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42.27. For a solid metal having a Fermi energy of 8.500 eV, what is the probability, at room temperature, that a state having an energy of 8.520 eV is occupied by an electron?

Short Answer

Expert verified
The probability is approximately 0.312.

Step by step solution

01

Understanding the Fermi-Dirac Distribution

The Fermi-Dirac distribution describes the probability that an electron state at a certain energy level is occupied at a given temperature. It is given by the formula: \( f(E) = \frac{1}{e^{(E-E_F)/kT} + 1} \), where \(E\) is the energy of the state, \(E_F\) is the Fermi energy, \(k\) is the Boltzmann constant \(8.617 \times 10^{-5} \text{ eV/K}\), and \(T\) is the temperature in Kelvin.
02

Convert Room Temperature to Kelvin

Room temperature is approximately 20°C, which needs to be converted to Kelvin. The conversion is given by: \( T(K) = 20 + 273.15 = 293.15 \text{ K} \).
03

Calculate the Energy Difference

Calculate the difference between the energy level \(E\) and the Fermi energy \(E_F\): \( E - E_F = 8.520 \text{ eV} - 8.500 \text{ eV} = 0.020 \text{ eV} \).
04

Calculate the Argument for the Exponential Function

Compute the argument for the exponential function in the Fermi-Dirac distribution formula: \( \frac{E - E_F}{kT} = \frac{0.020}{8.617 \times 10^{-5} \cdot 293.15} \approx 0.789 \).
05

Calculate the Fermi-Dirac Probability

Substitute the calculated values into the Fermi-Dirac distribution formula to find the probability: \( f(8.520) = \frac{1}{e^{0.789} + 1} \). Compute the exponential: \( e^{0.789} \approx 2.201 \). Then, \( f(8.520) = \frac{1}{2.201 + 1} \approx \frac{1}{3.201} \approx 0.312 \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Fermi Energy
Fermi energy is a fundamental concept in quantum physics, particularly in the study of solid-state physics and semiconductor devices. It is the highest energy level that electrons in a metal can occupy at absolute zero temperature. This energy level acts as a baseline, helping us understand how electrons behave when the metal is at higher temperatures.

Fermi energy is crucial for describing the distributions of electrons among different energy states. It defines the energy at which the probability of an electron occupying it is precisely 50%. In metals, the Fermi energy is typically measured in electron volts (eV), symbolized as \(E_F\). Understanding Fermi energy helps us predict the electrical properties of materials, such as conductivity and band structure.
Boltzmann Constant
The Boltzmann constant \(k\) links the macroscopic and microscopic worlds by relating temperature at a macroscopic level with energy at a microscopic level. This is essential when studying particles like electrons in a metal. Its value is \(8.617 \times 10^{-5} \text{ eV/K}\), and it plays a pivotal role in statistical mechanics.

In the context of Fermi-Dirac distribution, the Boltzmann constant is used to scale temperature, allowing us to study particle distributions at various temperatures. By combining it with energy differences and temperature measurements, it helps determine the occupancy probability of energy states, especially when the temperature deviates from absolute zero.
Probability at Room Temperature
To calculate the probability of an electron being in a specific energy state, we use the Fermi-Dirac distribution, which includes room temperature in its equations. At a typical room temperature of approximately 293 K, we express this as \(20 + 273.15 = 293.15 \text{ K}\). This is a standard conversion essential for calculations.

Room temperature conditions are crucial in practical scenarios, as they reflect standard living conditions. They affect electron distribution in conductive materials. Applied to Fermi-Dirac statistics, this temperature helps in calculating the likelihood or probability that an electron state is occupied, taking into account the Fermi energy and the specific energy level of the state being examined.
Energy Occupancy Probability
The energy occupancy probability is determined using the Fermi-Dirac formula: \[ f(E) = \frac{1}{e^{(E-E_F)/kT} + 1} \]This equation gives us the probability that a particular electron energy state is occupied by an electron. It adjusts based on temperature and the difference in energy between the state and the Fermi energy.

