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A 2.5-L flask at \(15^{\circ} \mathrm{C}\) contains a mixture of \(\mathrm{N}_{2}\), \(\mathrm{He},\) and Ne at partial pressures of 0.32 atm for \(\mathrm{N}_{2}, 0.15\) atm for He, and 0.42 atm for Ne. (a) Calculate the total pressure of the mixture. (b) Calculate the volume in liters at STP occupied by He and Ne if the \(\mathrm{N}_{2}\) is removed selectively.

Short Answer

Expert verified
Total pressure is 0.89 atm; volume of He and Ne at STP is approximately 1.39 L.

Step by step solution

01

Identify the Partial Pressures

First, note the partial pressures of the individual gases present in the flask. - The partial pressure of \( \text{N}_2 \) is 0.32 atm.- The partial pressure of \( \text{He} \) is 0.15 atm.- The partial pressure of \( \text{Ne} \) is 0.42 atm.
02

Calculate Total Pressure

The total pressure of a gas mixture is the sum of the partial pressures of each gas present. Using Dalton's Law of Partial Pressures: \[P_{\text{total}} = P_{\text{N}_2} + P_{\text{He}} + P_{\text{Ne}} \] Substitute in the known values: \[P_{\text{total}} = 0.32 \text{ atm} + 0.15 \text{ atm} + 0.42 \text{ atm} = 0.89 \text{ atm}\] Therefore, the total pressure is 0.89 atm.
03

Use Ideal Gas Law to Find the Volume of He and Ne at STP

To find the volume of \( \text{He} \) and \( \text{Ne} \) at STP (Standard Temperature and Pressure: 0°C and 1 atm), we need the moles of these gases. First, compute the moles of He and Ne using the Ideal Gas Law. The formula is \( PV = nRT \), where \( R = 0.0821 \; \text{L atm K}^{-1} \cdot \text{mol}^{-1} \).Correct the temperature to Kelvin: \( T = 15 + 273 = 288 \; \text{K} \).
04

Calculate Moles of Helium (He)

Using the Ideal Gas Law: \\[ n_{\text{He}} = \frac{P_{\text{He}} \cdot V}{R \cdot T} \] \Substituting in the values, \( P_{\text{He}} = 0.15 \; \text{atm} \), \( V = 2.5 \; \text{L} \), \( R = 0.0821 \; \text{L atm K}^{-1} \cdot \text{mol}^{-1} \), and \( T = 288 \; \text{K} \): \\[ n_{\text{He}} = \frac{0.15 \times 2.5}{0.0821 \times 288} \approx 0.016 \; \text{mol} \]
05

Calculate Moles of Neon (Ne)

Using the Ideal Gas Law: \\[ n_{\text{Ne}} = \frac{P_{\text{Ne}} \cdot V}{R \cdot T} \] \Substituting in the values, \( P_{\text{Ne}} = 0.42 \; \text{atm} \): \\[ n_{\text{Ne}} = \frac{0.42 \times 2.5}{0.0821 \times 288} \approx 0.046 \; \text{mol} \]
06

Combine Moles of He and Ne

Sum the moles of \( \text{He} \) and \( \text{Ne} \): \\[ n_{\text{total}} = n_{\text{He}} + n_{\text{Ne}} = 0.016 + 0.046 = 0.062 \; \text{mol} \]
07

