin{array}{r}\mathrm{Li}_{2} \mathrm{O}(s)+2 \mathrm{Al}(s)+4 \mathrm{SiO}_{2}(s)+\frac{3}{2} \mathrm{O}_{2}(g) \rightarrow 2 \beta-\mathrm{LiAlSi}_{2} \mathrm{O}_{6}(s) \\\\\Delta H_{\mathrm{rxn}}^{\circ}=-1814.6 \mathrm{kJ} \end{array}$$
During a strenuous workout, an athlete generates \(233 \mathrm{kJ}\) of thermal energy. What mass of water would have to evaporate from the athlete's skin to dissipate this energy?
Which of the following processes are exothermic, and which are endothermic? a. Molten aluminum solidifies. b. Rubbing alcohol evaporates from the skin. c. Fog forms over San Francisco Bay.
Without doing any calculations, predict which compound in each pair releases more energy during combustion: a. 1 mole of \(\mathrm{CH}_{4}\) or 1 mole of \(\mathrm{H}_{2}\) b. \(1 \mathrm{g}\) of \(\mathrm{CH}_{4}\) or \(1 \mathrm{g}\) of \(\mathrm{H}_{2}\)
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