Chapter 21: Problem 90
How many different pentapeptides can be formed using five different amino acids?
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Chapter 21: Problem 90
How many different pentapeptides can be formed using five different amino acids?
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The average molar mass of one base pair of nucleotides in DNA is approximately 600 g/mol. The spacing between successive base pairs is about \(0.34 \mathrm{nm},\) and a complete turn in the helical structure of DNA occurs about every \(3.4 \mathrm{nm}\). If a DNA molecule has a molar mass of \(4.5 \times 10^{9} \mathrm{g} / \mathrm{mol}\), approximately how many complete turns exist in the DNA \(\alpha\)-helix structure?
When acrylic polymers are burned, toxic fumes are produced. For example, in many airplane fires, more passenger deaths have been caused by breathing toxic fumes than by the fire itself. Using polyacrylonitrile as an example, what would you expect to be one of the most toxic, gaseous combustion products created in the reaction?
Considering your answers to Exercises 130 and \(131,\) how can you justify the existence of proteins and nucleic acids in light of the second law of thermodynamics?
Aspartame, the artificial sweetener marketed under the name NutraSweet, is a methyl ester of a dipeptide: a. What two amino acids are used to prepare aspartame? b. There is concern that methanol may be produced by the decomposition of aspartame. From what portion of the molecule can methanol be produced? Write an equation for this reaction.
Integrative Problems. These problems require the integration of multiple concepts to find the solutions. An organometallic compound is one containing at least one metal-carbon bond. An example of an organometallic species is \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2}\right) \mathrm{MBr},\) which contains a metal-cthyl bond. How does the hybridization of the starred carbon atom change, if at all, in going from reactants to products? c. What is the systematic name of the product? (Hint: In this shorthand notation, all the \(\mathrm{C}-\mathrm{H}\) bonds have been eliminated and the lines represent \(\mathrm{C}-\mathrm{C}\) bonds, unless shown differently. As is typical of most organic compounds, cach carbon atom has four bonds to it and the oxygen atoms have only two bonds.) a. If \(\mathrm{M}^{2+}\) has the electron configuration \([\mathrm{Ar}] 3 d^{10},\) what is the percent by mass of \(\mathrm{M}\) in \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2}\right) \mathrm{MBr} ?\) b. A reaction involving \(\left(\mathrm{CH}, \mathrm{CH}_{2}\right) \mathrm{MBr}\) is the conversion of a ketone to an alcohol as illustrated here:
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