Calculate New Volume at STP

Using the Ideal Gas Law rearranged for \( V \) and with \( P = 1 \; \text{atm} \), \( T = 273 \; \text{K} \): \\[ V = \frac{n \cdot R \cdot T}{P} \] \Substitute in the moles \( n = 0.062 \; \text{mol} \) and solve: \\[ V = \frac{0.062 \cdot 0.0821 \cdot 273}{1} \approx 1.39 \; \text{L} \] \ Therefore, the volume at STP for \( \text{He} \) and \( \text{Ne} \) is approximately 1.39 L.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Law
The Ideal Gas Law is one of the fundamental equations in chemistry that relates the pressure, volume, temperature, and number of moles of a gas. The formula is given by \( PV = nRT \), where:
  • \( P \) is the pressure of the gas in atmospheres (atm),
  • \( V \) is the volume of the gas in liters (L),
  • \( n \) is the number of moles of the gas,
  • \( R \) is the ideal gas constant (0.0821 L atm K-1 mol-1), and
  • \( T \) is the temperature in Kelvin (K).
To convert Celsius to Kelvin, simply add 273. This law assumes that the gas behaves ideally, meaning the gas particles do not interact and the volume of the particles themselves is negligible compared to the container. Ideal Gas Law helps to determine the unknown quantity among pressure, volume, temperature, or moles when the other three are known.
Partial Pressure
Partial pressure refers to the pressure exerted by a single type of gas in a mixture of gases. According to Dalton's Law of Partial Pressures, the total pressure of a mixture of gases is the sum of the partial pressures of all individual gases in the mixture. Mathematically:\[P_{\text{total}} = P_1 + P_2 + P_3 + ...\]For example, in the given problem, the partial pressures are given for nitrogen (\(\text{N}_2\)), helium (\(\text{He}\)), and neon (\(\text{Ne}\)). By adding these partial pressures, you determine the total pressure in the flask. This concept is vital for understanding how gases interact in a mixture and is used in various applications such as respiratory science and chemical engineering.
Standard Temperature and Pressure (STP)
Standard Temperature and Pressure (STP) is a reference point used in thermodynamics for the purpose of consistency in calculations involving gases. STP is defined as a temperature of 0°C (273 K) and a pressure of 1 atm. At STP, one mole of an ideal gas occupies 22.4 liters. This uniform benchmark allows scientists and engineers to compare different gases under the same conditions, making calculations more straightforward. In gas-related calculations, values of temperature and pressure are often converted to align with STP for easier analysis and comparison.
Gas Mixture Calculations
Solving problems involving gas mixtures often requires a clear understanding of both Dalton's Law and the Ideal Gas Law. When a gas mixture is described, you might need to find the total pressure from individual pressures or determine other properties like volume or number of moles under various conditions. For the given exercise:
  • First, calculate the total pressure using the partial pressures of the gases involved using Dalton's Law.
  • Then, use the Ideal Gas Law to find the volume at STP by first calculating the moles of the gases in the mixture.
  • It involves understanding the effect of selectively removing components, and converting conditions to STP allows for standardization in calculations.
Gas mixture calculations help in industries such as atmospheric science, engineering, and pharmaceuticals by ensuring the right conditions are applied for reactions or in processes, like gas purifications or blends.

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Most popular questions from this chapter

On heating, potassium chlorate \(\left(\mathrm{KClO}_{3}\right)\) decomposes to yield potassium chloride and oxygen gas. In one experiment, a student heated \(20.4 \mathrm{~g}\) of \(\mathrm{KClO}_{3}\) until the decomposition was complete. (a) Write a balanced equation for the reaction. (b) Calculate the volume of oxygen (in liters) if it was collected at 0.962 atm and \(18.3^{\circ} \mathrm{C}\)

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Propane \(\left(\mathrm{C}_{3} \mathrm{H}_{8}\right)\) burns in oxygen to produce carbon dioxide gas and water vapor. (a) Write a balanced equation for this reaction. (b) Calculate the number of liters of carbon dioxide measured at STP that could be produced from \(7.45 \mathrm{~g}\) of propane.

Sulfur dioxide reacts with oxygen to form sulfur trioxide. (a) Write the balanced equation and use data from Appendix 2 to calculate \(\Delta H^{\circ}\) for this reaction. (b) At a given temperature and pressure, what volume of oxygen is required to react with \(1 \mathrm{~L}\) of sulfur dioxide? What volume of sulfur trioxide will be produced? (c) The diagram on the right represents the combination of equal volumes of the two reactants. Which of the following diagrams [(i)-(iv)] best represents the result?

Dry air near sea level has the following composition by volume: \(\mathrm{N}_{2}, 78.08\) percent; \(\mathrm{O}_{2}, 20.94\) percent; \(\mathrm{Ar}, 0.93\) percent; \(\mathrm{CO}_{2}, 0.05\) percent. The atmospheric pressure is 1.00 atm. Calculate (a) the partial pressure of each gas in atmospheres and (b) the concentration of each gas in \(\mathrm{mol} / \mathrm{L}\) at \(0^{\circ} \mathrm{C}\). (Hint: Because volume is proportional to the number of moles present, mole fractions of gases can be expressed as ratios of volumes at the same temperature and pressure.)

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