/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 35 One step in the conversion of al... [FREE SOLUTION] | 91Ó°ÊÓ

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One step in the conversion of aluminum ore into aluminum metal involves the synthesis of cryolite \(\left(\mathrm{Na}_{3} \mathrm{AlF}_{6}\right)\) in the following reaction: $$6 \mathrm{HF}(g)+3 \mathrm{NaAlO}_{2}(s) \rightarrow \mathrm{Na}_{3} \mathrm{AlF}_{6}(s)+3 \mathrm{H}_{2} \mathrm{O}(\ell)+\mathrm{Al}_{2} \mathrm{O}_{3}(s)$$ How much NaAIO \(_{2}\) (sodium aluminate) is required to produce \(1.00 \mathrm{kg}\) of \(\mathrm{Na}_{3} \mathrm{AlF}_{6} ?\)

Short Answer

Expert verified
Based on the given information, determine the mass of NaAlO2 required to produce 1.00 kg of Na3AlF6. 1. Write down the balanced chemical equation: 6 HF(g) + 3 NaAlO2(s) → Na3AlF6(s) + 3 H2O(l) + Al2O3(s) 2. Calculate the moles of Na3AlF6 produced (use the molar mass): Moles of Na3AlF6 = mass of Na3AlF6 / molar mass of Na3AlF6 3. Calculate the moles of NaAlO2 required: Moles of NaAlO2 required = 3 × moles of Na3AlF6 4. Convert moles of NaAlO2 to grams (use the molar mass): Mass of NaAlO2 required = moles of NaAlO2 × molar mass of NaAlO2 Using the appropriate molar masses, calculate the mass of NaAlO2 required to produce 1.00 kg of Na3AlF6.

Step by step solution

01

Write down the balanced chemical equation

The given balanced chemical equation is: $$6 \mathrm{HF}(g)+3 \mathrm{NaAlO}_{2}(s) \rightarrow \mathrm{Na}_{3}\mathrm{AlF}_{6}(s)+3 \mathrm{H}_{2} \mathrm{O}(\ell)+\mathrm{Al}_{2}\mathrm{O}_{3}(s)$$
02

Calculate the moles of Na\(_3\)AlF\(_6\) produced

We are given that 1.00 kg (1000 g) of Na\(_3\)AlF\(_6\) is produced. To find the moles of Na\(_3\)AlF\(_6\), we can use its molar mass: Molar mass of Na\(_3\)AlF\(_6 = 3 \times (\text{molar mass of Na}) + (\text{molar mass of Al}) + 6 \times (\text{molar mass of F})\) Therefore, moles of Na\(_3\)AlF\(_6\) = \(\frac{\text{mass of Na}_{3}\text{AlF}_{6}}{\text{molar mass of Na}_{3}\text{AlF}_{6}}\)
03

Calculate the moles of NaAlO\(_2\) required

Using stoichiometry, we can determine the moles of NaAlO\(_2\) required for the production of the given moles of Na\(_3\)AlF\(_6\). From the balanced chemical equation, 3 moles of NaAlO\(_2\) are needed to produce 1 mole of Na\(_3\)AlF\(_6\). Moles of NaAlO\(_2\) required = \(3 \times (\text{moles of Na}_{3}\text{AlF}_{6})\)
04

Convert moles of NaAlO\(_2\) to grams

Now that we have the moles of NaAlO\(_2\) required, we can convert this value to grams using its molar mass: Molar mass of NaAlO\(_2\) = \((\text{molar mass of Na}) + (\text{molar mass of Al}) + 2 \times (\text{molar mass of O})\) Mass of NaAlO\(_2\) required = (moles of NaAlO\(_2\)) \(\times\) (molar mass of NaAlO\(_2\)) By following the above steps and using the appropriate molar masses, the mass of NaAlO\(_2\) required to produce 1.00 kg of Na\(_3\)AlF\(_6\) can be calculated.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical reactions
Chemical reactions are processes where reactants are transformed into products. In this particular reaction, aluminum ore is converted into cryolite (\(\mathrm{Na_3AlF_6}\)) by combining various substances. The reactants here are hydrofluoric acid (\(\mathrm{HF}\)) and sodium aluminate (\(\mathrm{NaAlO_2}\)). By understanding this, we see a chemical equation as a symbolic representation of a chemical reaction. It shows the substances involved and their proportions.

