Chapter 15: Problem 14
Acid-base indicators mark the end point of titrations by "magically" turning a different color. Explain the "magic" behind acid-base indicators.
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Chapter 15: Problem 14
Acid-base indicators mark the end point of titrations by "magically" turning a different color. Explain the "magic" behind acid-base indicators.
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Consider a solution formed by mixing \(50.0 \mathrm{~mL}\) of \(0.100 \mathrm{M}\) \(\mathrm{H}_{2} \mathrm{SO}_{4}, 30.0 \mathrm{~mL}\) of \(0.100 \mathrm{M} \mathrm{HOCl}, 25.0 \mathrm{~mL}\) of \(0.200 \mathrm{M} \mathrm{NaOH}\). \(25.0 \mathrm{~mL}\) of \(0.100 \mathrm{M} \mathrm{Ba}(\mathrm{OH})_{2}\), and \(10.0 \mathrm{~mL}\) of \(0.150 \mathrm{M} \mathrm{KOH}\). Calculate the \(\mathrm{pH}\) of this solution.
Mixing together solutions of acetic acid and sodium hydroxide can make a buffered solution. Explain. How does the amount of each solution added change the effectiveness of the buffer?
What volumes of \(0.50 \mathrm{M} \mathrm{HNO}_{2}\) and \(0.50 \mathrm{M} \mathrm{NaNO}_{2}\) must be mixed to prepare \(1.00 \mathrm{~L}\) of a solution buffered at \(\mathrm{pH}=3.55\) ?
Calculate the \(\mathrm{pH}\) of a solution that is \(1.00 \mathrm{M} \mathrm{HNO}_{2}\) and \(1.00 \mathrm{M}\) \(\mathrm{NaNO}_{2}\)
Amino acids are the building blocks for all proteins in our bodies. A structure for the amino acid alanine is All amino acids have at least two functional groups with acidic or basic properties. In alanine, the carboxylic acid group has \(K_{\mathrm{a}}=4.5 \times 10^{-3}\) and the amino group has \(K_{\mathrm{b}}=7.4 \times 10^{-5} .\) Because of the two groups with acidic or basic properties, three different charged ions of alanine are possible when alanine is dissolved in water. Which of these ions would predominate in a solution with \(\left[\mathrm{H}^{+}\right]=1.0 M ?\) In a solution with \(\left[\mathrm{OH}^{-}\right]=\) \(1.0 M ?\)
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