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A cylinder \(1.00 \mathrm{~m}\) tall with inside diameter \(0.120 \mathrm{~m}\) is used to hold propane gas (molar mass \(44.1 \mathrm{~g} / \mathrm{mol}\) ) for use in a barbecue. It is initially filled with gas until the gauge pressure is \(1.30 \times 10^{6} \mathrm{~Pa}\) at \(22.0^{\circ} \mathrm{C}\). The temperature of the gas remains constant as it is partially emptied out of the tank, until the gauge pressure is \(3.40 \times 10^{5} \mathrm{~Pa}\). Calculate the mass of propane that has been used.

Short Answer

Expert verified
The mass of propane that has been used is calculated by subtracting the final moles from the initial moles and multiplying by the molar mass of propane.

Step by step solution

01

Identify Known and Unknown Variables

The given variables are the dimensions of the cylinder, the gauge pressures (initial and final), temperature, and molar mass of propane. The volume of the cylinder can be calculated using the formula for the volume of a cylinder \(V= \pi r^2 h\), where \(r\) is the radius and \(h\) is height of the cylinder. The unknown is the mass of propane used.
02

Calculate the Initial and Final Pressures

We can calculate the initial and final pressures in Pascals. The given values are gauge pressures, which are the pressures above atmospheric pressure. To get the true pressure, we need to add atmospheric pressure (101,325 Pa) to the gauge pressure. The initial pressure \(P1\) becomes \(1.30 \times 10^6 + 101,325\) Pa, and the final pressure \(P2\) becomes \(3.40 \times 10^5 + 101,325\) Pa.
03

Calculate Initial and Final Moles

With the temperature \(T\) given in degrees Celsius, convert it to Kelvin by adding 273.15. We then substitute \(P\), \(V\), \(R\) (8.3145 \(J / mol·K\)) and \(T\) into the ideal gas law \(PV = nRT\) to get the initial and final moles \(n1\) and \(n2\) respectively.
04

Calculate the Mass of Propane Used

Subtract the final moles from the initial moles to get the amount of moles used. Multiply this by the molar mass of propane (44.1 g/mol) to obtain the mass of propane used in grams.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding the Ideal Gas Law (PV=nRT)
The Ideal Gas Law, represented by the equation \(PV=nRT\), is a fundamental principle in chemistry and physics that describes the behavior of ideal gases. In this equation, \(P\) stands for pressure, \(V\) for the volume of the gas, \(n\) for the amount of substance in moles, \(R\) is the ideal gas constant, and \(T\) is the temperature in Kelvin. When solving problems involving the Ideal Gas Law, it's essential to ensure all variables are in the proper units. For pressure, the unit should be Pascals (Pa), the volume in cubic meters (m³), the amount of gas in moles, and the temperature in Kelvin (K).

When using the Ideal Gas Law for calculations, convert temperatures from Celsius to Kelvin by adding 273.15, and remember that pressures may need to be total pressures, taking into account atmospheric pressure when dealing with gauge pressures. Becoming comfortable with converting units and understanding the conditions under which the law applies is crucial to correctly using the equation for calculations like finding the mass of a gas under certain conditions, as seen in the exercise.
Calculating Molar Mass
The molar mass of a substance is the mass of one mole of that substance. It's typically expressed in grams per mole (g/mol). In the context of the Ideal Gas Law, knowing the molar mass is necessary to find the mass of a gas if the number of moles is known. For example, propane has a molar mass of \(44.1 \text{g/mol}\).

The calculation of molar mass is straightforward when you know the amount of moles and the mass: it is simply the division of the mass by the number of moles. Conversely, if you're solving for the mass (as in the exercise), you multiply the number of moles by the molar mass of the compound. Molar mass is a conversion factor that bridges the microscopic scale of atoms and molecules with the macroscopic scale that we can measure physically in a lab or industrial setting.
Interpreting Gauge Pressure
Gauge pressure is the pressure of a gas or liquid measured relative to the ambient atmospheric pressure. Essentially, it is the additional pressure in a system compared to the atmospheric pressure. For instance, if a gauge reads \(1.30 \times 10^6 \text{Pa}\), that's the pressure above the atmospheric pressure of about \(101,325 \text{Pa}\).

In many practical situations, like the one described in the exercise, you will deal with gauge pressure readings. To use these in calculations involving the Ideal Gas Law, you need to convert gauge pressure to absolute pressure. This is done by adding atmospheric pressure to the gauge pressure reading. Failing to do so might lead to incorrect calculations. Understanding gauge pressure is crucial for safely managing pressurized gases in various applications, including industrial and medical fields.
Volume Calculation of a Cylinder
The volume of a cylinder can be found using the formula \(V = \pi r^2 h\), where \(V\) stands for volume, \(r\) is the radius of the circular base, and \(h\) is the cylinder's height. In real-world problems, like the exercise, knowing how to calculate the cylinder's volume is key to determining the amount of gas it can hold.