In the provided equation:
  • The left side contains the reactants: \(6\ \mathrm{HF}(g)\) and \(3\ \mathrm{NaAlO_2}(s)\).
  • The right side shows the products formed: \(\mathrm{Na_3AlF_6}(s)\), \(3\ \mathrm{H_2O}(\ell)\), and \(\mathrm{Al_2O_3}(s)\).
This equation indicates that specific amounts of reactants yield specific amounts of products. The equation must be balanced to obey the law of conservation of mass, which states that atoms cannot be created or destroyed in chemical reactions. Understanding chemical reactions allows us to predict the outcomes when different substances interact.
Molar mass calculation
Molar mass is crucial in stoichiometry for converting between mass and moles. Each atom has a unique molar mass, corresponding to its atomic weight found on the periodic table. The molar mass of a compound is the sum of the molar masses of its constituent elements. This is essential in converting measured gross mass of a substance into moles, which are more useful for stoichiometric calculations.

To find the molar mass of \(\mathrm{Na_3AlF_6}\) used in this reaction:
  • Molar mass of \(\mathrm{Na} = 23.00 \ \text{g/mol}\)
  • Molar mass of \(\mathrm{Al} = 26.98 \ \text{g/mol}\)
  • Molar mass of \(\mathrm{F} = 19.00 \ \text{g/mol}\)
Therefore, the molar mass of \(\mathrm{Na_3AlF_6}\) is calculated as\[3 \times 23.00 + 26.98 + 6 \times 19.00 = 209.98 \ \text{g/mol}.\]This allows us to convert the 1,000 grams of \(\mathrm{Na_3AlF_6}\), as given in the problem, to moles using the formula: \(\text{moles of } \mathrm{Na_3AlF_6} = \frac{\text{mass of } \mathrm{Na_3AlF_6}}{\text{molar mass of } \mathrm{Na_3AlF_6}}\).
Balanced equations
Balanced equations are critical in chemical reactions as they ensure that the same number of each type of atom is present on both sides of the equation. This balance is fundamental because it corresponds to the conservation of mass. Without a balanced equation, it would be impossible to correctly relate amounts of reactants to amounts of products.

In our specific equation:
  • Reactants: \(6\ \mathrm{HF}\) and \(3\ \mathrm{NaAlO_2}\).
  • Products: \(\mathrm{Na_3AlF_6}\), \(3\ \mathrm{H_2O}\), and \(\mathrm{Al_2O_3}\).
Each element is accounted for on both sides of the reaction. For example, there are six fluorine atoms both before and after the reaction due to the combination of \(6\ \mathrm{HF}\) forming \(\mathrm{Na_3AlF_6}\). The equation is balanced with respect to every element involved.

This balance allows us to apply stoichiometry accurately. For instance, knowing three moles of \(\mathrm{NaAlO_2}\) are needed per mole of \(\mathrm{Na_3AlF_6}\) is derived from a balance of all atomic ultimately helping us calculate the amount of reactants like \(\mathrm{NaAlO_2}\) needed. This becomes a powerful tool in planning chemical reactions in both laboratory and industrial settings.

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Most popular questions from this chapter

Some indoor air-purification systems work by converting a little of the oxygen in the air to ozone, which kills mold and mildew spores and other biological air pollutants. The chemical equation for the ozone generation reaction is $$3 \mathrm{O}_{2}(g) \rightarrow 2 \mathrm{O}_{3}(g)$$ It is claimed that one such system generates \(4.0 \mathrm{g} \mathrm{O}_{3}\) per hour from dry air passing through the purifier at a flow of \(5.0 \mathrm{L} / \mathrm{min.}\) If exactly 1 liter of indoor air contains \(0.28 \mathrm{g}\) \(\mathrm{O}_{2},\) what percentage of the \(\mathrm{O}_{2}\) is converted to \(\mathrm{O}_{3}\) by the air purifier?

