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A cylindrical tank has a tight-fitting piston that allows the volume of the tank to be changed. The tank originally contains \(0.110 \mathrm{~m}^{3}\) of air at a pressure of 0.355 atm. The piston is slowly pulled out until the volume of the gas is increased to \(0.390 \mathrm{~m}^{3}\). If the temperature remains constant, what is the final value of the pressure?

Short Answer

Expert verified
The final value of the pressure in the tank is 0.100 atm.

Step by step solution

01

Identify the Known and Unknown Variables

In this problem, the initial volume \(V_1\) is \(0.110 \mathrm{~m}^{3}\), the initial pressure \(P_1\) is \(0.355\) atm and the final volume \(V_2\) is \(0.390 \mathrm{~m}^{3}\). The final pressure \(P_2\) is unknown and is what we aim to find out.
02

Apply Boyle’s Law

We can use Boyle's law to solve for \(P_2\), the final pressure. Boyle's Law is given by: \(P_1V_1=P_2V_2\). Solving this equation for \(P_2\) gives us \(P_2 = \frac{P_1V_1}{V_2}\).
03

Substitute Values into the Formula and Solve

By substituting \(P_1 = 0.355\) atm, \(V_1 = 0.110 m^3\) and \(V_2 = 0.390 m^3\) into the formula, we can then solve for \(P_2\). Doing that we get \(P_2 = \frac{(0.355 \mathrm{~atm})(0.110 \mathrm{~m}^{3})}{0.390 \mathrm{~m}^{3}} = 0.100 \mathrm{~atm}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Gas Laws
Boyle's Law is part of a family known as the gas laws, forming a foundation for understanding how gases behave under different conditions. These laws are essential for predicting and interpreting gas behavior in various scenarios. They include:
  • Boyle's Law: Relates pressure and volume at constant temperature.
  • Charles's Law: Relates volume and temperature at constant pressure.
  • Avogadro's Law: Relates volume and number of moles at constant temperature and pressure.
  • Gay-Lussac's Law: Relates pressure and temperature at constant volume.
Among these, Boyle's Law is particularly useful for understanding how gas pressure changes when its volume changes, as seen in the piston problem.
When we know two of the three variables (pressure, volume, or temperature) and keep the third constant, we can predict how the others will change.
This is exactly the approach used in the original exercise to determine the final pressure after the volume changes, while the temperature remains consistent.
Cylindrical Tank
A cylindrical tank often includes a piston, specifically when dealing with experiments that need precise control over the gas volume. The tight-fitting piston in our problem ensures no gas escapes or enters, making our observations accurate. Here’s why such a setup is beneficial:
  • Maintains control over volume increase or decrease.
  • Enables investigation of pressure-volume relationships.
  • Helps keep the system closed, which is essential for applying Boyle’s Law.
This tank allows the user to vary the volume while keeping the other variables constant. For experiments requiring precise measurement of gas properties, such as the one described, the cylindrical tank with a piston offers reliability and accuracy.
The physical properties of the cylinder (such as its material and fit of the piston) ensure consistent behavior of the gas during volume changes.
This consistency is what allows for direct application of gas laws in controlled settings.
Pressure-Volume Relationship
At the heart of Boyle's Law is the pressure-volume relationship which states that pressure and volume are inversely proportional when temperature is constant. This principle can be demonstrated by the equation:\[ P_1V_1 = P_2V_2 \]This means if the volume of a gas increases, the pressure decreases provided the temperature remains unchanged, and vice versa.
In practical terms, for our problem:
  • Initial state: 0.355 atm and 0.110 m³.
  • Final state needed: 0.100 atm when volume is 0.390 m³.
This relationship is intuitive and observed in balloons or syringes, where changing the space a gas occupies results in changes in pressure.
By understanding this inverse relationship, we can confidently make predictions about one variable's changes if the other is manipulated, making it a crucial concept for problem-solving in thermodynamics and fluid mechanics.

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Most popular questions from this chapter

A Jaguar XK8 convertible has an eight-cylinder engine. At the beginning of its compression stroke, one of the cylinders contains \(499 \mathrm{~cm}^{3}\) of air at atmospheric pressure \(\left(1.01 \times 10^{5} \mathrm{~Pa}\right)\) and a temperature of \(27.0^{\circ} \mathrm{C}\). At the end of the stroke, the air has been compressed to a volume of \(46.2 \mathrm{~cm}^{3}\) and the gauge pressure has increased to \(2.72 \times 10^{6} \mathrm{~Pa}\). Compute the final temperature.

You have several identical balloons. You experimentally determine that a balloon will break if its volume exceeds \(0.900 \mathrm{~L}\). The pressure of the gas inside the balloon equals air pressure \((1.00 \mathrm{~atm}) .\) (a) If the air inside the balloon is at a constant \(22.0^{\circ} \mathrm{C}\) and behaves as an ideal gas, what mass of air can you blow into one of the balloons before it bursts? (b) Repeat part (a) if the gas is helium rather than air.

How much heat does it take to increase the temperature of \(1.80 \mathrm{~mol}\) of an ideal gas by \(50.0 \mathrm{~K}\) near room temperature if the gas is held at constant volume and is (a) diatomic; (b) monatomic?

A person at rest inhales \(0.50 \mathrm{~L}\) of air with each breath at a pressure of 1.00 atm and a temperature of \(20.0^{\circ} \mathrm{C}\). The inhaled air is \(21.0 \%\) oxygen. (a) How many oxygen molecules does this person inhale with each breath? (b) Suppose this person is now resting at an elevation of \(2000 \mathrm{~m}\) but the temperature is still \(20.0^{\circ} \mathrm{C}\). Assuming that the oxygen percentage and volume per inhalation are the same as stated above, how many oxygen molecules does this person now inhale with each breath? (c) Given that the body still requires the same number of oxygen molecules per second as at sea level to maintain its functions, explain why some people report "shortness of breath" at high elevations.

(a) Show that a projectile with mass \(m\) can "escape" from the surface of a planet if it is launched vertically upward with a kinetic energy greater than \(m g R_{p},\) where \(g\) is the acceleration due to gravity at the planet's surface and \(R_{\mathrm{p}}\) is the planet's radius. Ignore air resistance. (See Problem \(18.70 .\) ) (b) If the planet in question is the earth, at what temperature does the average translational kinetic energy of a nitrogen molecule (molar mass \(28.0 \mathrm{~g} / \mathrm{mol}\) ) equal that required to escape? What about a hydrogen molecule (molar mass \(2.02 \mathrm{~g} / \mathrm{mol}\) )? (c) Repeat part (b) for the moon, for which \(g=1.63 \mathrm{~m} / \mathrm{s}^{2}\) and \(R_{\mathrm{p}}=1740 \mathrm{~km}\) (d) While the earth and the moon have similar average surface temperatures, the moon has essentially no atmosphere. Use your results from parts (b) and (c) to explain why.

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