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Calculate the frequency, energy (in keV), and wavelength of the Kxray for the elements (a) calcium (Ca,Z=20) ; (b) cobalt (Co,Z=27) ; (c) cadmium (Cd,Z=48).

Short Answer

Expert verified

a)The frequency, energy, and wavelength of Kx-ray for the calcium are 8.951017Hz,3.70keVand 3.3510-10mrespectively.

b) The frequency, energy, and wavelength of Kx-ray for the cobalt is 1.671018Hz,6.93keVand 1.7910-10m respectively.

c) The frequency, energy, and wavelength of Kx-rays for the cadmium is 5.481018Hz,22.7keVand 5.4810-11mrespectively

Step by step solution

01

Define Moseley's Law.

If the frequency of Kxray of the spectrum of an element of an atomic number Z is v, then by Moseley鈥檚 law frequency is written as:

=(2.481015Hz)(Z-1)2鈥︹赌︹赌︹赌︹赌︹赌︹赌(1)

The energy of the photon is determined by the equation

E=hv

The relation between the wavelength and frequency of the photon is

=cv

02

Determine the frequency, energy, and wavelength of calcium.

Given that, the atomic number of calcium is 20.

The frequency of theKx- ray for the calcium:

vCa=2.481015Hz20-12=8.951017Hz

The energy of theKx- ray for the calcium:

Eca=4.31610-15eV.s8.951017Hz=3.86103eV1keV103eV=3.86keV

The wavelength of theKx- ray for the calcium:

Ca=3.0108m/s8.951017Hz=3.3510-10m

Hence, the frequency, energy, and wavelength of Kx-ray for the calcium are8.951017Hz,3.86keV and 3.3510-10mrespectively.

03

Determine the frequency, energy, and wavelength of cobalt.

Given that, the atomic number of cobalt is 27.

The frequency of theKx-ray for the cobalt:

vco=2.481015Hz27-12=1.671018Hz

The energy of theKx-ray for the cobalt:

Eco=4.31610-15eV.s1.681018Hz=7.25103eV1keV103eV=7.25keV

The wavelength of theKx-ray for the cobalt:

Co=3.0108m/s1.681018Hz=1.7910-10m

Hence, the frequency, energy, and wavelength ofKx- rays for the cobalt are 1.671018Hz,7.25keVand 1.7910-10mrespectively.

04

Determine the frequency, energy, and wavelength of cadmium.

Given that, the atomic number of cadmium is 48.

The frequency of theKx- ray for the cadmium:

vCd=2.481015Hz48-12=5.481018Hz

The energy of theKx- ray for the cadmium:

Ecd=4.13610-15eV.s5.481018Hz=2.36104eV1keV103eV=23.6keV

The wavelength of theKx- ray for the cadmium:

Cd=3.0108m/s5.481018Hz=5.4810-11m

Hence, the frequency, energy, and wavelength ofKx- ray for the cadmium are 5.481018Hz,23.6keVand 5.4810-11mrespectively.

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