To solve such a problem, like the one in the exercise, we first calculate \(E - E_F\) and then use this value in the formula. With the Boltzmann constant and temperature in the formula, we compute the exponential part. The final result gives us the probability, such as 0.312 in this case. This number tells us how likely it is for an electron to occupy the state at 8.520 eV at room temperature.

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Most popular questions from this chapter

(a) Consider the hydrogen molecule \(\left(\mathrm{H}_{2}\right)\) to be a simple harmonic oscillator with an equilibrium spacing of 0.074 \(\mathrm{nm}\) , and estimate the vibrational energy-level spacing for \(\mathrm{H}_{2}\) . The mass of a hydrogen atom is \(1.67 \times 10^{-27} \mathrm{kg}\) . (Hint: Estimate the force constant by equating the change in Coulomb repulsion of the protons, when the atoms move slightly closer together than \(r_{0},\) to the "spring" force. That is, assume that the chemical binding force remains approximately constant as \(r\) is decreased slightly from \(r_{0} .\) ) (b) Use the results of part (a) to calculate the vibrational energy-level spacing for the deuterium molecule, \(\mathrm{D}_{2}\) . Assume that the spring constant is the same for \(\mathrm{D}_{2}\) as for \(\mathrm{H}_{2}\) . The mass of a deuterium atom is \(3.34 \times 10^{-27} \mathrm{kg}\) .

Calculate the wavelengths of (a) a \(6.20-\mathrm{keV} \times\) ray; (b) a 37.6 -eV electron; (c) a 0.0205 -eV neutron.

The vibration frequency for the molecule \(\mathrm{HF}\) is \(1.24 \times 10^{14} \mathrm{Hz}\) . The mass of a hydrogen atom is \(1.67 \times 10^{-27} \mathrm{kg}\) , and the mass of a fluorine atom is \(3.15 \times 10^{-26} \mathrm{kg}\) . (a) What is the force constant \(k^{\prime}\) for the interatomic force? (b) What is the spacing between adjacent vibrational energy levels in joules and in electron volts? (c) What is the wavelength of a photon of energy equal to the energy difference between two adjacent vibrational levels? In what region of the spectrum does it lie?

Pure germanium has a band gap of 0.67 eV. The Fermi energy is in the middle of the gap. (a) For temperatures of 250 \(\mathrm{K}\) , 300 \(\mathrm{K}\) , and 350 \(\mathrm{K}\) , calculate the probability \(f(E)\) that a state at the bottom of the conduction band is occupied. (b) For each temperature in part (a), calculate the probability that a state at the top of the valence band is empty.

(a) The equilibrium separation of the two nuclei in an NaCl molecule is 0.24 \(\mathrm{nm}\) If the molecule is modeled as charges \(+e\) and \(-e\) separated by 0.24 \(\mathrm{nm}\) , what is the electric dipole moment of the molecule (see Section 21.7\() ?\) (b) The measured electric dipole moment of an NaCl molecule is \(3.0 \times 10^{-29} \mathrm{C} \cdot \mathrm{m} .\) If this dipole moment arises from point charges \(+q\) and \(-q\) separated by 0.24 \(\mathrm{nm}\) , what is \(q ?(\mathrm{c})\) A definition of the fractional ionic character of the bond is \(q | e .\) If the sodium atom has charge \(+e\) and the chlorine atom has charge \(-e\) , the fractional ionic character would be equal to \(1 .\) What is the actual fractional ionic character for the bond in NaCl?(d) The equilibrium distance between nuclei in the hydrogen iodide (HI) molecule is 0.16 \(\mathrm{nm}\) , and the measured electric dipole moment of the molecule is \(1.5 \times 10^{-30} \mathrm{C} \cdot \mathrm{m} .\) What is the fractional ionic character for the bond in HI? How does your answer compare to that for NaCl calculated in part (c)? Discuss reasons for the difference in these results.

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