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How many different 5g states does hydrogen have? (b) Which of the states in part (a) has the largest angle between L and the z-axis, and what is that angle? (c) Which of the states in part (a) has the smallest angle between L and the z-axis, and what is that angle?

Short Answer

Expert verified

(a) There are 9 states

(b) The largest angle corresponds to the states withml=-4 and the angle ismin=153.4

(c) The smallest angle corresponds to the states withml=-4 and the angle ismin=26.57

Step by step solution

01

Important Concepts

The z-component of the orbital angular momentum in a hydrogen atom is given by

Lz=mlh

Where is the magnetic quantum number, it can have values from 鈥搇 to +l.

The angle the vector L makes with the z-axis is given by

=cos-1LzL

02

Application

We know that the magnetic quantum number can have values from -l +l .

For the 5g state, the orbital quantum number is l=4. So the possible values of are0,1,2,3,4

Thus in total, there are 9 different states.

03

Find the angle

We know that the angle made by the orbital angular momentum vector is given by

=cos-1LzL

So, the largest value of the angle corresponds to the smallest value of

Lzmin=4h

=cos-1-4h44+1h=cos-1-425=153.4

The smallest value of the angle corresponds to the largest value of Lz

(Lz)max=4h

=cos-1-4h44+1h=cos-1-425=26.57

Hence, The largest angle corresponds to the states with ml=-4and the angle is min=153.4The smallest angle corresponds to the states withml=-4 and the angle ismin=26.57

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