Chapter 21: Problem 89
Write the sequence of all possible tetrapeptides composed of the following amino acids. a. two phenylalanines and two glycines b. two phenylalanines, glycine, and alanine
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Chapter 21: Problem 89
Write the sequence of all possible tetrapeptides composed of the following amino acids. a. two phenylalanines and two glycines b. two phenylalanines, glycine, and alanine
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For the following formulas, what types of isomerism could be exhibited? For each formula, give an example that illustrates the specific type of isomerism. The types of isomerism are structural, geometric, and optical. a. \(C_{6} H_{12}\) b. \(\mathrm{C}_{5} \mathrm{H}_{12} \mathrm{O} \quad\) c. \(\mathrm{C}_{6} \mathrm{H}_{4} \mathrm{Br}_{2}\)
Draw structural formulas for each of the following alcohols. Indicate whether the alcohol is primary, secondary, or tertiary. a. \(1-\) butanol c. 2 -methyl- 1 -butanol b. 2-butanol d. 2 -methyl- 2 -butanol
The following organic compounds cannot exist. Why? a. 2 -chloro-2-butyne b. 2 -methyl-2-propanone c. 1,1 -dimethylbenzene d. 2 -pentanal e. 3 -hexanoic acid f. 5,5 -dibromo- 1 -cyclobutanol
Ethylene oxide,is an important industrial chemical. Although most ethers are unreactive, ethylene oxide is quite reactive. It resembles \(\mathrm{C}_{2} \mathrm{H}_{4}\) in its reactions in that addition reactions occur across the C-O bond in ethylene oxide. a. Why is ethylene oxide so reactive? (Hint: Consider the bond angles in ethylene oxide as compared with those predicted by the VSEPR model.) b. Ethylene oxide undergoes addition polymerization, forming a polymer used in many applications requiring a nonionic surfactant. Draw the structure of this polymer.
Explain why methyl alcohol is soluble in water in all proportions, while stearyl alcohol \(\left[\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{16} \mathrm{OH}\right]\) is a waxy solid that is not soluble in water.
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