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How much heat does it take to increase the temperature of \(1.80 \mathrm{~mol}\) of an ideal gas by \(50.0 \mathrm{~K}\) near room temperature if the gas is held at constant volume and is (a) diatomic; (b) monatomic?

Short Answer

Expert verified
Therefore, the amount of heat required to increase the temperature of the given amount of ideal gas is approximately \(3563.1 \mathrm{~joules}\) for diatomic gas and \(2137.86 \mathrm{~joules}\) for monatomic gas.

Step by step solution

01

Define the given values

The given values are: Mol = \(1.80 \mathrm{~mol}\), Temperature Change = \(50.0 \mathrm{~K}\). The molar heat capacity at constant volume (\(C_v\)) differs for diatomic gases (5/2 * R) and monatomic gases (3/2 * R), where \(R=8.314 \mathrm{~joules~per~mole~kelvin}\).
02

Calculate the heat for diatomic gas

The formula for calculating the heat required is \(q = n * C_v * \Delta T\). Substituting the given values into the formula yields \(q_diatomic = 1.80 \mathrm{~mol}~*~(5/2 * 8.314 \mathrm{~joules~per~mole~kelvin})~*~50.0 \mathrm{~K}\). This gives \(q_diatomic = 3563.1 \mathrm{~joules}\).
03

Calculate the heat for monatomic gas

Using the same formula and substituting the respective value for \(C_v\), for a monatomic gas, yields \(q_monatomic = 1.80 \mathrm{~mol}~*~(3/2 * 8.314 \mathrm{~joules~per~mole~kelvin})~*~50.0 \mathrm{~K}\). This gives \(q_monatomic = 2137.86 \mathrm{~joules}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Law
Understanding the ideal gas law is fundamental to grasping how gases behave under various conditions. The ideal gas law is a mathematical equation that describes the relationship between pressure (P), volume (V), temperature (T), and the amount of substance (n) in moles for an ideal gas. It is expressed as \( PV = nRT \), where R is the universal gas constant, with a value of \( 8.314 \) joules per mole kelvin (J/mol·K).

When dealing with exercises related to the ideal gas law, it's crucial to recognize that the conditions of constant volume or pressure can significantly impact the calculation. In the given exercise, the gas is held at constant volume, meaning that the pressure and number of moles may vary with temperature. These conditions tie directly into thermodynamic principles and are key to determining how much heat is required to cause a temperature change in the gas.

Using the ideal gas law, students can get insights into other related properties of the gas, such as heat capacity, which will be crucial to solve thermodynamics problems.
Thermodynamics
Thermodynamics is a branch of physics that deals with heat and temperature and their relation to energy and work. The behavior of these quantities is governed by the four laws of thermodynamics which dictate how energy is transferred in the form of heat.

One important concept in thermodynamics is heat capacity, which refers to the amount of heat energy required to raise the temperature of a substance by a certain temperature interval. For gases, the heat capacity can be given at constant volume \( (C_v) \) or at constant pressure \( (C_p) \). The molar heat capacity is the heat capacity per mole of a substance. The exercise provided involves the molar heat capacity at constant volume, which is different for diatomic and monatomic gases due to their atomic structures influencing how they store energy.

Understanding molar heat capacity is essential for solving problems related to heat transfer in gases. The given step-by-step solution employs this concept to calculate the heat required to raise the temperature of a gas by using the specific molar heat capacities for diatomic and monatomic gases.
Heat Transfer
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, thermal convection, thermal radiation, and phase-change heat transfer.

The exercise at hand demonstrates a straightforward case of heat transfer where energy is added to a system (an ideal gas) at a constant volume to increase its temperature. This process is quantitatively expressed through the formula \( q = nC_v\bigtriangleup T \), where \( q \) is the heat added, \( n \) is the number of moles, \( C_v \) is the molar heat capacity at constant volume, and \( \bigtriangleup T \) is the temperature change.

The heat transferred to the gas results in increased kinetic energy of its particles, thereby raising the temperature. In the ideal gas approximation, the atoms or molecules in the gas do not interact except for elastic collisions, which simplifies the calculation of heat transfer compared to more complex interactions in real gases. By understanding the types of heat transfer and how they apply to different thermodynamic systems, students can more effectively solve problems related to temperature changes and energy dynamics.

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Most popular questions from this chapter

Solid water (ice) is slowly warmed from a very low temperature. (a) What minimum external pressure \(p_{1}\) must be applied to the solid if a melting phase transition is to be observed? Describe the sequence of phase transitions that occur if the applied pressure \(p\) is such that \(p

A flask with a volume of \(1.50 \mathrm{~L}\), provided with a stopcock, contains ethane gas \(\left(\mathrm{C}_{2} \mathrm{H}_{6}\right)\) at \(300 \mathrm{~K}\) and atmospheric pressure \(\left(1.013 \times 10^{5} \mathrm{~Pa}\right) .\) The molar mass of ethane is \(30.1 \mathrm{~g} / \mathrm{mol} .\) The system is warmed to a temperature of \(550 \mathrm{~K},\) with the stopcock open to the atmosphere. The stopcock is then closed, and the flask is cooled to its original temperature. (a) What is the final pressure of the ethane in the flask? (b) How many grams of ethane remain in the flask?

How many moles of an ideal gas exert a gauge pressure of 0.876 atm in a volume of \(5.43 \mathrm{~L}\) at a temperature of \(22.2^{\circ} \mathrm{C} ?\)

At what temperature is the root-mean-square speed of nitrogen molecules equal to the root-mean-square speed of hydrogen molecules at \(20.0^{\circ} \mathrm{C}\) ? (Hint: Appendix \(\mathrm{D}\) shows the molar mass (in \(\mathrm{g} / \mathrm{mol}\) ) of each element under the chemical symbol for that element. The molar mass of \(\mathrm{H}_{2}\) is twice the molar mass of hydrogen atoms, and similarly for \(\mathrm{N}_{2}\).)

It is possible to make crystalline solids that are only one layer of atoms thick. Such "two-dimensional" crystals can be created by depositing atoms on a very flat surface. (a) If the atoms in such a twodimensional crystal can move only within the plane of the crystal, what will be its molar heat capacity near room temperature? Give your answer as a multiple of \(R\) and in \(\mathrm{J} / \mathrm{mol} \cdot \mathrm{K}\). (b) At very low temperatures, will the molar heat capacity of a two-dimensional crystal be greater than, less than, or equal to the result you found in part (a)? Explain why.

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