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A sample of hydrogen atoms is irradiated with light with wavelength 85.5 nm, and electrons are observed leaving the gas. (a) If each hydrogen atom were initially in its ground level, what would be the maximum kinetic energy in electron volts of these photoelectrons? (b) A few electrons are detected with energies as much as 10.2 eV greater than the maximum kinetic energy calculated in part (a). How can this be?

Short Answer

Expert verified

(a) The maximum kinetic energy in electron volts of these photoelectrons is 0.90eV.

(b) When an atom is in the excited state n=2 and is hit by a 1.45eV photon, it will gain 10.2eV more kinetic energy than the maximum kinetic energy in part (a).

Step by step solution

01

Total energy of an electron in Bohr’s Model

=1n2mee4802h2theunitisbyjoule=1n2mee380h2unitbyeV=1n29.10941031kg1.6021019c388.85431012Nm2/c226.6261034J.s2En=13.6057n2eVEn=me4802n2h2

Planck鈥檚 Constant;

E=hf=hc

02

The maximum kinetic energy in electron volts of these photoelectrons

(a) The photon's energy is equal to

E=hc=4.1361015eVs3.0108m/s85.5109m=14.5eV

Some of this energy will be converted into kinetic energy, while the rest will be used to free an electron from the atom.

(From n=1 to n=), the energy required to liberate an electron is:

E=EE1=0(13.6eV)=13.6eV

As a result, the photoelectron's kinetic energy is

K=14.5eV-13.6eV=0.90eV

The maximum kinetic energy in electron volts of these photoelectrons is 0.90eV.

03

The maximum kinetic energy

(b) The difference in energy between the n=2 and ground levels is;

E=E2E1=13.6eV2213.6eV12=10.2eV

Hence, when an atom is in the excited state n=2 and is hit by a 1.45eV photon, it will gain 10.2eV more kinetic energy than the maximum kinetic energy in part (a)

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