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Your company develops radioactive isotopes for medical applications. In your work there, you measure the activity of a radioactive sample. Your results are given in the table.

Time (h) Decays ,s

0 20,000

0.5 14,800

1.0 11,000

1.5 8130

2.0 6020

2.5 4460

3.0 3300

4.0 1810

5.0 1000

6.0 550

7.0 300

(a) Find the half-life of the sample.

(b) How many radioactive nuclei were present in the sample att= 0?

(c) How many were present after 7.0 h?

Short Answer

Expert verified

a. T1/2=1.16h

b. N|t=0=1.20×108nuclei

c. N|t=7=1.80×106nuclei

Step by step solution

01

Known

the relation between the activity R of a sample and the number of radioactive nuclei N in the sample is given by:

R=λN ...............(i)

the number N of remaining nuclei after time t is given by:

N=N0e-λt ...............(ii)

Where N0is the number of nuclei at t = 0.

Multiplying equation (ii) by A and substituting equation (i), we get

R=R0e-λt ...............(iii)

Where R is the activity after time t and R0is the activity at t = 0.

the relation between the half-life T1/2and the decay constant λis given by:

λ=ln2T1/2 ..................(iv)

02

Calculate R

To take any information from any measured data, we need to fit the data first.

The equation that describes the dependence of the activity on the time is equation (iii); Taking the natural logarithm for equation (iii), we get:

lnR=lnR0e-λt

So, if we graph In R versus t, we should get a straight line, where its slope is -λand intercept ln R axis at lnR0. Thus, let us relist the given data but add one more column to is the values of In R, so we get:

03

a. Calculate the half-life of the sample with a graph

Now, we graph ln R versus t, as shown below.

From the graph, the slope is -0.60, thus, the decay constant is:

λ=0.60h-1=1.67×10-4s-1

Now, we substitute his value into equation (iv), so we get the half-life of the isotope:

T1/2=ln20.60h-1=1.16h

04

b. Calculate the number of radioactive nuclei present in the sample at t = 0

At t = 0, R= 20000, so we substitute our values for λand R into equation (i) and evaluate for N, so we get the number of nuclei present in the sample at [color(red)t = 0]

N=Rλ=20,000decay/s1.67×10-4s-1=1.20×108nuclei

05

c. Calculate the number of radioactive nuclei present in the sample at t = 7.0

At t= 7.0 h,

R = 300,

So we substitute our values for λand R into equation (i) and evaluate for N, so we get the number of nuclei present in the sample at [color(red)t = 7]

N=Rλ=300decay/s1.67×10-4s-1=1.80×106nuclei

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