The radius is half of the cylinder's diameter, so if the diameter is provided, you'll need to divide it by two to find the radius. Inserting the radius and height into the formula will give you the volume in cubic meters if you have used meters for the radius and height. For cylinders containing gases, the volume is essential for calculating properties like pressure and temperature using the Ideal Gas Law. When dealing with tanks, cylinders, or any similar storage containers, accurate volume calculation is fundamental in industries ranging from food and beverage to aeronautics.

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Most popular questions from this chapter

At what temperature is the root-mean-square speed of nitrogen molecules equal to the root-mean-square speed of hydrogen molecules at \(20.0^{\circ} \mathrm{C}\) ? (Hint: Appendix \(\mathrm{D}\) shows the molar mass (in \(\mathrm{g} / \mathrm{mol}\) ) of each element under the chemical symbol for that element. The molar mass of \(\mathrm{H}_{2}\) is twice the molar mass of hydrogen atoms, and similarly for \(\mathrm{N}_{2}\).)

A large tank of water has a hose connected to it (Fig. P18.61). The tank is sealed at the top and has compressed air between the water surface and the top. When the water height \(h\) has the value \(3.50 \mathrm{~m}\), the absolute pressure \(p\) of the compressed air is \(4.20 \times 10^{5} \mathrm{~Pa}\). Assume that the air above the water expands at constant temperature, and take the atmospheric pressure to be \(1.00 \times 10^{5} \mathrm{~Pa}\). (a) What is the speed with which water flows out of the hose when \(h=3.50 \mathrm{~m} ?\) (b) As water flows out of the tank, \(h\) decreases. Calculate the speed of flow for \(h=3.00 \mathrm{~m}\) and for \(h=2.00 \mathrm{~m} .\) (c) At what value of \(h\) does the flow stop?

Oxygen \(\left(\mathrm{O}_{2}\right)\) has a molar mass of \(32.0 \mathrm{~g} / \mathrm{mol} .\) What is (a) the average translational kinetic energy of an oxygen molecule at a temperature of \(300 \mathrm{~K} ;\) (b) the average value of the square of its speed; (c) the rootmean-square speed; (d) the momentum of an oxygen molecule traveling at this speed? (e) Suppose an oxygen molecule traveling at this speed bounces back and forth between opposite sides of a cubical vessel \(0.10 \mathrm{~m}\) on a side. What is the average force the molecule exerts on one of the walls of the container? (Assume that the molecule's velocity is perpendicular to the two sides that it strikes.) (f) What is the average force per unit area? (g) How many oxygen molecules traveling at this speed are necessary to produce an average pressure of 1 atm? (h) Compute the number of oxygen molecules that are contained in a vessel of this size at \(300 \mathrm{~K}\) and atmospheric pressure. (i) Your answer for part (h) should be three times as large as the answer for part \((\mathrm{g})\). Where does this discrepancy arise?

A physics lecture room at 1.00 atm and \(27.0^{\circ} \mathrm{C}\) has a volume of \(216 \mathrm{~m}^{3}\). (a) Use the ideal-gas law to estimate the number of air molecules in the room. Assume that all of the air is \(\mathrm{N}_{2} .\) Calculate (b) the particle density - that is, the number of \(\mathrm{N}_{2}\), molecules per cubic centimeter-and (c) the mass of the air in the room.

A parcel of air over a campfire feels an upward buoyant force because the heated air is less dense than the surrounding air. By estimating the acceleration of the air immediately above a fire, one can estimate the fire's temperature. The mass of a volume \(V\) of air is \(n M_{\text {air }},\) where \(n\) is the number of moles of air molecules in the volume and \(M_{\text {air }}\) is the molar mass of air. The net upward force on a parcel of air above a fire is roughly given by \(\left(m_{\text {out }}-m_{\text {in }}\right) g,\) where \(m_{\text {out }}\) is the mass of a volume of ambient air and \(m_{\text {in }}\) is the mass of a similar volume of air in the hot zone. (a) Use the ideal-gas law, along with the knowledge that the pressure of the air above the fire is the same as that of the ambient air, to derive an expression for the acceleration \(a\) of an air parcel as a function of \(\left(T_{\text {out }} / T_{\text {in }}\right),\) where \(T_{\text {in }}\) is the absolute temperature of the air above the fire and \(T_{\text {out }}\) is the absolute temperature of the ambient air. (b) Rearrange your formula from part (a) to obtain an expression for \(T_{\text {in }}\) as a function of \(T_{\text {out }}\) and \(a\). (c) Based on your experience with campfires, estimate the acceleration of the air above the fire by comparing in your mind the upward trajectory of sparks with the acceleration of falling objects. Thus you can estimate \(a\) as a multiple of \(g .\) (d) Assuming an ambient temperature of \(15^{\circ} \mathrm{C}\), use your formula and your estimate of \(a\) to estimate the temperature of the fire.

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