Chapter 20: Problem 40
Write equations describing the reactions of Sn with each of the following: \(\mathrm{Cl}_{2}, \mathrm{O}_{2}\), and \(\mathrm{HCl}\).
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Chapter 20: Problem 40
Write equations describing the reactions of Sn with each of the following: \(\mathrm{Cl}_{2}, \mathrm{O}_{2}\), and \(\mathrm{HCl}\).
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Use the symbols of the elements described in the following clues to fill in the blanks that spell out the name of a famous American scientist. Although this scientist was better known as a physicist than as a chemist, the Philadelphia institute that bears his name does include a biochemistry research facility. (1) The oxide of this alkaline earth metal is amphoteric. (2) The element that makes up approximately \(3.0 \%\) by mass of the human body. (3) The element having a \(7 s^{1}\) valence electron configuration. (4) This element is the alkali metal with the least negative standard reduction potential. Write its symbol in reverse order. (5) The alkali metal whose ion is more concentrated in intracellular fluids as compared with blood plasma. (6) This is the only alkali metal that reacts directly with nitrogen to make a binary compound with formula \(\mathrm{M}_{3} \mathrm{~N}\). (7) This element is the first in Group \(3 \mathrm{~A}\) for which the \(+1\) oxidation state is exhibited in stable compounds. Use only the second letter of its symbol.
What ions are found in hard water? What happens when water is "softened"?
Hydrogen peroxide is used as a cleaning agent in the treatment of cuts and abrasions for several reasons. It is an oxidizing agent that can directly kill many microorganisms; it decomposes upon contact with blood, releasing elemental oxygen gas (which inhibits the growth of anaerobic microorganisms); and it foams upon contact with blood, which provides a cleansing action. In the laboratory, small quantities of hydrogen peroxide can be prepared by the action of an acid on an alkaline earth metal peroxide, such as barium peroxide: $$\mathrm{BaO}_{2}(s)+2 \mathrm{HCl}(a q) \longrightarrow \mathrm{H}_{2} \mathrm{O}_{2}(a q)+\mathrm{BaCl}_{2}(a q)$$ What mass of hydrogen peroxide can result when \(1.50 \mathrm{~g}\) barium peroxide is treated with \(25.0 \mathrm{~mL}\) hydrochloric acid solution containing \(0.0272 \mathrm{~g} \mathrm{HCl}\) per \(\mathrm{mL}\) ? What mass of which reagent is left unreacted?
The Group 5 A elements can form molecules or ions that involve three, five, or six covalent bonds; \(\mathrm{NH}_{3}, \mathrm{AsCl}_{5}\), and \(\mathrm{PF}_{6}^{-}\) are examples. Draw the Lewis structure for each of these substances, and predict the molecular structure and hybridization for each. Why doesn't \(\mathrm{NF}_{5}\) or \(\mathrm{NCl}_{6}^{-}\) form?
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