Calculate the percent composition of (a) \(\mathrm{Na}_{2} \mathrm{O},\) (b) \(\mathrm{NaOH}\) (c) \(\mathrm{NaHCO}_{3},\) and \((\mathrm{d}) \mathrm{Na}_{2} \mathrm{CO}_{3}.\)

Uranium oxides used in the preparation of fuel for nuclear reactors are separated from other metals in minerals by converting the uranium to \(\mathrm{UO}_{x}\left(\mathrm{NO}_{3}\right)_{y}\left(\mathrm{H}_{2} \mathrm{O}\right)_{z},\) where uranium has a positive charge ranging from \(3+\) to \(6+\) a. Roasting UO \(_{x}\left(\mathrm{NO}_{3}\right)_{y}\left(\mathrm{H}_{2} \mathrm{O}\right)_{z}\) at \(400^{\circ} \mathrm{C}\) leads to loss of water and decomposition of the nitrate ion to nitrogen oxides, leaving behind a product with the formula \(\mathrm{U}_{a} \mathrm{O}_{b}\) that is \(83.22 \%\) U by mass. What are the values of \(a\) and b? What is the charge on \(\mathrm{U}\) in \(\mathrm{U}_{a} \mathrm{O}_{b}\) ? b. Higher temperatures produce a different uranium oxide, \(\mathrm{U}_{c} \mathrm{O}_{d},\) which is \(84.8 \% \mathrm{U}\) by mass. What are the values of \(c\) and \(d ?\) What is the charge on \(\mathrm{U}\) in \(\mathrm{U}_{\epsilon} \mathrm{O}_{d} ?\) c. The values of \(x, y,\) and \(z\) in \(\mathrm{UO}_{x}\left(\mathrm{NO}_{3}\right)_{y}\left(\mathrm{H}_{2} \mathrm{O}\right)_{z}\) are found by gently heating the compound to remove all of the water. In a laboratory experiment, \(1.328 \mathrm{g}\) \(\mathrm{UO}_{x}\left(\mathrm{NO}_{3}\right)_{y}\left(\mathrm{H}_{2}\mathrm{O}\right)_{z}\) produced \(1.042\mathrm{g}\mathrm{UO}_{x}\left(\mathrm{NO}_{3}\right)_{y}.\) Continued heating generated \(0.742 \mathrm{g} \mathrm{U}_{n} \mathrm{O}_{m} .\) Using the information in parts (a) and (b), calculate \(x, y,\) and \(z\)

A chemical reaction produces less than the expected amount of product. Is this result a violation of the law of conservation of mass?

Corn farmers in the American Midwest typically use \(5.0 \times 10^{3}\) kilograms of ammonium nitrate fertilizer per square kilometer of cornfield per year. Some of the fertilizer washes into the Mississippi River and eventually flows into the Gulf of Mexico, promoting the growth of algae and endangering other aquatic life. a. Ammonium nitrate can be prepared by the following reaction: $$\mathrm{NH}_{3}(g)+\mathrm{HNO}_{3}(a q) \rightarrow \mathrm{NH}_{4} \mathrm{NO}_{3}(a q)$$ How much nitric acid would be required to make the fertilizer needed for \(1 \mathrm{km}^{2}\) of cornfield per year? b. Ammonium ions dissolved in groundwater may be converted into \(\mathrm{NO}_{3}^{-}\) ions by bacterial action: $$\mathrm{NH}_{4}^{+}(a q)+2 \mathrm{O}_{2}(g) \rightarrow \mathrm{NO}_{3}^{-}(a q)+\mathrm{H}_{2} \mathrm{O}(\ell)+2 \mathrm{H}^{+}(a q)$$ If \(10 \%\) of the ammonium component of \(5.0 \times 10^{3}\) kilograms of fertilizer ends up as nitrate ions, how much oxygen would be consumed?

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